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Block Copolymer Micelles

Part of the Advances in Polymer Science book series (POLYMER,volume 190)

Abstract

This review summarizes recent advances to date in the area of block copolymer micelles and also tries to highlight some new directions in that field. Generalities about the preparation, characterization, and dynamics of block copolymer micelles are first outlined. Selected examples of micelle formation in aqueous and organic media are shown for block copolymers with various architectures. The different types of micellar morphologies are discussed. New directions in block copolymer micellization are finally presented.

  • ABC triblock copolymers
  • Block copolymers
  • Interpolyelectrolyte complexes
  • Micelles
  • Nanostructures
  • Polyelectrolytes
  • Supramolecular chemistry

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Abbreviations

AFM:

atomic force microscopy

AUC:

analytical ultracentrifugation

b :

grafting distance

BIC:

block ionomer complex

CMC:

critical micelle concentration

CMD:

critical micelle density

CMT:

critical micelle temperature

CWC:

critical water concentration

DMF:

N,N-dimethylformamide

DLS:

dynamic light scattering

D h :

hydrodynamic diameter

FCS:

fluorescence correlation spectroscopy

IPEC:

interpolyelectrolyte complex

LCST:

lower critical solubility temperature

MALS:

multiangle light scattering

MW:

molecular weight

N :

degree of polymerization

N A :

degree of polymerization of core-forming block

N B :

degree of polymerization of corona-forming block

NMR:

nuclear magnetic resonance

PAA:

poly(acrylic acid)

PaspA:

Poly(aspartic acid)

PB:

polybutadiene

PBAEMA:

poly(tert-butylaminoethyl methacrylate)

PBLG:

poly(γ-benzyl-L-glutamate)

PBO:

poly(butylene oxide)

PDEAEMA:

poly(N,N-diethylaminoethyl methacrylate)

PDMAEMA:

poly(N,N-dimethylaminoethyl methacrylate)

PDMAI:

poly(N,N-dimethylaminoisoprene)

PDPAEMA:

poly(N,N-diisopropylaminoethyl methacrylate)

PCEMA:

poly(cinnamoylethyl methacrylate)

PCL:

poly(ε-caprolactone)

PDMS:

poly(dimethylsiloxane)

PEB:

poly(ethylene-co-butylene)

PEI:

poly(ethylene imine)

PEG:

poly(ethylene glycol)

PEHA:

poly(2-ethylhexyl acrylate)

PEHMA:

poly(2-ethylhexyl methacrylate)

PEO:

poly(ethylene oxide)

PEOVE:

poly(2-ethoxyethyl vinyl ether)

PFS:

poly(ferrocenylsilane)

PGANa:

poly(sodium L-glutamate)

PHIC:

poly(hexyl isocyanate)

PI:

poly(isoprene)

PIB:

poly(isobutylene)

PIC:

poly(isocyanodipeptide)

PLL:

poly(L-lysine)

PMAA:

poly(methacrylic acid)

PMANa:

poly(sodium methacrylate)

PMACs:

poly(cesium methacrylate)

PMEMA:

poly(2-(N-morpholinoethyl) methacrylate)

PMMA:

poly(methylmethacrylate)

PMOVE:

poly(2-methoxyethyl vinyl ether)

PMOXA:

poly(methyl oxazoline)

PMPS:

poly(methylphenylsilane)

PMTGEVE:

poly(methyl tri(ethyleneglycol) vinyl ether)

PMVE:

poly(methyl vinyl ether)

PNIPAAM:

poly(N-isopropyl acrylamide)

PPO:

poly(propylene oxide)

PPQ:

poly(phenylquinoline)

PS:

polystyrene

PSCNa:

poly(sodium 4-styrene carboxylate)

PSMA:

poly(stearylmethacrylate)

PSOH:

poly(styrene-co-[p-(2,2,2- trifluoro-1-hydroxy-1-trifluoromethyl)ethylmethylstyrene])

PSS:

poly(styrene sulfonate)

PTAN:

poly(1,1,2,2-tetrahydroperfluorooctyl acrylate)

PtBA:

poly(tert-butylacrylate)

PtBMA:

poly(tert-butyl methacrylate)

PtBS:

poly(tert-butylstyrene)

PVA:

poly(vinyl alcohol)

PVAC:

poly(vinylacetate)

P2VP:

poly(2-vinylpyridine)

P2VPQ:

poly(2-vinylpyridine) quaternized

P4VP:

poly(4-vinylpyridine)

R c :

micellar core radius

R g :

radius of gyration

R h :

hydrodynamic radius

R m :

total micellar radius

SANS:

small-angle neutron scattering

SAXS:

small-angle X-ray scattering

SEC:

size-exclusion chromatography

SEM:

scanning electron microscopy

scCO2 :

supercritical CO2

SLS:

static light scattering

TEM:

transmission electron microscopy

T g :

glass transition temperature

THF:

tetrahydrofuran

UCST:

upper critical solubility temperature

Z :

aggregation number

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Gohy, JF. Block Copolymer Micelles. In: Abetz, V. (eds) Block Copolymers II. Advances in Polymer Science, vol 190. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_048

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