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Enzymatic Catalysis in the Synthesis of Polyanilines and Derivatives of Polyanilines

  • Peng Xu
  • Amarjit Singh
  • David L. Kaplan
Chapter
Part of the Advances in Polymer Science book series (POLYMER, volume 194)

Abstract

Enzyme catalysis in the synthesis of polyaniline is reviewed. Oxidoreductase enzymes and biomimetic catalysts have been used for the polymerization in aqueous, aqueous organic, and interfacial or templating environments to optimize polymer features. The results showed significant structural control in the presence of templates to produce water soluble and processable polymeric materials. Dip-pen nanolithography technology has also been used to process these materials into conducting nano-wires and thus provides new opportunities for the formation of electrical contacts among biological components for various applications such as synthetic biological interfaces.

Keywords

Sodium Dodecyl Benzenesulfonate Enzymatic Catalysis Oxalyl Chloride Aniline Derivative Enzymatic Polymerization 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abbreviations

AFM

Atomic force microscopy

BOD

Bilirubin oxidase

CD

Circular dichroism

CSA

Camphorsulphonic acid

DBSA

Dodecylbenzenesulfonic acid

DMF

Dimethyl Formaldehyde

DMSO

Dimethylsulfoxide

DP

1,2-Diamino propane

DPN

Dip-pen nanolithography

EDOT

Ethylenedioxythiophene

ELBL

Electrostatic layer-by-layer

FeB

2,6-bis[1-2,6-diisopropylphenylimino-ethyl]pyridine iron(II) chloride

HRP

Horseradish peroxidase

HRPC

Horseradish peroxidase isoenzyme C

HTBA

Hexadecyltrimethylammonium bromide

LB

Langmuir-Blodgett

LGS

Lignosulfonate

LT

Langmuir trough

MALDI

Matrix-assisted laser desorption ionization

OC

Oxalyl chloride

PAA

Poly(acrylic acid)

PANI

Polyaniline

PDAC

Poly(dimethyl diallylammonium chloride)

PEO

Poly(ethylene oxide)

PVA

Poly(vinyl alcohol)

PVP

Poly(vinylphosphonic acid)

PYR

Pyrrole

SBP

Soybean peroxidase

SDBS

Sodium dodecyl benzenesulfonate

SPE

Screen-printed electrode

SPM

Scanning probe microscopy

SPS

Sulfonated polystyrene

TOF

Time of flight

Triton

Polyoxyethylene(10) isooctylphenyl ether

XPS

X-ray photoelectron spectroscopy

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Authors and Affiliations

  1. 1.Departments of Biomedical Engineering and Chemical & Biological EngineeringBioengineering & Biotechnology CenterMedfordUSA
  2. 2.Department of RadiologyHarvard Medical SchoolBostonUSA

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