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Enzymatic Synthesis and Properties of Polymers from Polyphenols

  • Hiroshi Uyama
  • Shiro KobayashiEmail author
Chapter
Part of the Advances in Polymer Science book series (POLYMER, volume 194)

Abstract

Enzymatic synthesis and properties of polymers from polyphenols are reviewed. Catechol derivatives were subjected to oxidative polymerization and curing. High-performance coatings were prepared from urushiol and its analogues using laccase as a catalyst. Flavonoids were oxidatively polymerized by polyphenol oxidase, laccase, and peroxidase to produce the flavonoid polymers. The conjugation of polyphenols on amine-containing polymers took place via the enzyme catalysis. The flavonoid-containing polymers showed good antioxidant properties and enzyme inhibitory effects.

Enzymatic oxidative polymerization Flavonoid Urushi Curing Conjugate 

Abbreviations

AAPH

2,2′-azobis(2-amidinopropane)dihydrochloride

AP

acetone powder

ChC

Clostridium histolyticum collagenase

CNSL

cashew nut shell liquid

DP

degree of polymerization

EGCG

epigallocatechin gallate

HRP

horseradish peroxidase

LDL

low-density lipoprotein

ML

Myceliophthora laccase

MMP

matrix metalloproteinases

PCL

Pycnoporus coccineus laccase

PL

poly(ε-lysine)

POSS

polyhedral oligomeric silsesquioxane

PPO

polyphenol oxidases

ROS

reactive oxygen species

SP

starch-urea phosphate

XO

xanthine oxidase

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Authors and Affiliations

  1. 1.Department of Materials Chemistry, Graduate School of EngineeringOsaka UniversitySuitaJapan
  2. 2.Department of Materials Chemistry, Graduate School of EngineeringKyoto UniversityKyotoJapan

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