Abstract
This review summarizes the current status of radical-based transition metal catalyzed reactions in organic chemistry. The underlying features of radical generation from transition metal complexes and radical reactivity in the framework of transition metal catalysis are discussed. The available arsenal to detect radicals in transition metal catalyzed transformations is presented. Available strategies to combine radical intermediates with transition metal catalysis are outlined. In the main part the currently known synthetic methodology of transition metal catalyzed reactions proceeding via radical intermediates is discussed. This part covers catalytic radical reactions involving group 4 to group 7 elements.
Keywords
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Acknowledgments
This manuscript is dedicated to Professor Dr. Bernd Giese, a pioneer of preparative radical chemistry and early contributor to this topic, on the occasion of his 70th birthday. Generous funding by the Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic (Z4 055 0506), and the Grant Agency of the Czech Republic (203/09/1936) is gratefully acknowledged. I thank my group for critical reading of the manuscript and many helpful comments and discussions. I apologize to all colleagues for the omissions of their work that were necessary due to space constraints of the manuscript.
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Jahn, U. (2011). Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? A Fruitful Interplay Anyway. In: Heinrich, M., Gansäuer, A. (eds) Radicals in Synthesis III. Topics in Current Chemistry, vol 320. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2011_261
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DOI: https://doi.org/10.1007/128_2011_261
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