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Solid-State NMR of Inorganic Semiconductors

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Solid State NMR

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 306))

Abstract

Studies of inorganic semiconductors by solid-state NMR vary widely in terms of the nature of the samples investigated, the techniques employed to observe the NMR signal, and the types of information obtained. Compared with the NMR of diamagnetic non-semiconducting substances, important differences often result from the presence of electron or hole carriers that are the hallmark of semiconductors, and whose theoretical interpretation can be involved. This review aims to provide a broad perspective on the topic for the non-expert by providing: (1) a basic introduction to semiconductor physical concepts relevant to NMR, including common crystal structures and the various methods of making samples; (2) discussions of the NMR spin Hamiltonian, details of some of the NMR techniques and strategies used to make measurements and theoretically predict NMR parameters, and examples of how each of the terms in the Hamiltonian has provided useful information in bulk semiconductors; (3) a discussion of the additional considerations needed to interpret the NMR of nanoscale semiconductors, with selected examples. The area of semiconductor NMR is being revitalized by this interest in nanoscale semiconductors, the great improvements in NMR detection sensitivity and resolution that have occurred, and the current interest in optical pumping and spintronics-related studies. Promising directions for future research will be noted throughout.

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Abbreviations

BOM:

Bond orbital model

CB:

Conduction band

CP:

Cross-polarization

CSA:

Chemical shift anisotropy

CT:

Central transition

CVD:

Chemical vapor deposition

DFT:

Density functional theory

DMS:

Diluted magnetic semiconductors

DNP:

Dynamic nuclear polarization

DOS:

Density of states

EFG:

Electric field gradient

ENDOR:

Electron-nuclear double resonance

EPR:

Electron paramagnetic resonance

ESR:

Electron spin resonance

FID:

Free induction decay

FMR:

Ferromagnetic magnetic resonance

HETCOR:

Heteronuclear correlation

HVPE:

Hydride vapor-phase epitaxy

LD:

Laser diode

LED:

Light-emitting diode

MAS:

Magic-angle spinning

MAT:

Magic-angle turning

MBE:

Molecular beam epitaxy

MCDA:

Magnetic circular dichroism absorption

MOCVD:

Metal-organic chemical vapor deposition

MQ:

Multiple-quantum

MRFM:

Magnetic resonance force microscopy

MSN:

Magic-sized nanocrystals

NAR:

Nuclear acoustic resonance

NC:

Nanocrystal

NMR:

Nuclear magnetic resonance

NNN:

Next nearest neighbors

NQCC:

Nuclear quadrupole coupling constant

NQR:

Nuclear quadrupole resonance

NW:

Nanowires

ODMR:

Optically-detected magnetic resonance

OMVPE:

Organometallic vapor-phase epitaxy

OPNMR:

Optically pumped NMR

POWER:

Perturbations observed with enhanced resolution (NMR)

QD:

Quantum dot

QIP:

Quantum information processing

SEDOR:

Spin-echo double resonance

SI:

Semi-insulating

ST:

Satellite transition

TCO:

Transparent conducting oxides

TEM:

Transmission electron microscopy

TOPO:

Trioctylphosphine oxide

VB:

Valence band

WZ:

Wurtzite

XRPD:

X-ray powder diffraction

ZB:

Zincblende

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Acknowledgments

This research was supported by the Office of Naval Research.

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Yesinowski, J.P. (2011). Solid-State NMR of Inorganic Semiconductors. In: Chan, J. (eds) Solid State NMR. Topics in Current Chemistry, vol 306. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2011_208

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