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Photochemistry and Photophysics of Coordination Compounds: Osmium

  • Duraisamy Kumaresan
  • Kalpana Shankar
  • Srivathsa Vaidya
  • Russell H. SchmehlEmail author
Chapter
Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 281)

Abstract

This review provides an overview of research since the year 2000 relating to photochemical and photophysical processes involving complexes of osmium. The review is broken into four focus subjects. The photophysical investigations of Os(II) imine complexes and other classical transition metal complexes is presented, including a brief discussion of theoretical approaches to understanding electronic structure. An overview of light induced energy and electron transfer reactions involving Os complexes is also covered. Photoreactions of organometallic Os complexes are discussed, focusing on mechanistic aspects of metal–metal cleavage in diosmium and triosmium carbonyl complexes. Finally, reports of applications of Os complexes to sensors, dye sensitized solar cells, electroluminescent devices, and biological systems are presented.

Bipyridyl Energy transfer Osmium complexes Osmium photochemistry Osmium photophysics Photosubstitution Terpyridyl 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2007

Authors and Affiliations

  • Duraisamy Kumaresan
    • 1
  • Kalpana Shankar
    • 1
  • Srivathsa Vaidya
    • 1
  • Russell H. Schmehl
    • 1
    Email author
  1. 1.Department of ChemistryTulane UniversityNew OrleansUSA

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