Summary
A thin film with barrier property contained in damascene process flows prevents the conducting copper from mixing with the dielectric. Due to control of chemical reactions at the surface and its excellent step coverage, ALD has drawn considerable attention for this application. A significant amount of processes for transition metal nitrides and metal films have been developed, which are mostly based on thermal or plasma-enhanced ALD. Both of these techniques have benefits and drawbacks to guarantee a substrate compatible process, as well as a dense and sufficiently conductive material. The substrate sensitivity is inherent to the ALD processing technique. Preparing a substrate surface that shows high reactivity towards a given ALD process is crucial to guaranteeing an intact film with a low thickness of 5 nm or less. Transition metal nitrides are mainly considered as ALD layers with barrier property. ALD metal layers of cobalt and ruthenium are useful as barrier adhesion promoters. Ruthenium films are also potential Cu seed and direct plating materials.
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Schuhmacher, J., Martina, A., Satta, A., Maexa, K. (2005). Atomic-layer Deposited Barrier and Seed Layers for Interconnects. In: Zschech, E., Whelan, C., Mikolajick, T. (eds) Materials for Information Technology. Engineering Materials and Processes. Springer, London. https://doi.org/10.1007/1-84628-235-7_4
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DOI: https://doi.org/10.1007/1-84628-235-7_4
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