Abstract
Rock digestion methods, including lithium metaborate fusion and three microwave digestion procedures, are evaluated for the analysis of the rare earth elements (REEs) and 42 other trace elements in samples of Paleozoic carbonate, Paleozoic quartzite and shale from southern Nevada, and the U.S. Geological Survey standard for diabase, W-2. The trace elements were determined in the dissolved rock samples by low resolution inductively coupled plasma-mass spectrometry (ICP-MS). The lithium metaborate fusion method gave excellent recoveries of the REEs and most other trace elements for W-2. However, the method yielded relatively poor recoveries for some trace elements such as Cr, Zn, and Pb. Two of the three microwave digestion procedures performed better overall than the fusion method. Potential interference from the suspected major components (Si, Cl, Fe, Sr, and Ba) and interference of the light rare earth element oxides on the heavy REEs are discussed. Since the rock type may determine the chemical composition of the associated groundwater, the relative solubilities for the elements under study were approximated for a carbonate system by water-rock concentration ratios.
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Banner, J.L. Wasserburg, G.J., Dobson, P.F., Carpenter, A.B. and Moore, C.H. 1989. Isotopic and Trace element constrains on the origin and evolution of saline ground waters from central Missouri. Geochim. Cosmochim, Acta. 53, 383–398.
CEM Corporation 1991a. Microwave sample preparation system, Matthews, NC, U.S.A.
CEM Corporation, 1991b. Operation Manual. Matthews, NC, USA.
Cook, N.J., Wood, S.A. and Zhang, Y. 1992. Transport and fixation of Au, Pt and Pd around the Lac Sheen Cu-Ni-PGE occurrence in Quebec, Canada. J. Geochem. Explor. 46, 187.
CRC Press, 1985–1986. Handbook of Chemistry and Physics, 66th Edition, ed. R.C. Weast.
Drever, J.I. 1997. The geochemistry of natural water. Simon and Schuster, Upper Saddle River, NJ.
Dulski, P. 1994. Interferences of oxide, hydroxide and chloride analyte species in the determination of rare earth elements in geological samples by inductively coupled plasma-mass spectrometry. Fresenlus J. Anal. Chem. 350, 194–203.
Dudley, Jr., W.W. and Larson, J.D. 1976. Effect of irrigation pumping on desert pupfish habitats in Ash Meadows, Nye County, NV. U.S. Geol. Surv. Prof. Pap. 927, 52 pp.
Eakin, T.E. 1966. A regional interbasin groundwater flow system in the White River area, southeastern Nevada. Water Res. 2, 251–271.
Farnham, I.M., Stetzenbach, K.J., Singh, A.K., and Johannesson, K.H. 2000. Deciphering groundwater flow system in Oasis Valley, Nevada, using trace element chemistry, multivariate statistics, and geographical information system. Mathematical Geology, vol. 32, No. 8, 943–968.
Feldman, C. 1983. Behavior of trace refractory minerals in the lithium metaborate fusion-acid dissolution procedure. Anal. Chem. 55, 2451–2453.
Frape, S.K., Fritz, P., and Nutt, R.H. 1984. Water-rock interaction and chemistry of groundwaters of the Canadian Shield. Geochim. Cosmochim. Acta. 48, 1617–1627.
Garrels, R.M. and MacKenzie, F.T. 1967. Origin of the chemical composition of some springs and lakes, equilibrium concepts in natural water systems. Am. Chem. Soc. Adv. Chem. Ser. V. 67, pp. 222–242.
Gilman, L.B. and Engelhart, W.G. 1989. Recent advances in microwave sample preparation. Spectroscopy V. 4, No. 8, 14–21.
Gosselin, D.C., Smith, M.R., Lepel, E.A., and Laul, E.A. 1992. Rare earth elements in chloride-rich ground water, Palo Duro Basin Texas USA. Geochim. Cosmochim. Acta. 56, 1495–1505.
Gromet, L.P. and Silver, L.T. 1983. Rare earth element distributions among minerals in a granodiorite and their petrogenetic implications, Geochim. Cosmochim. Acta. 47, 925–939.
Guo, C.X. 1996. Determination of fifty-six elements in three distinct types of geological materials by inductively coupled plasma-mass spectrometry. M.S. thesis, University of Nevada Las Vegas.
Hanson, G.N. 1980. Rare earth elements in petrogenetic studies of igneous systems, Ann. Rev. Earth Planet. Sci. 8, 371.
Hem, J.D. 1985. Study and interpretation of chemical characteristics of natural waters. U.S. Geol. Survey. Water Supply Pap. 2254, 3rd ed.
Hodge, V.F., Johannesson, K.H., and Stetzenbach, K.J. 1996. Rhenium, molybdenum, and uranium in groundwater from the southern Great Basin, USA: Evidence for conservative behavior, Geochim. Cosmochim. Acta. 60, 3197–3214.
Hodge, V.F., Stetzenbach, K.J., and Johannesson, K.H. 1998. Similarities in the chemical composition of carbonate groundwaters and seawater. Environ. Sci. Technol. 32, 2481–2486.
Hurlbut, Jr., C.S., and Klein, C. 19777 Manual of Mineralogy, 19th Edition, John Wiley and Sons, New York.
Jarvis, I. and Jarvis, K.E. 1992. Plasma spectrometry in the earth sciences: techniques, applications and future trends. Chem. Geol. 95, 1–33.
Jarvis, K.E., Gray A.L., and Mcmurdy, E. 1989. Avoidance of spectral interference on europium in inductively coupled plasma mass spectrometry by sensitive measurement of the doubly charged ion. J. Anal. At. Spectrom. 4, 743–747.
Jarvis, K.E. 1988. Inductively coupled plasma mass spectrometry: A new technique for the rapid or ultra-trace level determination of the rare-earth elements in geological materials. Chem. Geol. 68, 31–39.
Jarvis, K.E. 1990. A critical evaluation of two sample preparation techniques for low-level determination of some geologically incompatible elements by inductively coupled plasma-mass spectrometry. Chem. Geol. 83, 89–103.
Jenner, G.A., Longerich, H.P., Jackson, S.E., and Fryer, B.J. 1990. ICP-MS — A powerful tool for high precision trace-element analysis in Earth sciences: Evidence from analysis of selected USGS reference samples. Chem. Geol. 83, 133–148.
Johannesson, K.H., Lyons, W.B., Fee, J.H., Gaudette, H.E., and McArthur, J.M. 1994. Geochemical processes affecting the acidic ground waters of Lake Gilmore, Yilgarn Block, Western Australia: A preliminary study using neodymium, samarium, and dysprosium. J. Hydrol. 154, 271–289.
Johnnesson, K.H., Stetzenbach, K.J., Hodge, V.F. and Lyons, W.B. 1996a. Rare earth element complexion behavior in circum-neutral pH groundwater: Assessing the role of carbonate and phosphate ions. Earth Planet. Sci. Lett. 139, 305–319.
Johannesson, K., Stetzenbach, K.J., and Hodge, V.F. 1996b. Speciation of the rare earth element neodymium in ground water of the Nevada Test Site and Yucca Mountain and implications on actinide solubility. J. Hydrol. 178, 181–204.
Johannesson, K.H., Stetzenbach, K.J., Hodge, V.F., Kreamer, K., and Zhou, X. 1997a. Delineation of groundwater flow systems in the southern Great Basin using aqueous rare earth element distributions. Ground Water. 35, 807–819.
Johannesson, K.H., Stetzenbach, K.J. and Hodge, V.F. 1997b. Rare earth-elements as geochemical tracers of regional groundwater mixing. Geochim. Cosmochim. Acta. 61, 3605–3618.
Johannesson, K.H., Zhou, X., Guo, X., Stetzenbach, K.J., and Hodge, V.F. 2000. Origin of rare earth element signatures in groundwaters of circumneutral pH from Southern Nevada and Eastern California, USA. Chem. Geol. 164, 239–257.
Kreamer, D.K., Hodge, V.F., Rabinowitz, I., Johannesson, K.H., and Stetzenbach, K.J. 1996. Trace elements geochemistry in water from selected springs in Death Valley National Park, California. Ground Water 34, 95–103.
Long, S.E., and Martin, T.D. 1991. Determination of trace elements in waters and wasters by inductively coupled plasma-mass spectrometry. U.S. Environmental Protection Agency.
Longerich, H.P., Fryer, B. J., Strong, D.F. and Kantipuly, C.J. 1987. Effects of operation conditions on the determination of the rare earth elements by inductively coupled plasma mass spectrometry (ICP-MS). Spectrochimica Acta. 42B, 75–92.
Nadkarni, R.A. 1984. Applications of microwave oven sample dissolution in analysis. Anal. Chem. 56, 2233–2237.
Perkin Elmer 1992. Reference manual ELAN 5000 inductively coupled plasma-mass spectrometer. Norwalk, Connecticut, U.S.A.
Sholkovitz, E.R. 1988. Rare earth elements in the sediments of the North Atlantic Ocean, Amazon Delta, and East China Sea: Reinterpretation of terrigenous input patterns to the ocean. Am. J. Sci. v. 288, 236–281.
Smedley, P.L. 1991. The geochemistry of rare earth elements in ground water from the Carnmenellis area, Southwest England. Geochim. Cosmochim. Acta. 55, 2767–2779.
Starik I. E., and Kolyadin, L. B. 1957. The occurrence of uranium in ocean water. Geochemistry 3, 245–256.
Stetzenbach, K.J., Amano, M., Kreamer, D.K., and Hodge, V.F. 1994. Testing the limits of ICP-MS: Determination of trace elements in ground water at the part-per-trillion level. Ground Water 32, 976–985.
Stetzenbach, K.J., Farnham, I.M., Hodge, V.F., and Johannesson, K.H. 1999. Using multivariate statistical analysis of groundwater flow in a regional aquifer. Hydrol. Processes. 13, 2655–2673.
Stetzenbach, K,J., Hodge, V.F., Guo, X., Farnham, I.M., and Johannesson, K.H. 2001. Geochemical and statistical evidence of deep carbonate groundwater within overlying volcanic rock aquifers/ aquitards of Southern Nevada, USA. J. Hydrol. 243, 254–271.
Thomas, J.M., Welch, A.H., and Preissler, A.M. 1989. Geochemical evolution of ground water in Smith Creek Valley-A hydrologically closed basin in central Nevada, USA. Appl. Geochem. V. 4, 493–510.
Totland, M.M., Jarvis, I., and Jarvis, K.E. 1992. An assessment of dissolution techniques for the analysis of geological samples by plasma spectrometry. Chem. Geol. 95, 35–64.
Totland, M.M., Jarvis, I., and Jarvis, K.E. 1995. Microwave digestion and alkali, fusion procedures for the determination of the platinum-group elements and gold in geological materials by Welch, A.H., Lico, M.S. and Hughes, J.L. 1988 Arsenic in ground water of the western United States. Ground Water. 26, 333–347.
White, A.F., Classen, H.C., and Benson, L.V. 1980. The effect of dissolution of volcanic blass on the water chemistry in a tuffaceous aquifer, Rainier Mesa, Nevada. U.S. Geol. Surv. Water Supply Pap. 2535, 34 pp.
Winograd, I.J., and Friedman, I. 1972. Deuterium as a tracer of groundwater flow, southern Great Basin, Nevada and California. Geol. Soc. Am. Bull. 83, 3691–3708.
Winograd, I.J. and Thordarson, W. 1975. Hydrogeologic and hydrochemical framework, south-central Great basin, Nevada, California, with special reference to the Nevada Test Site, U.S. Geol. Surv. Prof. Pap. 712-C, 125 pp.
Winograd, I.J. and Pearson, R.J. 1976. Major carbon-14 anomaly in a regional carbonate aquifer: possible evidence for megascale channeling, south central Great Basin. Water Resours. Res. 12, 1125–1143.
Wood, S.A. and Vlassopoulos, D. 1990. The dispersion of Pt, Pd and Au in surficial media about two PGE-Cu-Ni prospects in Quebec. Can. Mineral. 28, 649.
Wood, S.A., Mountain, B.A., and Pan, P. 1992. The aqueous geochemistry of platinum, palladium, and gold: Recent experimental constraints and a re-evaluation of theoretical predictions. Can. Mineral. 30, 955.
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Guo, C., Stetzenbach, K.J., Hodge, V.F. (2005). Determination of 56 Trace Elements in Three Aquifer- Type Rocks by ICP-MS and Approximation of the Relative Solubilities for These Elements in a Carbonate System by Water-Rock Concentration Ratios. In: Johannesson, K.H. (eds) Rare Earth Elements in Groundwater Flow Systems. Water Science and Technology Library, vol 51. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3234-X_2
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DOI: https://doi.org/10.1007/1-4020-3234-X_2
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