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New Challenges in Superconductivity: Experimental Advances and Emerging Theories pp 69–72Cite as

Exploring the Oxygen Order in Hg -1223 and Hg -1201 by 199Hg Mas Nmr

Part of the NATO Science Series II: Mathematics, Physics and Chemistry book series (NAII,volume 183)

Abstract

We demonstrate the use of a high-resolution solid-state fast (45 kHz) magic angle spinning (MAS) NMR for mapping the oxygen distribution in Hg-based cuprate superconductors. We identify observed three peaks in 199Hg spectrum as belonging to the different chemical environments in the HgOδ layer with no oxygen neighbors, single oxygen neighbor, and two oxygen neighbors. We discuss observed differences between Hg-1201 and Hg-1223 materials.

Key words

  • 199Hg NMR
  • MAS
  • High-Tc superconductors
  • oxygen order

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Author information

Authors and Affiliations

  1. National Institute of Chemical Physics and Biophysics (NICPB), 12618, Tallinn, Estonia

    Raivo Stern & Ivo Heinmaa

  2. Department of Inorganic Chemistry, Arrhenius Laboratory, SE-10691, Stockholm, Sweden

    Dmitriy A. Pavlov & Ingrid Bryntse

Authors
  1. Raivo Stern
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  2. Ivo Heinmaa
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  3. Dmitriy A. Pavlov
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  4. Ingrid Bryntse
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Editor information

Editors and Affiliations

  1. University of Miami, FL, USA

    J. Ashkenazi , Joshua L. Cohn  & Fulin Zuo ,  & 

  2. Kazan State University, Kazan, Russian Federation

    Mikhail V. Eremin

  3. Freie Universität Berlin, Germany

    Ilya Eremin

  4. Max-Planck-Institute for Solid State Research, Stuttgart, Germany

    Dirk Manske

  5. EPFL, Institute of Physics of Complex Matter, Lausanne, Switzerland

    Davor Pavuna

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© 2005 Springer

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Stern, R., Heinmaa, I., Pavlov, D.A., Bryntse, I. (2005). Exploring the Oxygen Order in Hg -1223 and Hg -1201 by 199Hg Mas Nmr. In: Ashkenazi, J., et al. New Challenges in Superconductivity: Experimental Advances and Emerging Theories. NATO Science Series II: Mathematics, Physics and Chemistry, vol 183. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3085-1_12

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