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Nonlinear Dielectric Losses and Dynamics of Intrinsic Conductivity of Dielectrics

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Nonlinear Dielectric Phenomena in Complex Liquids

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 157))

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Abstract

The phenomenological approach to dynamics of the intrinsic electric conductivity of dielectrics in the electric field was used for analyzing the respective contribution to dielectric losses. The proposed differential equation contains only two parameters — the effective time τ F of conductivity decay in electric field, and time τ R describing the rate of conductivity recovery after switching field off. The proposed approach predicts the linear dependence of specific conductivity of dielectrics on the sample thickness experimentally confirmed by Du Pont [1] for Teflon FEP. The field, time and frequency dependences of intrinsic conductivity G(t,ω,E and related dependences of dielectric losses component ε”(ωE) was calculated, analyzed and illustrated by published experimental data.

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References

  1. Małecki, J. (1976) Investigation of tautomeric A-H...B↔A...H-B equilibrium by linear and non-linear dielectric polarization, J. Chem. Soc. Faraday Trans. II, 72, 1214–1220.

    Article  Google Scholar 

  2. Małecki, J. (1976) Theory of non-linear dielectric effects in liquids, J. Chem. Soc. Faraday Trans. II, 72, 104–112.

    Article  Google Scholar 

  3. Eigen M., and De Mayer L. (1963) Techniques of Organic Chemistry, in S. L. Fries, E. S. Lewis and A. Wessberger (Eds), Vol. VIII, part 2, Interscience, New York (Eds. S. L. Fries, E. S. Lewis and A. Wessberger, Vol. VIII, part 2)

    Google Scholar 

  4. Małecki, J. and Nowak J, (1999) Intermolecular interactions in benzene solutions of 4-heptyl-3′-cyanobiphenyl studied with non-linear dielectric effects, J. Mol. Liquids 81, 245–252.

    Article  Google Scholar 

  5. Małecki, J. (1988) Non-linear dielectric behavior and chemical equilibria in liquids, Electrochim. Acta 33, 1235–1241.

    Article  Google Scholar 

  6. Małecki, J. and Krowarsch A, (1963) Badanie przewodnictwa elektrycznego cieczy dielektrycznych metodą impulsową PTPN, Prace Kom. Mat.-Przyr, 11, (2), 113–124.

    Google Scholar 

  7. Małecki, J. (1963) Przewodnictwo elektryczne cieczy dielektrycznych w słabym polu elektrycznym. Teoria i porównanie z wynikami doświadczalnymi PTPN, Prace Kom. Mat.-Przyr. 11, (2), 125–136.

    Google Scholar 

  8. Silver, M., (1965), J. Chem. Phys. 42, 1011

    Article  ADS  Google Scholar 

  9. Małecki, J. and Pierański, P. (1976) Thomson model of ion conduction in liquid dielectric. I. Steady state, Acta Phys. Polon. A50, 581–596.

    Google Scholar 

  10. Pierański, P. and Małecki, J. (1976) Thomson model of ion conduction in liquid dielectric. II. Steady states, Acta Phys. Polon. A50, 597–609.

    Google Scholar 

  11. Małecki, J. (1999) Linear decay of charge in electrets, Phys. Rev. B 59, 9954–9960.

    Article  ADS  Google Scholar 

  12. Hilczer, B., and Mał, J. (1986) Electrets, Elsevier, Amsterdam, Oxford, New York, Tokyo.

    Google Scholar 

  13. Du Pont de Nemours Technical Report No. 240670C (unpublished).

    Google Scholar 

  14. Jonscher, A.K., and Frost, M.S. (1976) Thin Solid Films 37, 267–273.

    Article  ADS  Google Scholar 

  15. Jonscher, A.K., Deori, K.L., Reau, J.M., and Moali, J. (1979) J. Materials Science 14, 1308.

    Article  ADS  Google Scholar 

  16. Kułek, J. and Hilczer, B. (1998) Dielectric, piezoelectric and pyroelectric response of PbTiO3-PVDF composites, J. Korean Physical Society 32, S1079–S1081.

    Google Scholar 

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© 2004 Kluwer Academic Publishers

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Małecki, J.A. (2004). Nonlinear Dielectric Losses and Dynamics of Intrinsic Conductivity of Dielectrics. In: Rzoska, S.J., Zhelezny, V.P. (eds) Nonlinear Dielectric Phenomena in Complex Liquids. NATO Science Series II: Mathematics, Physics and Chemistry, vol 157. Springer, Dordrecht. https://doi.org/10.1007/1-4020-2704-4_9

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