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Heterometallic Fullerides of Transition Metals with the Composition K2MC60

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Hydrogen Materials Science and Chemistry of Carbon Nanomaterials

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 172))

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Abstract

Heterometallic fullerides with composition K2C60, synthesized by exchange chemical reaction of K5C60 or K4C60 with chlorides of metals Fe and Cu groups have been investigated by X-ray diffraction, magnetic resonance, Raman and Mössbauer spectroscopy. Magnetization and susceptibility measurements also have been carried out. Metal chlorides from Fe and Cu groups enable to cover the whole range of electronic configuration of metal from d1 to d10. Heterometallic fullerides with M=Cu+2, Fe+2, Fe+3, V+2, Cr+3 and Ni+2 appeared to be superconductors with Tc=13.9–16.5K.

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Author information

Authors and Affiliations

  1. Department of Physics, Moscow State University, 119992, GSP-2, Moscow, Russia

    V. A. Kulbachinskii, R. A. Lunin, A. V. Krechetov & V. G. Kytin

  2. Department of Chemistry, Moscow State University, 119992, GSP-2, Moscow, Russia

    B. M. Bulychev & K. V. Poholok

  3. Abteilung Silizium-Photovoltaik, Hahn-Meitner-Institute, D-12489, Berlin, Germany

    K. Lips & J. Rappich

Authors
  1. V. A. Kulbachinskii
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  2. B. M. Bulychev
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  3. R. A. Lunin
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  4. A. V. Krechetov
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  5. V. G. Kytin
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  6. K. V. Poholok
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  7. K. Lips
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  8. J. Rappich
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Editor information

Editors and Affiliations

  1. International Association for Hydrogen Energy, University of Miami, FL, USA

    T. Nejat Veziroglu

  2. Institute of Hydrogen and Solar Energy, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko

  3. Institute for Problems of Materials Science of NAS, Kiev, Ukraine

    Dmitry V. Schur  & Valeriy V. Skorokhod  & 

  4. Institute of Physical Chemistry of PAS, Warsaw, Poland

    B. Baranowski

  5. Institute for Metal Physics of NAS, Kiev, Ukraine

    Anatoliy P. Shpak

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© 2004 Kluwer Academic Publishers

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Kulbachinskii, V.A. et al. (2004). Heterometallic Fullerides of Transition Metals with the Composition K2MC60 . In: Veziroglu, T.N., Yu. Zaginaichenko, S., Schur, D.V., Baranowski, B., Shpak, A.P., Skorokhod, V.V. (eds) Hydrogen Materials Science and Chemistry of Carbon Nanomaterials. NATO Science Series II: Mathematics, Physics and Chemistry, vol 172. Springer, Dordrecht. https://doi.org/10.1007/1-4020-2669-2_19

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