Abstract
Modeling photocatalytic reaction processes requires careful consideration of reaction and adsorption phenomena. In order to establish the importance of these matters, experiments can be developed using model pollutants such as methylene blue, phenol, 2-chlorophenol, 2,4-dichlorophenol, catechol (or 1,2 benzenediol), and pyrogallol (or 1,2,3 benzenetriol), each having quite different behaviours of adsorption and reaction.
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References
Al-Ekabi, H. and Serpone, N., 1988, Kinetic studies in heterogeneous photocatalysis. 1. Photocatalytic degradation of chlorinated phenols in aerated aqueous solutions over TiO2 supported on a glass matrix, J. Phys. Chem., 92: 5726–5731.
Al-Sayyed, G., D’Oliveira, J. C. and Pichat, P., 1991, Semiconductor — sensitized phot-degradation of 4chlorophenol in water, J. Photochem. Photobiol. A: Chem., 58: 99–114.
Barbeni, M., Pramauro, E., Pelizzetti, E., Borgarello, E., Serpone, N., 1985, Photodegradation of pentachlorophenol catalyzed by semiconductor particles. Chemosphere, 14 (2): 195–208.
Dean, A.J., 1985, Lange’s handbook of chemistry. McGraw Hill Company, 13th Edition, p.18.
Gerischer, H. and Heller, A., 1991, The role of oxygen in photooxidation of organic molecules on semiconductor particles. J. Phys. Chem., Vol. 95 (13): 5261–5267.
Ku, Y., Leu, R. M. L., and Kuen C., 1996, Decomposition of 2-chlorophenol in aqueous solution irradiation with the presence of titanium dioxide. Wat. Res., 30: 2569–2578.
Lide, D.R., 1997, CRC handbook of chemistry and physics, CRC Press, 78th Edition, p.43.
Matthews, R. W., 1989, Photocatalytic oxidation and adsorption of methylene blue on thin films of nearultraviolet-illuminated Ti02. J. Chem. Soc., Faraday Trans. 1, 85 (6): 1291–1302.
Okamoto, K., Yamamoto, Y., Tanaka, H., Itaya, A., 1985, Kinetics of heterogeneous photocatalytic decomposition of phenol over anatase 1102 powder. Bull. Chem. Soc. Japan, Vol. 58: 2023–2028.
Salaices, M., Serrano, B. and de Lasa, H., 2001, Photocatalytic conversion of organic pollutants: extinction coefficients and quantum efficiencies. Ind. & Eng. Chem. Res., 40: 5455–5464.
Sehili, T., Boule, P. and Lemaire, J., 1989, Photocatalyzed transformation of chloroaromatic derivatives on zinc oxide III: chlorophenols. J. Photochem. Photobiol. A: Chem., 50: 117–127.
Serrano, B., 1998, Photocatalytic degradation of organic water pollutants: energy efficiency and kinetic modelling, PhD Dissertation, The University of Western Ontario.
Serrano, B. and de Lasa, H., 1997, Photocatalytic degradation of water organic pollutants. kinetic modeling and energy efficiency. Ind. & Eng. Chem. Res., 36: 4705–4711.
Serrano, B. and de Lasa, H, 1999, Photocatalytic degradation of water organic pollutants: pollutant reactivity and kinetic modeling. Chem. Eng. Sci., 54: 3063–3069.
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de Lasa, H., Serrano, B., Salaices, M. (2005). Water Decontamination of Organic Species: Modeling Reaction and Adsorption Processes. In: Photocatalytic Reaction Engineering. Springer, Boston, MA. https://doi.org/10.1007/0-387-27591-6_7
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DOI: https://doi.org/10.1007/0-387-27591-6_7
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4419-3627-1
Online ISBN: 978-0-387-27591-8
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