Skip to main content
SpringerLink
Log in
Book cover

Gas Adsorption Equilibria pp 287–357Cite as

Impedance Spectroscopy

  • Chapter

Abstract

The physical principles and basic experimental techniques of impedance spectroscopy, i. e. static or frequency dependent dielectric permittivity measurements of sorbent/sorbate systems are given. These measurements can be used to characterize the state of a sorbent material in industrial adsorption processes. Combined with either manometric or gravimetric measurements of adsorption equilibria leading to calibration curves, permittivity measurements also allow fairly simple and quick measurements of gas adsorption equilibria. Kinetic processes and catalytic reactions inside a sorbent/sorbate system also can be observed. Pros and cons of dielectric measurements are discussed. List of Symbols. References.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Jackson J. D. Classical Electrodynamics John Wiley & Sons, New York, 2nd Ed., 1975 Klassische Elektrodynamik, W. de Gruyter, Berlin-New-York, 1993.

    Google Scholar 

  2. Bötcher C. J. F. Theory of Electric Polarization, Vols. 1, 2, Elsevier, 2nd Ed. Amsterdam, 1973.

    Google Scholar 

  3. Staudt R. Gasadsorption, Ingenieurwissenschaftliche Grundlagen, Messmethoden zur Bestimmung und Modelle zur Beschreibung von Adsorptionsgleichgewichten reiner Gase und Gasgemische an poröen Stoffen, Habilitationsschrift, IFT, University of Siegen, Siegen, 2000.

    Google Scholar 

  4. Doll Th., Editor Advanced Gas Sensing — The Electroadsorptive Effect and Related Techniques, Kluwer, Dordrecht etc., 2003.

    Google Scholar 

  5. Grimnes S., Martinsen O. G. Bioimpedance and Bioelectricity Basics, Academic Press, New York etc., 2000.

    Google Scholar 

  6. Macdonald J. R. Impedance Spectroscopy, Emphasizing solid materials and systems, J. Wiley & Sons, New York etc., 1987.

    Google Scholar 

  7. Rost A. Messung dielektrischer Stoffeigenschaften, Vieweg, Braunschweig, 1978.

    Google Scholar 

  8. Dohrmann St. Charakterisierung von poröen Stoffen mit Hilfe der Impedanzspektroskopie, Diploma-Thesis, IFT, University of Siegen, Siegen, 1997.

    Google Scholar 

  9. Channen E. W., McIntosh R. Investigation of the Physically Adsorbed State by Means of Dielectric Measurements, Canad. J. Chem., 33 (1955), p. 172.

    Article  CAS  Google Scholar 

  10. Staudt R., Rave H., Keller J. U. Impedance Spectroscopic Measurements of Pure Gas Adsorption Equilibria on Zeolites, Adsorption, 5 (1999), p. 159–167.

    Article  CAS  Google Scholar 

  11. Geis S., Müller B., Fricke J. The Response Function Method as a Novel Technique to Determine the Dielectric Permittivity of Highly Porous Materials, Studies in Suface Science and Catalysis, Vol. 128, p. 545–555, K. Unger et al., Eds., Elsevier Science B. V., Amsterdam etc., 2000.

    Google Scholar 

  12. Cauer W. Theorie der linearen Wechselstromschaltungen, Springer, Berlin etc., 1954.

    Google Scholar 

  13. Staudt R., Saller G., Tomalla M., Keller J. U. Electro-gravimetric measurements of binary coadsorption equilibria, Characterization of Porous Solids III (COPS III), Studies in Surface Science and Catalysis, Vol. 87, p. 345–351, Elsevier Science B. V., Amsterdam etc., 1994.

    Google Scholar 

  14. Staudt R., Kramer S., Dreisbach F., Keller J. U. Impedance Spectroscopic Measurements of Breakthrough Curves, Fundamental of Adsorption 6, Proceedings of FoA 6 Conference, May 1998, Giens, p. 153–158, Meunier, Ed., Elsevier, Paris, 1998.

    Google Scholar 

  15. Staudt R., Ohm M., Lör M., Keller J. U. Impedanzspektroskopische Untersuchungen von Adsorptionsgleichgewichten zur Optimierung von technischen Adsorbern, Chemie Ingenieur Technik (CIT) 10 (2002), p. 1410–1413.

    Article  Google Scholar 

  16. Kestin J. A Course in Thermodynamics, Vols. I, II, Blaisdell Publ. Comp., London, 1968.

    Google Scholar 

  17. Keller J. U. Thermodynamik der irreversiblen Prozesse mit Aufgaben, Rechenweg und Löungen, Teil I: Thermodynamik und Grundbegriffe, Kap. A 14, W. de Gruyter, Berlin — New York, 1977.

    Google Scholar 

  18. Michels W., Keller J. U. Elektrogravimetrische Untersuchung der Adsorption von reinem Stickstoff und Stickstoff-Wasser-Gemischen bei Umgebungstemperatur im Druckbereich 0, 1–12 MPa an Molekularsieben und Aktivkohle, Diploma-Thesis, IFT, University of Siegen, Siegen, 1988.

    Google Scholar 

  19. Fischer M., Keller J. U. Elektrogravimetrische Untersuchung von Adsorptionsgleichgewichten von reinem Argon und Argon-Wasser-Gemischen an Molekularsieben und Aktivkohle, Diploma-Thesis, IFT, University of Siegen, Siegen, 1988.

    Google Scholar 

  20. Gray D. E., Editor American Institute of Physics Handbook, Mc Graw Hill, New York etc., 1990.

    Google Scholar 

  21. Landolt-Bönstein Zahlenwerte und Funktionen der Physik etc., Springer, Berlin etc., 1980 etc.

    Google Scholar 

  22. Frohlich H. Theory of Dielectrics, Dielectric Constant and Dielectric Loss, Oxford Science Publ., Oxford, UK, Reprint 1986.

    Google Scholar 

  23. Deutsches Institut für Normung e. V. (DIN) Einheiten und Begriffe für physikalische Gröen (AEF-Taschenbuch 1) DIN-Taschenbuch 22, Beuth-Verlag, Berlin etc., 7. Aufl., 1990.

    Google Scholar 

  24. Kohlrausch F. Praktische Physik, D. Hahn, S. Wagner, Eds., Vol. 2, 23rd Ed., B. G. Teubner, Stuttgart, 1985.

    Google Scholar 

  25. Keller J. U., Zimmermann W., Schein A. Determination of Absolute Gas Adsorption Isotherms by Combined Calorimetric and Dielectric Measurements, Adsorption, 9 (2003), p. 177–188.

    Article  CAS  Google Scholar 

  26. Ohm M. Impedanzspektroskopische Untersuchungen von Adsorptionsgleichgewichten reiner Gase, Gasgemischen und feuchter Luft an poröen Stoffen, Diploma-Thesis, IFT, University of Siegen, Siegen, 2000.

    Google Scholar 

  27. Köig H., Meixner J. Linear Passive Transformationen, Math. Nachrichten, 19 (1958), 265.

    Google Scholar 

  28. Köig H. Archiv für Mathematik, 10 (1959), 447.

    Article  Google Scholar 

  29. Meixner J., J. Appl. Mech., 33 (1966), 481.

    Google Scholar 

  30. Keller J. (U.) Über Linear Passive Transformationen Stochastischer Prozesse I, II Zeitschrift für Naturforschung, 23 a (1968), p. 1430; 24 a (1969), p. 716.

    Google Scholar 

  31. Coelho R. Physics of Dielectrics for the Engineer, Elsevier Science Publishers B. V., Amsterdam, 1979.

    Google Scholar 

  32. Meixner J. Network Theory in its Relation to Thermodynamics, Proc. Symp. on Generalized Networks, New York, 1966; Vol. XVI of the Microwave Research Institute Symposia Series, Polytechnic Press of the Polytechnic Institute of Brooklyn, N. Y., 1966.

    Google Scholar 

  33. Mandelbrot B. B. The Fractal Geometry of Nature, W. H. Freeman & Co., New York, 1977 etc.

    Google Scholar 

  34. Bunde A., Havlin Sh. (Eds.) Fractals and Disordered Systems, Springer, Berlin etc., 1991.

    Google Scholar 

  35. Staudt R. „Analytische und experimentelle Untersuchungen von Adsorptionsgleichgewichten von reinen Gasen und Gasgemischen an Aktivkohlen und Zeolithen.“, PHD-Thesis, IFT, University of Siegen, Siegen, 1994.

    Google Scholar 

  36. Kramer St. Messung und Korrelation von Durchbruchskurven an einer PSA-Anlage mit Hilfe der Impedanzspektroskopie Diploma-Thesis, IFT, University of Siegen, Siegen, 1998.

    Google Scholar 

  37. Keller J. U., Schmidt O., Michels W., Fischer M., Seelbach M., Staudt R. Influence of Water on Adsorption Kinetics and Equilibria of Ar, N 2 , and CO on Zeolite and Molecular Sieve, Proceedings Conf. “Fundamentals of Adsorption 7”, Nagasaki, May 2001, K. Kaneko et al., Eds., p. 594–600, IAS, IK International, Chiba, 2002.

    Google Scholar 

  38. Kienle H. von, Bäer E. Aktivkohle und ihre industrielle Anwendung F. Enke Verlag, Stuttgart, 1980.

    Google Scholar 

  39. Stoeckli H. F. Microporous Carbons and their Characterization: The Present State of the Art, Carbon, 28 (1990), p. 1–6.

    Article  CAS  Google Scholar 

  40. Mersmann A. Adsorption, 3.2 Carbon Adsorbents, article in ULLMANN’S Encyclopedia of Industrial Chemistry, Release 2001, 6th Ed., Wiley-VCH, Weinheim etc., 2001.

    Google Scholar 

  41. Yang R. T. Adsorbents, Fundamentals and Applications, Wiley-Interscience, Hoboken, New Jersey, 2003.

    Google Scholar 

  42. Dorf R. C., Svoboda J. A. Introduction to Electric Circuits, Wiley Interscience, 6th Ed., Chichester, London, New York etc., 2004.

    Google Scholar 

  43. Schwarzer R., Rave H., Staudt R., Keller J. U. Messung von Sorptionsgleichgewichten von CO2 an Polymeren, part of Diploma-Thesis, IFT, University of Siegen, Siegen, 1999.

    Google Scholar 

  44. Ruthven D. M. Principles of Adsorption and Adsorption Processes, J. Wiley & Sons, New York etc., 1984.

    Google Scholar 

  45. Bathen D., Breitbach M. Adsorptionstechnik, VDI-Buch, Springer, Berlin, New York etc., 2001.

    Google Scholar 

  46. Ruthven D. M., Shamsuzzaman F., Knaebel K. S. Pressure Swing Adsorption, VCH Publishers, New York, Weinheim, 1994.

    Google Scholar 

  47. Gummersbach M., Staudt R., Keller J. U. Impedanzspektroskopische Untersuchungen von poröen Stoffen und deren Adsorbat, Diploma-Thesis, IFT, University of Siegen, Siegen, 1999.

    Google Scholar 

Download references

Rights and permissions

Reprints and permissions

Copyright information

© 2005 Springer Science + Business Media, Inc.

About this chapter

Cite this chapter

(2005). Impedance Spectroscopy. In: Gas Adsorption Equilibria. Springer, Boston, MA. https://doi.org/10.1007/0-387-23598-1_7

Download citation

Publish with us

Policies and ethics

Search

Navigation