Hydrogen Bond Scalar Couplings — A New Tool In Biomolecular NMR

  • Stephan Grzesiek
  • Florence Cordier
  • Andrew J. Dingley
Part of the Biological Magnetic Resonance book series (BIMR, volume 20)


This chapter gives a summary of the recent findings on electron-mediated scalar couplings across hydrogen bonds. The main emphasis is put on a discussion of the various types and sizes of such couplings which have been detected in biological macromolecules. Various experimental schemes for the detection of H-bond couplings are summarized and possible applications are suggested.


Scalar Coupling Radio Frequency Pulse Proton Chemical Shift Imino Proton Selective Pulse 
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Copyright information

© Kluwer Academic Publishers 2002

Authors and Affiliations

  • Stephan Grzesiek
    • 1
  • Florence Cordier
    • 1
  • Andrew J. Dingley
    • 2
    • 3
  1. 1.Department of Structural Biology, BiozentrumUniversity of BaselBaselSwitzerland
  2. 2.Institute of Physical BiologyHeinrich-Heine-UniversitätDüsseldorfGermany
  3. 3.Institute of Structural Biology, IBI-2Forschungszentrum JülichJülichGermany

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