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Composite Materials Derived from Oxovanadium Sulfates

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Polyoxometalate Chemistry for Nano-Composite Design

Part of the book series: Nanostructure Science and Technology ((NST))

Conclusion

The molecular and solid systems described here represent an interesting class of compounds. [V IV 2 O 2 (OH) 2 (SO 4 )(2,2′-bipyridine) 2 ] and [V IV 2 O 2 (SO 4 ) 2 (2,2′-bipyridine) 2 ] constitute the examples of fully reduced oxovanadium sulfate based hybrid materials with novel extended structures. Their preparations appear to be a significant step towards the development of V/O/SO 4 /organic ligand systems and its potential in providing new materials. These results point out that a large number of oxovanadium sulfate phases incorporating organic ligands with novel structures remain to be discovered. The results also suggest that use of robust rod like organic ligands may lead to the formation of V/O/SO4 2−/organic based composites with three-dimensional structures. Some of these possibilities are being explored in our laboratories and the outcome of this effort will be published elsewhere.

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Authors and Affiliations

  1. Department of Biological, Chemical, and Physical Sciences, Illinois Institute of Technology, Chicago, IL, 60616, USA

    M. Ishaque Khan & Sabri Cevik

  2. Department of Chemistry, University of California, Irvine, CA, 92697, USA

    Robert J. Doedens

Authors
  1. M. Ishaque Khan
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  2. Sabri Cevik
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  3. Robert J. Doedens
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Editor information

Editors and Affiliations

  1. Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama, Japan

    Toshihiro Yamase

  2. Department of Chemistry, Georgetown University, Washington, DC, USA

    Michael T. Pope

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© 2002 Kluwer Academic Publishers

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Khan, M.I., Cevik, S., Doedens, R.J. (2002). Composite Materials Derived from Oxovanadium Sulfates. In: Yamase, T., Pope, M.T. (eds) Polyoxometalate Chemistry for Nano-Composite Design. Nanostructure Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/0-306-47933-8_3

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  • DOI: https://doi.org/10.1007/0-306-47933-8_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-306-47359-3

  • Online ISBN: 978-0-306-47933-5

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