Abstract
New 17O NMR, potentiometry and ESI-MS measurements on aqueous peroxomolybdates and peroxotungstates reveal many new species, including diperoxo hepta-anions and also confirm other proposals based on potentiometry alone, such as a monoperoxo monomer. They also show the presence of many anions previously identified only in the solid state, including both forms of the Mo 2 (peroxide) 4 anion. Comparison with recent work on peroxovanadates and peroxoniobates shows a marked preference in all cases for each metal atom to be coordinated to two peroxo ligands. Peroxotungstates, like tungstates themselves, are generally more complex than peroxovanadates and -molybdates.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
V. Nardello, J. Marko, G. Vermeersch and J. M. Aubry: Inorg. Chem. 37, 5418 (1998).
V. Conte: J. Inorg. Biochem. in press(1999)
B. Sels, D. De Vos, M. Buntinx, F. Pierard, A. K.-D. Mesmaeker and P. Jacobs: Nature 400, 855 (1999).
C. Djordevic and G. L. Wampler: J. Inorg. Bioch. 25, 51 (1985).
L. Pettersson, I. Andersson, S. Angus-Dunne and O. W. Howarth: J. Inorg. Biochem. in press(1999)
O. W. Howarth and J. R. Hunt: J. C. S. Dalton Trans: 1388 (1979).
A. T. Harrison and O. W. Howarth: J. C. S. Dalton Trans. 1173 (1985).
O. W. Howarth: Prog. NMR Spectroscopy 22, 453 (1991).
R. E. Drew and F. W. B. Einstein: Inorg. Chem. 11, 829 (1972)
R. Stomberg: Acta Chem. Scand. 23, 2755 (1969).
F. Taube, M. Hashimoto, I. Andersson and L. Pettersson: in press (1999)
O. W. Howarth, P. Kelly and L. Pettersson: J. C. S. Dalton Trans. 81 (1990).
O. W. Howarth, L. Pettersson and I. Andersson: J. C. S. Dalton Trans. 1799 (1991).
N. J. Campbell, A. C. Dengel, C. J. Edwards and W. P. Griffith: J. Chem. Soc. Dalton Trans. 1203 (1989).
N. M. Gresley, W. P. Griffith, A. C. Laemmel, H. I. S. Noguiera and B. C. Parkin: J. Mol. Catalysis A117, 185 (1997).
C. B. Shoemaker, D. P. Shoemaker, L. V. McAfee and C. W. DeKock: Acta Cryst. C 41, 347 (1985).
R. Stomberg: Acta Chem. Scand. 22, 1076 (1968).
L. Trysberg and R. Stomberg: Acta Chem. Scand. A 35, 823 (1981).
R. Stomberg, L. Trysberg and I. Larking: Acta Chem. Scand. 24, 678 (1970).
I. Persdotter, L. Trysberg and R. Stomberg: Acta Chem. Scand. A 40, 335 (1986).
I. Persdotter, L. Trysberg and R. Stomberg: Acta Chem. Scand. A 40, 1 (1986).
I. Persdotter, L. Trysberg and R. Stomberg: Acta Chem. Scand. A 40, 83 (1986).
R. Stomberg: Acta Chem. Scand. 23, 2755 (1969).
J.-M. Le Carpentier, A. Mitchler and R. Weiss: Acta Cryst. B 28, 1288 (1972).
E. Heath and O. W. Howarth: J. C. S. Dalton Trans. 1105 (1981).
R. Stomberg: Acta Chem. Scand. A 39, 507 (1985).
R. Stomberg: J. Less Common Metals. 143, 363 (1988).
F. W. B. Einstein and B. R. Penfold: Acta Cryst. A35, 16 (supplement) (1963).
O. W. Howarth and P. Kelly: J.C.S.Chem. Comm. 1236 (1988).
O. W. Howarth and J. J. Hastings: J. C. S. Dalton Trans. 209 (1992).
O. W. Howarth, I. Andersson, J. J. Hastings and L. Pettersson: J. Chem. Soc. Dalton Trans. 2705 (1996).
M. J. Deery, O. W. Howarth and K. R. Jennings: J. C. S. Dalton Trans. 4783 (1997).
M. J. Deery, T. Fernandez, O. W. Howarth and K. R. Jennings: J. C. S., Dalton Trans. 2177 (1998).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2001 Kluwer Academic Publishers
About this chapter
Cite this chapter
Howarth, O.W., Pettersson, L., Andersson, I. (2001). Aqueous Peroxoisopolyoxometalates. In: Pope, M.T., Müller, A. (eds) Polyoxometalate Chemistry From Topology via Self-Assembly to Applications. Springer, Dordrecht. https://doi.org/10.1007/0-306-47625-8_11
Download citation
DOI: https://doi.org/10.1007/0-306-47625-8_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-7011-6
Online ISBN: 978-0-306-47625-9
eBook Packages: Springer Book Archive