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Construction of Microporous Materials from Molecular Building Blocks

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Access in Nanoporous Materials

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References

  1. O.M. Yaghi, A. Sun, D.A. Richardson, and T.L. Groy, Directed transformation of molecules to solids: synthesis of a microporous sulfide from molecular germanium sulfide cages, J. Am. Chem. Soc. 116:807 (1994). (b) T. Jiang, G.A. Ozin, and R.L. Bedard, Nanoporous tin(IV) sulfides: mode of formation, Adv. Mater. 6:860 (1994). (c) J.B. Parise, An antimony sulfide with a two-dimensional, intersecting system of channels, Science 251:293 (1991). (d) R.L. Bedard, S.T. Wilson, L.D. Vail, J.M. Bennett, E.M. Flanigen, The next generation: synthesis, characterization, and structure of metal sulfide-based microprous solids. in: “Zeolites: Facts, Figures, Future,” P.A. Jacobs and R.A. van Santen, eds., Elsevier, Amsterdam (1989).

    Article  CAS  Google Scholar 

  2. O.M. Yaghi and G. Li, Presence of mutually interpenetrating sheets and channels in the extended structure of Cu(4,4′-bipyridine)C1, Angew. Chem., Int. Ed. Engl. 207 (1995). (b) O.M. Yaghi, G. Li, and TL. Groy, Conversion of hydrogen-bonded Mn(II) and Zn(II) squarate molecules, chains and sheets to 3-D cage networks, J. Chem. Soc.. Dalton Trans. 727 (1995). (c) K.-M. Park and T. Iwamoto, Urea-and thiourea-like host structures of catena-[(1,2-diaminopropane)-cadmium(II) tetra-Ecyanonickelate(II)] accommodating aliphatic guests, J. Chem. Soc., Chem. Commun. 72 (1992). (b) B.F. Abrahams, BF. Hoskins, J. Liu, and R. Robson, The archetype for a new class of simple extended 3D honeycomb frameworks. The synthesis and x-ray crystal structures of Cd(CN)5/3(OH)1/3.1/3(C6H12N4), Cd(CN)2.1/3(C6H12N4), and Cd(CN)2.2/3H2O.tBuOH (C6H12N4 = hexamethylenetetramine) revealing two topologically equivalent but geometrically different frameworks, J. Am. Chem. Soc. 113:3045 (1991). (e) A. Weiss, E. Riegler, and C. Robl, Transition metal uarates, II: On the structure of cubic (MC4O4.2H2O)3.CH3COOH.H2O (M = Zn2+, Ni2+), Z. Naturforsch. 41b 1329 (1986).

    Google Scholar 

  3. M.R. Ghadiri, J.R. Granja, R.A. Milligan, D.E. McRee, and N. Khazanovich, Self-assembling organic nanotubes based on a cyclic peptide architecture, Nature 366:324 (1993).

    Article  CAS  Google Scholar 

  4. O.M. Yaghi, G. Li, and T.L. Groy, Preparation of single crystals of coordination solids in silica gels: synthesis and structure of Cu11(1,4-C4H4N2)(C4O4)(OH2)4, J. Solid State Chem., in press (1995).

    Google Scholar 

  5. For example:(a) O.M. Yaghi, D.A. Richardson, G. Li, C.E. Davis, and T.L. Groy, Open-framework solids with diamond-like structures prepared from clusters and metal-arganic building blocks, Mater. Res. Soc. Symp. Proc. 15 (1995). (b) L.R. MacGillivray, S. Subramanian, and M.J. Zaworotko, Interwoven two-and three-dimensional coordination polymers through self-assembly of Cu1 cations with linear bidentate ligands, J. Chem. Soc., Chem. Commun. 1325 (1994).

    Google Scholar 

  6. O.M. Yaghi and H. Li, Hydrothermal synthesis of a metal-organic framework containing large rectangular channels, submitted.

    Google Scholar 

  7. O. Ermer, Fivefold-diamond structure of adamantane-1,3,5,7-tetracarboxylic acid, J. Am. Chem. Soc. 110:3747 (1988).

    Article  CAS  Google Scholar 

  8. O. Ermer and L. Lindenberg, Double-diamond inclusion compounds of 2,6-dimethylideneadamantane-1,3,5,7-tetracarboxylic acid, Helvet. Chim. Acta 74:825 (1991).

    CAS  Google Scholar 

  9. X. Wang, M. Simard, and J.D. Wuest, Molecular tectonics. Three-dimensional organic networks with zeolitic properties, J. Am. Chem. Soc. 116:12119 (1994).

    CAS  Google Scholar 

  10. B.F. Hoskins and R. Robson, Design and construction of a new class of scaffolding-like materials comprising infiite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the Zn(CN)2 and Cd(CN)2 structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4] [Cu1Zn11(CN)4] and Cu1[4,4′,4″,4‴-tetracyanotetraphenylmethane]-BF4. x C6H5NO2, J. Am. Chem. Soc., 112:1546 (1990). (b) B.F. Hoskins and R. Robson, Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments, J. Am. Chem. Soc. 111:5962 (1989).

    Article  CAS  Google Scholar 

  11. S.B. Copp, S. Subramanian, and M.J. Zaworotko, Supramolecular chemistry of [Mn(CO)33-OH)]4: assembly of a cubic hydrogen-bonded diamondoid network with 1,2-diaminoethane, J. Am. Chem. Soc. 114:8719 (1992).

    Article  CAS  Google Scholar 

  12. A.F. Wells. “Structural Inorganic Chemistry,” Fifth Ed.. Clarendon Press, Oxford (1984).

    Google Scholar 

  13. T. Kitazawa, S.-i. Nishikiori, R. Kuroda, and T. Iwamoto, Novel clathrate compound of cadmium cyanide host with an adamantane-like cavity. Cadmium cyanide-carbon tetrachloride (1/1), Chem. Lett. 1729 (1988).

    Google Scholar 

  14. S.R. Batten, B.F. Hoskins, and R. Robson, 3D Knitting patterns. Two independent, interpenetrating rutile-related infinite frameworks in the structure of Zn[C(CN)3]2, J. Chem. Soc., Chem. Commun. 445 (1991).

    Google Scholar 

  15. B.F. Abrahams, B.F. Hoskins, D.M. Michall, and R. Robson, Assembly of porphyrin building blocks into network structures with large channels, Nature 369:727 (1994).

    Article  CAS  Google Scholar 

  16. G.B. Gardner, D. Venkataraman, J.S. Moore, and S. Lee, Spontaneous assembly of a hinged coordination network, Nature 374:792 (1995).

    CAS  Google Scholar 

  17. O.M. Yaghi and G. Li, Demonstrated mobility and binding selectivity of inclusions in a microporous metal-organic framework, submitted.

    Google Scholar 

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Yaghi, O.M. (2002). Construction of Microporous Materials from Molecular Building Blocks. In: Pinnavaia, T.J., Thorpe, M.F. (eds) Access in Nanoporous Materials. Fundamental Materials Research. Springer, Boston, MA. https://doi.org/10.1007/0-306-47066-7_8

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  • DOI: https://doi.org/10.1007/0-306-47066-7_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-306-45218-5

  • Online ISBN: 978-0-306-47066-0

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