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Chiral-at-Metal Complexes as Asymmetric Catalysts

  • Marc FontecaveEmail author
  • Olivier Hamelin
  • Stéphane Ménage
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 15)

Abstract

In general, asymmetric catalysts are based on the combination of a chiral organic ligand and a metal ion. Here we show that future research should also focus on complexes in which the chirality resides only at the metal center, as the result of a given topology of coordination of achiral ligands to the metal ion. Here we make a brief presentation of the methods available for preparing such compounds as well as the very few examples of enantioselective reactions catalyzed by chiral-at-metal complexes.

Asymmetric transformation Bipyridine Catalysis Chiral-at-metal Phenanthroline Ruthenium 

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Authors and Affiliations

  • Marc Fontecave
    • 1
    Email author
  • Olivier Hamelin
    • 1
  • Stéphane Ménage
    • 1
  1. 1.Laboratoire de Chimie et Biochimie des Centres Rédox BiologiquesUMR Université J. Fourier-CEA-CNRS no 5047, CEA-Grenoble, DRDC/CBGrenoble Cedex 9France

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