Organolanthoid Chemistry: Synthesis, Structure, Catalysis pp 1-32

Part of the Topics in Current Chemistry book series (TOPCURRCHEM, volume 179) | Cite as

Features of organolanthanide complexes

  • Reiner Anwander
  • Wolfgang A. Herrmann
Chapter

Abstract

The intrinsic properties of the lanthanide elements guarantee promising applications in the fields of catalysis and material science. How to cope with these features on a molecular level and under anaerobic conditions is discussed, including thermodynamic and kinetic considerations. Due to the importance of a prolific metal/ligand synergism, current developments in ligand design are emphasized.

List of symbols and abbreviations

BINOL

binaphthol

CN

coordination number

Cp

η5-cyclopentadienyl

DME

1,2-dimethoxyethane

Diglyme

di-β-methoxyethylether

E

element

hfc

3-(heptafluoropropylhydroxymethylene)-d-camphorato

HSAB

hard soft acid base

Im

imidazole

L

ligand

Ln

lanthanide (Sc, Y, La, Ce-Lu)

MOCVD

metal-organic chemical vapor deposition

Py

pyridine

TBP

tri-n-butylphosphane

Tf

“triflate” ligand, CF3SO3

thd

2,2,6,6-tetramethyl-3,5-heptandionate

THF

tetrahydrofurane

TMEDA

tetramethylethylenediamine

tritox

tri-tert-butyl methoxide

Z

nuclear charge

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Copyright information

© Springer-Verlag 1996

Authors and Affiliations

  • Reiner Anwander
    • 1
  • Wolfgang A. Herrmann
    • 2
  1. 1.Institut für Technische ChemieUniversität StuttgartStuttgartGermany
  2. 2.Anorganisch-Chemisches InstitutTechnische Universität MünchenGarchingGermany

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