Skip to main content

Optimizing Fluoride Removal and Energy Consumption in a Batch Reactor Using Electrocoagulation: A Smart Treatment Technology

  • Conference paper
  • First Online:
Smart Cities—Opportunities and Challenges

Part of the book series: Lecture Notes in Civil Engineering ((LNCE,volume 58))

Abstract

Electrochemical-based approaches have gained much attention as sustainable, eco-friendly and cleaner methods of treatment technologies as they are less sludge producing. The presence of excess fluoride in drinking water supplies is responsible for dental, skeleton and other forms of fluorosis. Among various defluoridation techniques available, electrocoagulation (EC) process was experimentally applied and optimized aiming higher removal efficiency along with minimum energy consumption. Electrocoagulation process was employed at batch scale using both aluminium and iron electrodes, and a comparative assessment was carried out. The effects of initial pH (4–10), applied current (0.2–1.0 A), initial F concentration (5–20 ppm) and reaction time (5–30 min) were explored. The EC reactor was optimized for initial F concentration of 20 ppm, applied current of 0.5 A, pH 6 and reaction time of 20 min using aluminium electrodes giving 97.6% removal efficiency and energy consumption of 0.0195 W hour per gm of fluoride. Operational cost was also analysed, and it was found that among the two, aluminium electrodes outclassed iron electrodes in terms of higher removal efficiency proving cost effective as well.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 349.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 449.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 449.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Khan SU, Zaidi R, Hassan SZ, Farooqi IH, Azam A (2016) Application of Fe–Cu binary oxide nanoparticles for the removal of hexavalent chromium from aqueous solution. Water Sci Technol 741(1):165–175

    Article  Google Scholar 

  2. Nayak B et al (2009) Health effects of groundwater fluoride contamination. Clin Toxicol (Phila) 47(4):292–295

    Article  Google Scholar 

  3. World Health Organization (2006) Fluoride in drinking water

    Google Scholar 

  4. Khan SU, Noor A, Farooqi IH (2015) GIS application for groundwater management and quality mapping in rural areas of District Agra. India. Int J Water Res Arid Env 4(1):89–96

    Google Scholar 

  5. Kumar E, Bhatnagar A, Ji M, Jung W, Lee SH, Kim SJ, Lee G, Song H, Choi JY, Yang JS, Jeon BH (2009) Defluoridation from aqueous solutions by granular ferric hydroxide (GFH). Water Res 43:490–498

    Article  Google Scholar 

  6. Hu CY, Lo SL, Kuan WH, Lee YD (2005) Removal of fluoride from semiconductor wastewater by electrocoagulation–flotation. Water Res 39:895

    Article  Google Scholar 

  7. Mameri N, Yeddou AR, Lounici H, Belhocine D, Grib H, Bariou B (1998) Defluoridation of septentrional Sahara water of north Africa by electrocoagulation process using bipolar aluminium electrodes. Water Res 32:1604–1612

    Article  Google Scholar 

  8. Viswanathan G, Jaswanth A, Gopalakrishnan S, Sivailango S, Aditya G (2009) Determining the optimal fluoride concentration in drinking water for fluoride endemic regions in South India. Sci Total Environ 407(20):5298

    Article  Google Scholar 

  9. Brouwer ID, De Bruin A, Dirks OB, Hautvast JGAJ (1988) Unsuitability of World Health Organisation guidelines for fluoride concentrations in drinking water in Senegal. Lancet 331:223–225

    Article  Google Scholar 

  10. Tor A (2007) Removal of fluoride from water using anion-exchange membrane under Donnan dialysis condition. J Hazard Mater 141:814–818

    Article  Google Scholar 

  11. Wu X, Zhang Y, Dou X, Yang M (2007) Fluoride removal performance of a novel Fe–Al–Ce trimetal oxide adsorbent. Chemosphere 69:1758–1764

    Article  Google Scholar 

  12. Zuo Q, Chen X, Li W, Chen G (2008) Combined electrocoagulation and electroflotation for removal of fluoride from drinking water. J Hazard Mater 159:452–457

    Article  Google Scholar 

  13. Adhoum N, Monser L, Bellakhal N, Belgaied JE (2004) Treatment of electroplating wastewater containing Cu2+, Zn2+ and Cr(VI) by electrocoagulation. J Hazard Mater 112:207–213

    Article  Google Scholar 

  14. Mollah MYA, Morkovsky P, Gomes JAG, Kesmez M, Parga J, Cocke DL (2004) Fundamentals, present and future perspectives of electrocoagulation. J Hazard Mater 114:199–210

    Article  Google Scholar 

  15. Balla W, Essdki AH, Geourich B, Dassaa A, Chenik H, Azzi M (2010) Electrocoagulation/electro-flotation of reactive, disperse and mixture dyes in an external-loop airlift reactor. J Hazard Mater 184:710–716

    Article  Google Scholar 

  16. Drouiche N, Ghaffour N, Lounici H, Mameri M (2007) Electrocoagulation of chemical mechanical polishing wastewater. Desalination 214:31–37

    Article  Google Scholar 

  17. Feng J, Sun Y, Zheng Z, Zhang J, Li S, Tian Y (2007) Treatment of tannery wastewater by electrocoagulation. J Environ Sci 19:1409–1415

    Article  Google Scholar 

  18. Khan SU, Islam DT, Farooqi IH, Ayub S, Basheer F (2019) Hexavalent chromium removal in an electrocoagulation column reactor: process optimisation using CCD, adsorption kinetics and pH modulated sludge formation. Proc Saf Env Prot 122:118–130

    Article  Google Scholar 

  19. Khansorthong S, Hunsom M (2009) Remediation of wastewater from pulp and paper mill industry by the electrochemical technique. Chem Eng J 151:228–234

    Article  Google Scholar 

  20. Shen F, Chen X, Gao P, Chen G (2003) Electrochemical removal of fluoride ions from industrial wastewater. Chem Eng Sci 58:987–993

    Article  Google Scholar 

  21. Hu CY, Lo SL, Kuan WH (2005) Effects of the molar ratio of hydroxide and fluoride to Al(III) on fluoride removal by coagulation and electrocoagulation. J Colloid Interface Sci 283:472–476

    Article  Google Scholar 

  22. Martínez-Miranda V, García-Sánchez JJ, Solache-Ríos M (2011) Fluoride ions behavior in the presence of corrosion products of iron: effects of other anions. Sep Sci Technol 46:1443–1449

    Article  Google Scholar 

  23. Bazrafshan E, Ownagh K, Mahvi AH (2012) Application of electrocoagulation process using Iron and Aluminum electrodes for fluoride removal from aqueous environment. E-J Chem 9(4):2297–2308

    Article  Google Scholar 

  24. Malakootian M, Yousefi N (2009) Efficiency of electrocoagulation process using aluminum electrodes in removal of hardness from water. Iran J Environ Health Sci Eng 6(2):131–136

    Google Scholar 

  25. Aoudj S, Khelifa A, Drouiche N, Belkada R, Miroud D (2015) Simultaneous removal of chromium (VI) and fluoride by electrocoagulation- electroflotation: application of a hybrid Fe–Al anode. Chem Eng J. 267:153–162

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Khan, S.U., Asif, M., Alam, F., Khan, N.A., Farooqi, I.H. (2020). Optimizing Fluoride Removal and Energy Consumption in a Batch Reactor Using Electrocoagulation: A Smart Treatment Technology. In: Ahmed, S., Abbas, S., Zia, H. (eds) Smart Cities—Opportunities and Challenges. Lecture Notes in Civil Engineering, vol 58. Springer, Singapore. https://doi.org/10.1007/978-981-15-2545-2_62

Download citation

  • DOI: https://doi.org/10.1007/978-981-15-2545-2_62

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-2544-5

  • Online ISBN: 978-981-15-2545-2

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics