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A Study on Pyrolysis of Plastic Wastes for Product Recovery and Analysis

  • Ankita MukherjeeEmail author
  • Biswajit Ruj
  • Parthapratim Gupta
  • A. K. Sadhukhan
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Abstract

In this twenty-first century, industrialization, urbanization and modernization have led to rapid generation of waste plastics causing a global concern for safe disposal. Owing to the current trend in plastic waste generation, there is a need to utilize the huge amount of high calorific plastic trash into a valuable source of energy as a solution to the waste disposal cum energy crisis issues. In this context, pyrolysis has been acknowledged as an efficient waste to energy technology degrading waste plastics under anaerobic conditions into oil, gas and char products. The current initiative deals with the study of thermal pyrolysis of waste plastic polyethylene in a batch pyrolyser at an inert environment to recover value-added products followed by their characterization. The plastic waste pyro-feedstock of 100 g shredded low-density polyethylene (LDPE) bags, a significant part of plastic waste stream, was used per batch experiment. Thermo-gravimetric analysis (TGA) was done at different heating rates of 10, 20 and 40 °C/min to evaluate the waste degradation profile based on temperature. Pyrolysis experiments were carried out in the temperature range of 450–600 °C at a heating rate 20 °C/min producing 74–84% oil, 11–20% gas and 2–15% char as by-products. The highest oil yield was observed at 550 °C with maximized gas and solid char formation at 600 and 450 °C, respectively. The FTIR data infers that the derived pyro-oil comprises mainly alkanes, alkenes and aromatic groups indicating fuel quality. The gas product was analysed using gas chromatography which highlights the presence of H2, CO and C1–C6 hydrocarbons without any trace of CO2 after the process. The residual char was also characterized using BET and FESEM. Thus, LDPE plastic wastes offer a potential energy value after pyrolysis through the sustainable recovery of value-added products. Further research on process scale-up and product applications is anticipated.

Keywords

Waste disposal LDPE plastic wastes Waste to product Pyrolysis Product recovery Characterization 

Notes

Acknowledgements

The authors are grateful to Director, CSIR-CMERI, Durgapur, and Director, NIT Durgapur, for supporting the research work. The University Grants Commission (UGC), New Delhi, is being sincerely thanked for providing NET Fellowship for pursuing the Ph.D. research work.

References

  1. Central Pollution Control Board, CPCB. (2012). Material on waste plastic management, pp. 1–23, India.Google Scholar
  2. Chen, D., Yin, L., Wang, H., & He, P. (2014). Pyrolysis technologies for municipal solid waste: A review. Waste Management.  https://doi.org/10.1016/j.wasman.2014.08.004.CrossRefGoogle Scholar
  3. Cit, I., Sınag, A., Yumak, T., Ucar, S., Mısırlıoglu, Z., & Canel, M. (2010). Comparative pyrolysis of polyolefins (PP and LDPE) and PET. Polymer Bulletin, 64, 817–834.CrossRefGoogle Scholar
  4. Delattre, C., Forissiera, M., & Pitault, I. (2001). Improvement of the microactivity test for kinetic and deactivation studies involved in catalytic cracking. Chemical Engineering Science, 56(4), 1337–1345.CrossRefGoogle Scholar
  5. Geyer, R., Jambeck, J. R., & Law, K. L. (2017). Production, use and fate of all plastics ever made. Science Advances, 3(7), e1700782.CrossRefGoogle Scholar
  6. Lam, S. S., Liew, R. K., Jusoh, A., Chong, C. T., Ani, F. N., & Chase, H. A. (2016). Progress in waste oil to sustainable energy, with emphasis on pyrolysis techniques. Renewable and Sustainable Energy Reviews, 53741–53753.Google Scholar
  7. Onwudili, J. A., Insura, N., & Williams, P. T. (2009). Composition of products from the pyrolysis of polyethylene and polystyrene in a closed batch reactor: Effects of temperature and residence time. Journal of Analytical and Applied Pyrolysis, 86, 293–303.CrossRefGoogle Scholar
  8. Paethonom, A., & Yoshikawa, K. (2012). Influence of pyrolysis temperature on rice husk char characteristics and its tar adsorption capability. Energies, 5, 4941–4951.CrossRefGoogle Scholar
  9. Panda Achyut, K., Singh, R. K., & Mishra, D. K. (2010). Thermolysis of waste plastics to liquid fuel: A suitable method for plastic waste management and manufacture of value added products—A world prospective. Renewable and Sustainable Energy Reviews, 14, 233–248.CrossRefGoogle Scholar
  10. Plastics Europe. (2017). An analysis of European plastics production, demand and waste data. Plastics.Google Scholar
  11. Scheirs, J., & Kaminsky, W. (2006). Thermal and catalytic conversion of polyolefins. Wiley.Google Scholar
  12. Wang, J., Liu, Y., Yan, R., Dong, Z., & Tay, J. H. (2012). Pyrolysis characteristics and kinetics of MSW in Singapore. In: 3rd International Conference on Industrial and Hazardous waste management, CRETE 2012.Google Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2020

Authors and Affiliations

  • Ankita Mukherjee
    • 1
    Email author
  • Biswajit Ruj
    • 2
  • Parthapratim Gupta
    • 1
  • A. K. Sadhukhan
    • 1
  1. 1.Department of Chemical EngineeringNational Institute of Technology (NIT)DurgapurIndia
  2. 2.Environmental Engineering GroupCSIR-Central Mechanical Engineering Research Institute (CMERI)DurgapurIndia

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