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Inter-spin Interactions of Organic Radical Chains in Organic 1D Nanochannels: An ESR Study of the Molecular Orientations and Dynamics of Guest Radicals

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Theoretical Chemistry for Advanced Nanomaterials

Abstract

Unique inter-spin interaction appears in one-dimensional (1D) organic inclusion compounds which are synthesized by using 2,4,6-tris(4-chlorophenoxy)-1,3,5-triazine (CLPOT) and (o-phenylenedioxy) cyclotri phosphazene (TPP). Molecular orientations and dynamics of guest radicals incorporated in CLPOT or TPP nanochannels have been investigated using variable-temperature electron spin resonance (ESR) measurement, together with ESR simulation. When 4-substituted-2,2,6,6-tetramethyl-1-piperidinyloxyl (4-X-TEMPO) is incorporated in 1D CLPOT and TPP nanochannels, they exhibited three-dimensional, temperature-independent or 1D, temperature-dependent exchange interactions. It will be possible to design and develop innovative organic magnet based on these features.

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Acknowledgments

These works were partially supported by the Strategic Research Base Development program for Private Universities of the Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT), 2009–2013. These works were also partially supported by the Common Research Funding by Showa University, 2017–2018. The authors wish to thank Professor T. Asaji of Nihon University for assistance with the ESR analyses, Professor T. Hashimoto of Nihon University for assistance with the TG-DTA measurements, Prof. S. Stoll of the University of Washington for assistance with the EasySpin calculations, and the Organic Elemental Analysis Research Center, Kyoto University, for performing the elemental analyses.

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  1. Faculty of Arts and Sciences at Fujiyoshida, Showa University, Yamanashi, Japan

    Hirokazu Kobayashi

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  1. Hylleraas Centre for Quantum Molecular Sciences, Department of Chemistry, University of Oslo, Oslo, Norway, Graduate School of Engineering Mie University, Tsu, Norway

    Taku Onishi

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Kobayashi, H. (2020). Inter-spin Interactions of Organic Radical Chains in Organic 1D Nanochannels: An ESR Study of the Molecular Orientations and Dynamics of Guest Radicals. In: Onishi, T. (eds) Theoretical Chemistry for Advanced Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-15-0006-0_12

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