Skip to main content

Fabrication of Porous HA Ceramic Substrates by Freeze-Tape-Casting and Its Permeability Features

  • Conference paper
  • First Online:
Physics and Techniques of Ceramic and Polymeric Materials (CMC 2018)

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 216))

Included in the following conference series:

Abstract

Hydroxyapatite (HA) porous substrates were fabricated by freeze-tape-casting and used as filter and biomaterials. The influence of the freezing temperature on the pore structures of HA porous substrates was investigated. The permeabilities of the samples with different solid contents and freezing temperatures were also measured. The open porosity of the fabricated HA porous substrate was high, with a closed porosity of only 5–10%, and the lamellar spaces decreased from 2.36 ± 0.53 to 1.11 ± 0.30 μm with the decreasing freezing temperature. Multilayer HA porous substrates with uniform porosity were obtained by multiple freeze-tape-castings using HA slurry with solid content of 35 wt%. The highest compressive strength of multilayer HA porous substrates was 34.98 MPa when being frozen at −45 °C. The permeability value was 4.1 μL cm−2 min−1. The pore structure and permeability of the porous substrates can be controlled by different physical parameters and freezing conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. W. Chen, Fabrication of porous silicon carbide ceramics with high porosity and high strength. J. Eur. Ceram. Soc. 34(3), 837–840 (2014)

    Article  CAS  Google Scholar 

  2. D. Jia, Characterization of porous silicon nitride/silicon oxynitride composite ceramics produced by sol infiltration. Mater. Chem. Phys. 124(1), 97–101 (2010)

    Article  CAS  Google Scholar 

  3. S. Deville, Freeze‐casting of porous ceramics: a review of current achievements and issues. Adv. Eng. Mater. 10(3), 155–169 (2010)

    Article  CAS  Google Scholar 

  4. S.W. Sofie, Fabrication of functionally graded and aligned porosity in thin ceramic substrates with the novel freeze-tape-casting process. J. Am. Ceram. Soc. 90(7), 2024–2031 (2010)

    Article  Google Scholar 

  5. Y. Tang, Novel freeze-casting fabrication of aligned lamellar porous alumina with a centrosymmetric structure. J. Eur. Ceram. Soc. 34(15), 4077–4082 (2014)

    Article  CAS  Google Scholar 

  6. S. Deville, Ice-templated porous alumina structures. Acta Mater. 55(6), 1965–1974 (2007)

    Article  CAS  Google Scholar 

  7. G. Singh, Effect of freezing conditions on β-Tricalcium Phosphate/Camphene scaffold with micro sized particles fabricated by freeze casting. J. Mech. Behav. Biomed. Mater. 79, 189 (2017)

    Article  Google Scholar 

  8. Y. Tang, Freeze cast fabrication of porous ceramics using tert-butyl alcohol–water crystals as template. J. Eur. Ceram. Soc. 36, 1513–1518 (2016)

    Article  CAS  Google Scholar 

  9. Q. Liu, Composite biomaterials with chemical bonding between hydroxyapatite filler particles and PEG/PBT copolymer matrix. Biomaterials 19, 1067–1072 (1998)

    Article  CAS  Google Scholar 

  10. W. Ren, Bull. Chin. Ceram. Soc. 21(1), 38–43 (2002)

    Google Scholar 

  11. A. Jungbauer, Biotechnol. Bioeng. 87(3), 364–375 (2004)

    Article  CAS  Google Scholar 

  12. S. Suzuki, Preparation of sintered filter for ion exchange by a doctor blade method with aqueous slurries of needlelike hydroxyapatite. Ceram. Int. 25(3), 287–291 (1999)

    Article  CAS  Google Scholar 

  13. D.H. Pashley, The effects of burnishing NaF/kaolin/glycerin paste on dentin permeability. J. Periodontol. 58(1), 19–23 (1987)

    Article  CAS  Google Scholar 

  14. L. Hu, Control of pore channel size during freeze casting of porous YSZ ceramics with unidirectionally aligned channels using different freezing temperatures. J. Eur. Ceram. Soc. 30(16), 89–3396 (2010)

    Article  Google Scholar 

  15. Q. Dong, An, optimization of the tape casting slurries for high-quality zirconia substrates. Ceram. Int. 43, 16943–16949 (2017)

    Article  CAS  Google Scholar 

  16. Y. Tang, Two-step freeze casting fabrication of hydroxyapatite porous scaffolds with bionic bone graded structure. Ceram. Int. 39(8), 703–779 (2013)

    Google Scholar 

  17. J.C. Le Huec, Influence of porosity on the mechanical resistance of hydroxyapatite ceramics under compressive stress. Biomaterials 16, 113–118 (1995)

    Article  Google Scholar 

  18. R.W. Rice, Comparison of stress concentration versus minimum solid area based mechanical property-porosity relations. J. Mater. Sci. 28, 2187–2190 (1993)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors would like to acknowledge the support from the National Natural Science Foundation of China (Nos. 81571014 and 51572217), China Postdoctoral Science special Foundation (2016T90937) and the Natural Science Foundation of Shaanxi Province (2016JQ5058).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yufei Tang .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Mao, M., Tang, Y., Xu, R., Zhao, K., Zhao, X. (2019). Fabrication of Porous HA Ceramic Substrates by Freeze-Tape-Casting and Its Permeability Features. In: Han, Y. (eds) Physics and Techniques of Ceramic and Polymeric Materials. CMC 2018. Springer Proceedings in Physics, vol 216. Springer, Singapore. https://doi.org/10.1007/978-981-13-5947-7_10

Download citation

  • DOI: https://doi.org/10.1007/978-981-13-5947-7_10

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-13-5946-0

  • Online ISBN: 978-981-13-5947-7

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics