Organic-Inorganic Hybrid Material with Surface-Modified Zirconia Nanoparticles as Element Blocks

  • Kimihiro MatsukawaEmail author
  • Koji Mitamura
  • Seiji Watase


Organic-inorganic hybrid materials by dispersing inorganic nanoparticles in organic polymers are expected as functional substances with synergistic properties. Recently, high refractive index thin films are most important materials for optical devices such as flat panel display, touch panel, etc. These hybrids with dispersion of surface-modified zirconia nanoparticles can provide the controlled refractive index materials. It is necessary for the preparation of transparent hybrid materials to disperse zirconia nanoparticles in organic solvent or polymer solution by a beads mill process. Effective surface modifications of zirconia nanoparticles were successfully developed by two treatments of (1) with silane coupling agent and isocyanate compound and (2) with dual-site silane coupling agent. These dispersions can be applied to prepare the high refractive index thin films.


Nanoparticles High refractive index Organic-inorganic hybrids Thin films 



We thank Dr. Yuki Minami (Mikuni Color Ltd.), Mr. Eiichiro Takeuchi (Osaka Institute of Technology), Mr. Takashi Fukuda, and Mr. Atsushi Sasaki (Osaka Tele-communication University). This work was supported in part by a Grant-in-Aid for Scientific Research on Innovative Areas “New Polymeric Materials Based on Element-Blocks (No. 2401)” provided by the Ministry of Education, Culture, Sports, Science and Technology, Japan.


  1. 1.
    Chujo Y (1996) Polym Mater Encycl 6:4793Google Scholar
  2. 2.
    Wen J, Wilkes GL (1996) Chem Mater 8:1667CrossRefGoogle Scholar
  3. 3.
    Gomez-Romero P (2001) Adv Mater 13:161CrossRefGoogle Scholar
  4. 4.
    Sanchez C, Julian B, Belleville P, Popall M (2005) J Mater Chem 15:3559CrossRefGoogle Scholar
  5. 5.
    Gomez-Romero P, Sanchez C (2006) Functional hybrid materials. WileyGoogle Scholar
  6. 6.
    Matsukawa K, Matsuura Y, Nakamura A, Nishioka N, Motokawa T, Murase H (2006) J Photopolym Sci Technol 19:89CrossRefGoogle Scholar
  7. 7.
    Matsukawa K, Matsuura Y, Nakamura A, Nishioka N, Murase H, Kawasaki S (2007) J Photopolym Sci Technol 20:307CrossRefGoogle Scholar
  8. 8.
    Matsukawa K, Fukuda T, Watase S, Goda H (2010) J Photopolym Sci Technol 23:115CrossRefGoogle Scholar
  9. 9.
    Matsukawa K, Katada K, Nishioka N, Matsuura Y, Inoue H, Photopolym J (2004) Sci Technol 17:51–52Google Scholar
  10. 10.
    Matsukawa K, Matsuura Y, Katayama K, Nishioka N, Chikaraishi M, Naito H (2008) Kobunshi Ronbunsyu 65:440CrossRefGoogle Scholar
  11. 11.
    Matsukawa K, Matsuura Y, Michiwaki Y, Chikaraishi M, Naito H (2009) J Photopolym Sci Technol 22:307CrossRefGoogle Scholar
  12. 12.
    Murata K, Minami Y, Yomoyasu H, Matsukawa K (2008) J Adhes Soc Jpn 44:438CrossRefGoogle Scholar
  13. 13.
    Joni M, Purwanto A, Iskandar F, Okuyama K (2009) Ind Eng Chem Res 48:6916CrossRefGoogle Scholar
  14. 14.
    Iskandar F (2009) Adv Powder Technol 20:283CrossRefGoogle Scholar
  15. 15.
    Minami Y, Murata K, Watase S, Matsukawa K (2010) Kobunshi Ronbunsyu 67:397CrossRefGoogle Scholar
  16. 16.
    Matsukawa K, Minami Y, Watase S (2012) IDW/AD’ 12 Proc 965Google Scholar
  17. 17.
    Sugimoto H, Nakanishi E, Yamauchi K, Daimatsu K, Yasumura T, Inomata K (2004) Polym Bull 52:209CrossRefGoogle Scholar
  18. 18.
    Sugimoto H, Daimatsu K, Nakanishi E, Ogasawara Y, Yasumura T, Inomata K (2006) Polymer 47:3754CrossRefGoogle Scholar
  19. 19.
    Minami Y, Murata K, Watase S, Matsumoto A, Matsukawa K (2013) J Photopolym Sci Technol 26:491CrossRefGoogle Scholar
  20. 20.
    Hoyle CE, Lee TY, Roper T (2004) J Polym Sci. Part A: Polym Chem 5301:42Google Scholar
  21. 21.
    Hoyle CE, Bowman CN (2010) Angew Chem Int Ed 49:1540CrossRefGoogle Scholar
  22. 22.
    Minami Y, Murata K, Watase S, Matsukawa K (2014) Photopolym J  Sci Technol 27:261–262Google Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  • Kimihiro Matsukawa
    • 1
    Email author
  • Koji Mitamura
    • 2
  • Seiji Watase
    • 2
  1. 1.Kyoto Institute of TechnologyKyotoJapan
  2. 2.Osaka Research Institute of Industrial Science and TechnologyOsakaJapan

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