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Design of Element Blocks for Photoresponsive Organosiloxane-Based Materials

  • Sufang Guo
  • Kazuyuki Kuroda
  • Atsushi ShimojimaEmail author
Chapter

Abstract

In this chapter, preparation, structures, and photoresponsive properties of various azobenzene–siloxane hybrid nanomaterials based on the design of element blocks are described. Hydrolysis and polycondensation reactions accompanied by self-assembly of different types of azobenzene-functionalized alkoxysilane precursors yield hybrids with ordered mesostructures. Lamellar films show reversible d-spacing changes and macroscopic bending–unbending motion by partial transcis photoisomerization of the azobenzene groups. Further, incorporation of a cage oligosiloxane into the precursor leads to the formation of cylindrical assemblies, in which efficient photoisomerization of azobenzene is achieved. These findings will contribute to the creation of novel photoresponsive materials.

Keywords

Photoresponsive materials Azobenzene Siloxane Self-assembly Sol–gel processing 

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Copyright information

© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  • Sufang Guo
    • 1
    • 3
  • Kazuyuki Kuroda
    • 1
    • 2
  • Atsushi Shimojima
    • 2
    Email author
  1. 1.Kagami Memorial Research Institute for Materials Science and TechnologyWaseda UniversityShinjuku-kuJapan
  2. 2.Department of Applied ChemistryWaseda UniversityShinjuku-kuJapan
  3. 3.Present address: School of Materials Science and TechnologyChina University of Geosciences, Haidian DistrictBeijingChina

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