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Lead Adsorption by Biomass and Weathered Coal Fly Ashes

  • Xenia Wirth
  • N. N. Nortey Yeboah
  • Susan Burns
Conference paper
Part of the Environmental Science and Engineering book series (ESE)

Abstract

Adsorption is an extensively-studied, cost-effective method of removing heavy metal ions from wastewater, such as lead, which is known to be toxic. Removal of metals with adsorbents that beneficially use waste materials are particularly advantageous to study due to their low cost. This research determined the adsorption capacity of three fly ashes (two biomass and one weathered coal ash) for Pb(II) from aqueous solutions. The adsorptive capacity of the alternative ashes were compared to one sample of activated carbon. The biomass fly ashes demonstrated good removal capacity for Pb(II) through a combination of adsorption and precipitation mechanisms. The weathered coal fly ash had low adsorption capacity (less than 3 mg/g). Biomass fly ashes have potential as low-cost alternatives for heavy metal removal.

Keywords

Heavy metals Wastewater treatment Precipitation Beneficial use 

Notes

Acknowledgements

This research was funded by Southern Company. The authors graciously acknowledge the continued support of Southern Company, and the opinions expressed in this paper are the authors’ alone and do not necessarily reflect the policies and views of Southern Company. This work was performed in part at the Georgia Tech Institute for Electronics and Nanotechnology, a member of the National Nanotechnology Coordinated Infrastructure, which is supported by the National Science Foundation (Grant ECCS-1542174).

References

  1. 1.
    Zhao G, Wu X, Tan X, Wang X (2011) Sorption of heavy metal ions from aqueous solutions: a review. Open Colloid Sci J 4:19–31CrossRefGoogle Scholar
  2. 2.
    Feng Q, Lin Q, Gong F, Sugita S, Shoya M (2004) Adsorption of lead and mercury by rice husk ash. J Colloid Interface Sci 278:1–8.  https://doi.org/10.1016/j.jcis.2004.05.030CrossRefGoogle Scholar
  3. 3.
    Xu X, Cao X, Zhao L (2013) Comparison of rice husk- and dairy manure-derived biochars for simultaneously removing heavy metals from aqueous solutions: role of mineral components in biochars. Chemosphere 92:955–961.  https://doi.org/10.1016/j.chemosphere.2013.03.009CrossRefGoogle Scholar
  4. 4.
    Kongsuwan A, Patnukao P, Pavasant P (2009) Binary component sorption of Cu(II) and Pb(II) with activated carbon from Eucalyptus camaldulensis Dehn bark. J Ind Eng Chem 15:465–470.  https://doi.org/10.1016/j.jiec.2009.02.002CrossRefGoogle Scholar
  5. 5.
    Strawn DG, Sparks DL (1999) The use of XAFS to distinguish between inner- and outer-sphere lead adsorption complexes on montmorillonite. J Colloid Interface Sci 216:257–269.  https://doi.org/10.1006/jcis.1999.6330CrossRefGoogle Scholar
  6. 6.
    Srivastava SK, Singh AK, Sharma A (1994) Studies on the uptake of lead and zinc by lignin obtained from black liquor - a paper industry waste material. Environ Technol (United Kingdom) 15:353–361.  https://doi.org/10.1080/09593339409385438CrossRefGoogle Scholar
  7. 7.
    Anis M, Haydar S, Bari AJ (2013) Adsorption of lead and copper from aqueous solution using unmodified wheat straw. Environ Eng Manag J 12:2117–2124CrossRefGoogle Scholar
  8. 8.
    Castaldi P, Silvetti M, Garau G, Demurtas D, Deiana S (2015) Copper(II) and lead(II) removal from aqueous solution by water treatment residues. J Hazard Mater 283:140–147.  https://doi.org/10.1016/j.jhazmat.2014.09.019CrossRefGoogle Scholar
  9. 9.
    Zhou YF, Haynes RJ (2010) Sorption of heavy metals by inorganic and organic components of solid wastes: significance to use of wastes as low-cost adsorbents and immobilizing agents. Crit Rev Environ Sci Technol 40:909–977.  https://doi.org/10.1080/10643380802586857CrossRefGoogle Scholar
  10. 10.
    Moreno-Barbosa J, López-Velandia C, Maldonado A, Giraldo L, Moreno-Piraján J (2013) Removal of lead(II) and zinc(II) ions from aqueous solutions by adsorption onto activated carbon synthesized from watermelon shell and walnut shell. Adsorption 19:675–685.  https://doi.org/10.1007/s10450-013-9491-xCrossRefGoogle Scholar
  11. 11.
    Shao Y, Wang J, Preto F, Zhu J, Xu C (2012) Ash deposition in biomass combustion or co-firing for power/heat generation. Energies 5:5171–5189.  https://doi.org/10.3390/en5125171CrossRefGoogle Scholar
  12. 12.
    Yeboah NNN, Shearer CR, Burns SE, Kurtis KE (2014) Characterization of biomass and high carbon content coal ash for productive reuse applications. Fuel 116:438–447.  https://doi.org/10.1016/j.fuel.2013.08.030CrossRefGoogle Scholar
  13. 13.
    Gitari WM, Petrik LF, Etchebers O, Key DL, Okujeni C (2008) Utilization of fly ash for treatment of coal mines wastewater: solubility controls on major inorganic contaminants. Fuel 87:2450–2462.  https://doi.org/10.1016/j.fuel.2008.03.018CrossRefGoogle Scholar
  14. 14.
    Vassilev SV, Menendez R, Alvarez D, Diaz-Somoano M, Martinez-Tarazona MR (2003) Phase-mineral and chemical composition of coal fly ashes as a basis for their multicomponent utilization. 1. Characterization of feed coals and fly ashes. Fuel 82:1793–1811.  https://doi.org/10.1016/S0016-2361(03)00123-6CrossRefGoogle Scholar
  15. 15.
    Al-Degs YS, El-Barghouthi MI, Issa AA, Khraisheh MA, Walker GM (2006) Sorption of Zn(II), Pb(II), and Co(II) using natural sorbents: equilibrium and kinetic studies. Water Res 40:2645–2658.  https://doi.org/10.1016/j.watres.2006.05.018CrossRefGoogle Scholar
  16. 16.
    Hayes KF, Leckie JO (1987) Modeling ionic strength effects on cation adsorption at hydrous oxide/solution interfaces. J Colloid Interface Sci 115:564–572 CrossRefGoogle Scholar
  17. 17.
    Erol M, Küçükbayrak S, Ersoy-Meriçboyu A, Uluba T (2005) Removal of Cu2+ and Pb2+ in aqueous solutions by fly ash. Energy Convers Manag 46:1319–1331.  https://doi.org/10.1016/j.enconman.2004.06.033CrossRefGoogle Scholar
  18. 18.
    Hayes KF, Papelis C, Leckie JO (1988) Modeling ionic strength effects on anion adsorption at hydrous oxide/solution interfaces. J Colloid Interface Sci 125:717–726.  https://doi.org/10.1016/0021-9797(88)90039-2CrossRefGoogle Scholar
  19. 19.
    Singh A, Kumar D, Gaur JP (2008) Removal of Cu(II) and Pb(II) by Pithophora oedogonia: sorption, desorption and repeated use of the biomass. J Hazard Mater 152:1011–1019.  https://doi.org/10.1016/j.jhazmat.2007.07.076CrossRefGoogle Scholar
  20. 20.
    Pesavento M, Profumo A, Alberti G, Conti F (2003) Adsorption of lead(II) and copper(II) on activated carbon by complexation with surface functional groups. Anal Chim Acta 480:171–180.  https://doi.org/10.1016/S0003-2670(02)01597-0CrossRefGoogle Scholar
  21. 21.
    Wang J, Teng X, Wang H, Ban H (2004) Characterizing the metal adsorption capability of a class F coal fly ash. Environ Sci Technol 38:6710–6715.  https://doi.org/10.1021/es049544hCrossRefGoogle Scholar
  22. 22.
    Parkhurst DL, Appelo CAJ (2013) Description of input and examples for PHREEQC version 3—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. Groundw. B. 6, Model. Tech 1–497.  https://doi.org/10.1016/0029-6554(94)90020-5CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  • Xenia Wirth
    • 1
  • N. N. Nortey Yeboah
    • 2
  • Susan Burns
    • 1
  1. 1.AtlantaUSA
  2. 2.AtlantaUSA

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