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Resonant Raman Spectroscopy of Two Dimensional Materials Beyond Graphene

  • Hyeonsik CheongEmail author
  • Jae-Ung Lee
Chapter
Part of the Springer Series in Materials Science book series (SSMATERIALS, volume 276)

Abstract

The resonance Raman effects in two dimensional materials including transition metal dichalcogenides and black phosphorus are reviewed. The Raman intensities of high-frequency intra-layer vibration modes are enhanced near resonance with exciton states. Some Raman peaks that are either forbidden or weak in non-resonant cases show strong enhancement near resonances. In the low-frequency Raman spectra, some unusual features, in addition to shear and breathing modes, appear near resonance with exciton states. Some intra-layer vibration modes exhibit Davydov splitting due to inter-layer interactions when the excitation energy is close to resonances. The polarization behaviors of some Raman modes in anisotropic two-dimensional materials have peculiar dependences on the excitation energy, which is related to the resonance effect.

Notes

Acknowledgements

This work was supported by the National Research Foundation (NRF) grant funded by the Korean government (MSIP) (NRF-2016R1A2B3008363) and by a grant (No. 2011-0031630) from the Center for Advanced Soft Electronics under the Global Frontier Research Program of MSIP. The authors also acknowledge the contributions of K. Kim, M. Kim, J. Kim, J. Yang, J. Park, S. Lim, D. Nam, S. Han, and S. Kim.

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© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  1. 1.Department of PhysicsSogang UniversitySeoulKorea

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