Skip to main content

Influential Factors of Thermochemical Conversion of Basic Components

  • Chapter
  • First Online:
Combustible Solid Waste Thermochemical Conversion

Part of the book series: Springer Theses ((Springer Theses))

  • 418 Accesses

Abstract

Chapter 3 investigated the pyrolytic characteristics and mechanisms of basic components, while the reaction conditions were constant, which simplified the comparison of different components. Then, which factors could influence the pyrolytic process of basic components? This chapter will try to provide an answer to this question. Actually, part of the content was involved in Chap. 3. For example, during the study of kinetics in 3.1, the pyrolysis in thermogravimetric analyzer (TGA), slow pyrolysis in Macro-TGA, and fast pyrolysis in Macro-TGA were compared. This chapter aims to investigate this question systematically. Limited by the number of experiments, we could not study the influential factors of all the basic components. Lignin and polyvinyl chloride (PVC) account for high fractions in combustible solid waste (CSW); the thermochemical conversion processes of them are complicated; and a large amount of polycyclic aromatic hydrocarbons (PAHs) are formed during the thermochemical processes. In particular for PVC, the chlorine in its structure is the main chlorine source of dioxins. Therefore, this chapter chose lignin as the representative of biomass basic components and PVC as the representative of biomass basic components. Investigation of different influence factors could help us determine suitable factors to enhance efficiency and control pollution in industrial applications. In addition, understanding the effect of different factors could help to further explore the pyrolytic mechanisms of basic components. It should be noted that the study of influence factor in this chapter was limited to single component, and the interactions of basic components were the research focus of next chapter.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Asmadi M, Kawamoto H, Saka S (2011a) Thermal reactivities of catechols/pyrogallols and cresols/xylenols as lignin pyrolysis intermediates. J Anal Appl Pyrol 92:76–87

    Article  CAS  Google Scholar 

  • Asmadi M, Kawamoto H, Saka S (2011b) Thermal reactions of guaiacol and syringol as lignin model aromatic nuclei. J Anal Appl Pyrol 92:88–98

    Article  CAS  Google Scholar 

  • Asmadi M, Kawamoto H, Saka S (2011c) Gas- and solid/liquid-phase reactions during pyrolysis of softwood and hardwood lignins. J Anal Appl Pyrol 92:417–425

    Article  CAS  Google Scholar 

  • Cheng WH, Liang YC (2000) Catalytic pyrolysis of polyvinylchloride in the presence of metal chloride. J Appl Polym Sci 77:2464–2471

    Article  CAS  Google Scholar 

  • Gordillo G, Annamalai K (2010) Adiabatic fixed bed gasification of dairy biomass with air and steam. Fuel 89:384–391

    Article  CAS  Google Scholar 

  • Gui B, Qiao Y, Wan D et al (2013) Nascent tar formation during polyvinylchloride (PVC) pyrolysis. Proc Combust Inst 34:2321–2329

    Article  CAS  Google Scholar 

  • Han J, Kim H (2008) The reduction and control technology of tar during biomass gasification/pyrolysis: an overview. Renew Sustain Energy Rev 12:397–416

    Article  CAS  Google Scholar 

  • Hayashi S, Amano H, Niki T et al (2010) A new pyrolysis of metal hydroxide-mixed waste biomass with effective chlorine removal and efficient heat recovery. Ind Eng Chem Res 49:11825–11831

    Article  CAS  Google Scholar 

  • Jiang G, Nowakowski DJ, Bridgwater AV (2010) Effect of the temperature on the composition of lignin pyrolysis products. Energy Fuels 24:4470–4475

    Article  CAS  Google Scholar 

  • Kleen M (1995) Influence of inorganic species on the formation of polysaccharide and lignin degradation products in the analytical pyrolysis of pulps. J Anal Appl Pyrol 35:15–41

    Article  CAS  Google Scholar 

  • Kuroda K, Inoue Y, Sakai K (1990) Analysis of lignin by pyrolysis-gas chromatography. I. Effect of inorganic substances on guaiacol-derivative yield from softwoods and their lignins. J Anal Appl Pyrol 18:59–69

    Article  CAS  Google Scholar 

  • Kwon EE, Castaldi MJ (2012) Urban energy mining from municipal solid waste (MSW) via the enhanced thermo-chemical process by carbon dioxide (CO2) as a reaction medium. Bioresour Technol 125:23–29

    Article  CAS  Google Scholar 

  • Ledesma EB, Marsh ND, Sandrowitz AK et al (2002) Global kinetic rate parameters for the formation of polycyclic aromatic hydrocarbons from the pyrolyis of catechol, a model compound representative of solid fuel moieties. Energy Fuels 16:1331–1336

    Article  CAS  Google Scholar 

  • Li XT, Grace JR, Lim CJ et al (2004) Biomass gasification in a circulating fluidized bed. Biomass Bioenerg 26:171–193

    Article  CAS  Google Scholar 

  • Lv P, Yuan Z, Ma L et al (2007) Hydrogen-rich gas production from biomass air and oxygen/steam gasification in a downdraft gasifier. Renewable Energy 32:2173–2185

    Article  Google Scholar 

  • Ma S, Lu J, Gao J (2002) Study of the low temperature pyrolysis of PVC. Energy Fuels 16:338–342

    Article  CAS  Google Scholar 

  • Mastral AM, Callén MS (2000) A review on polycyclic aromatic hydrocarbon (PAH) emissions from energy generation. Environ Sci Technol 34:3051–3057

    Article  CAS  Google Scholar 

  • Masuda Y, Uda T, Terakado O et al (2006) Pyrolysis study of poly(vinyl chloride)–metal oxide mixtures: quantitative product analysis and the chlorine fixing ability of metal oxides. J Anal Appl Pyrol 77:159–168

    Article  CAS  Google Scholar 

  • McNeill IC, Memetea L, Cole WJ (1995) A study of the products of PVC thermal degradation. Polym Degrad Stab 49:181–191

    Article  CAS  Google Scholar 

  • Montaudo G, Puglisi C (1991) Evolution of aromatics in the thermal degradation of poly(vinyl chloride): a mechanistic study. Polym Degrad Stab 33:229–262

    Article  CAS  Google Scholar 

  • Müller J, Dongmann G (1998) Formation of aromatics during pyrolysis of PVC in the presence of metal chlorides. J Anal Appl Pyrol 45:59–74

    Article  Google Scholar 

  • Müller J, Dongmann G, Frischkorn CGB (1997) The effect of aluminium on the formation of PAH, Methyl-PAH and chlorinated aromatic compounds during thermal decomposition of PVC. J Anal Appl Pyrol 43:157–168

    Article  Google Scholar 

  • Sharma RK, Hajaligol MR (2003) Effect of pyrolysis conditions on the formation of polycyclic aromatic hydrocarbons (PAHs) from polyphenolic compounds. J Anal Appl Pyrol 66:123–144

    Article  CAS  Google Scholar 

  • Shukla B, Koshi M (2012) A novel route for PAH growth in HACA based mechanisms. Combust Flame 159:3589–3596

    Google Scholar 

  • Wang D, Xu X, Zheng M et al (2002) Effect of copper chloride on the emissions of PCDD/Fs and PAHs from PVC combustion. Chemosphere 48:857–863

    Article  CAS  Google Scholar 

  • Wang Z, Wang J, Richter H et al (2003) Comparative study on polycyclic aromatic hydrocarbons, light hydrocarbons, carbon monoxide, and particulate emissions from the combustion of polyethylene, polystyrene, and poly(vinyl chloride). Energy Fuels 17:999–1013

    Article  CAS  Google Scholar 

  • Williams PT, Horne PA (1994) The role of metal salts in the pyrolysis of biomass. Renewable Energy 4:1–13

    Article  CAS  Google Scholar 

  • Williams PT, Williams EA (1999) Interaction of plastics in mixed-plastics pyrolysis. Energy Fuels 13:188–196

    Article  CAS  Google Scholar 

  • Yu H, Zhang Z, Li Z et al (2014) Characteristics of tar formation during cellulose, hemicellulose and lignin gasification. Fuel 118:250–256

    Article  CAS  Google Scholar 

  • Zhou H, Meng A, Long Y et al (2014a) An overview of characteristics of municipal solid waste fuel in China: physical, chemical composition and heating value. Renew Sustain Energy Rev 36:107–122

    Article  CAS  Google Scholar 

  • Zhou H, Wu C, Onwudili JA et al (2014b) Polycyclic aromatic hydrocarbon formation from the pyrolysis/gasification of lignin at different reaction conditions. Energy Fuels 28:6371–6379

    Article  CAS  Google Scholar 

  • Zhou H, Wu C, Onwudili JA et al (2016) Influence of process conditions on the formation of 2–4 ring polycyclic aromatic hydrocarbons from the pyrolysis of polyvinyl chloride. Fuel Process Technol 144:299–304

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hui Zhou .

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer Nature Singapore Pte Ltd.

About this chapter

Cite this chapter

Zhou, H. (2017). Influential Factors of Thermochemical Conversion of Basic Components. In: Combustible Solid Waste Thermochemical Conversion. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-3827-3_4

Download citation

Publish with us

Policies and ethics