Calcined Clays for Sustainable Concrete pp 479-486 | Cite as
Clay Activation and Color Modification in Reducing Calcination Process: Development in Lab and Industrial Scale
Abstract
Calcined clays have been used in pozzolanic portland cement manufacturing in Brazil for many years. However, their color imposes commercial limitation when cements show reddish or pinkish hues. This work presents two case studies consisting of reducing process calcination of two clays by reducing process in: electric static furnace to obtain maximum temperature (700–1000 °C) and burning time (5–20 min) conditions, as a function of color and pozzolanic reactivity, and; rotary kiln for both laboratorial and industrial scales. Chemical (XRF, TGA/DTA), mineralogical (XRD), physical-mechanical (compressive strength), pozzolanic reactivity (Chapelle´s method and Strength Activity Index) and color test (colorimeter spectrometer using CIE color system standard) were applied in clays and pozzolanic cements characterization. Results show satisfactory performance of grayish pozzolanic cements, and indicate an alternative process to obtain calcined clays according to cements specifications.
Keywords
Compressive Strength Pozzolanic Reactivity Rotary Kiln Petroleum Coke Compressive Strength TestPreview
Unable to display preview. Download preview PDF.
References
- 1.Gámiz, E., et al.: Relationships between chemico-mineralogical composition and color properties in selected natural and calcined Spanish kaolins. Appl. Clay Sci. 28, 269–282 (2005)CrossRefGoogle Scholar
- 2.Chandrasekhar, S., Ramaswamy, S.: Iron minerals and their influence on the optical properties of two Indian kaolins. Appl. Clay Sci. 33, 269–277 (2006)CrossRefGoogle Scholar
- 3.Hofstetter, T.B., et al.: Reactivity of Fe(II) species associated with clay minerals. Environ. Sci. Technol. 37, 519–528 (2003)CrossRefGoogle Scholar
- 4.Chandrasekhar, S., Ramaswamy, S.: Influence of mineral impurities on the properties of kaolin and its thermally treated products. Appl. Clay Sci. 21, 133–142 (2002)CrossRefGoogle Scholar
- 5.Castanho, M.P., Chotoli, F.F., Costa, R.G.: Forno Rotativo Tubular Laboratorial—Estudo de Perfil Térmico. In: Enqualab. São Paulo (2008). (http://www.vertent.net/remesp/enqualab2008/cdrom/pdf/TT036.pdf)
- 6.CIE System L*a*b* by L’ECLAIRAGE INTERNATIONAL COMMISSION in 1976Google Scholar
- 7.DE Souza, C.M., Garcia, E., Jäger, C.H., Quarcioni, V.A., Greiser, S.: Evaluation of pozzolanic reactivity of calcined kaolinite. In: 5th International Conference Non Traditional Cement and Concrete, 2014, Brno. Non-Traditional Cement & Concrete V, vol. 1, pp. 225–228. Brno: NOVPRESS (2014)Google Scholar
- 8.Fernandez, R., Martirena, F., Scrivener, K.L.: The origin of the pozzolanic activity of calcined clay minerals: a comparison between kaolinite, illite and montmorillonite. Cem. Concr. Res. 41, 113–122 (2011)CrossRefGoogle Scholar