Mineral Processing and the Environment pp 165-196 | Cite as
Removal and Recovery of Metals from Dilute Solutions
Abstract
Dilute aqueous solutions, generated or used by mineral industry, generally contain several metal species; the latter are known to be non-biode-gradable substances. For this reason, various processes suitable for metal ions removal from water and effluents will be briefly reviewed, among them the conventional ones such as precipitation, sorption and ion exchange. Nevertheless, attention will be mainly paid to the application of innovative processes, particularly aiming for metals recovery. In today’s world of water shortage, water reuse in the mineral processing plants is also of great importance. Stress will be given to the necessary solid-liquid separation technique applied downstream, following the metals removal. The important aspect of applying industrial by-products (i.e. mineral fines, etc.) as efficient sorbents, including the biosorbents, will be discussed. Finally, the chemistry of pyrite flotation will be reported.
Keywords
Activate Sludge Acid Mine Drainage Mineral Processing Pyrite Concentrate Flotation TechniquePreview
Unable to display preview. Download preview PDF.
References
- 1.Brenner, A., Belkin, S., and Abeliovich, A. (1994) Development of a pretreatment program to improve biological treatability of high strength and toxic industrial wastewater, Wat. Sci. Tech. 29 (9), 29–37.Google Scholar
- 2.Hanna, H.S. and Rampacek, C. (1980) Resources potential of mineral and metallurgical wastes, in P. Somasundaran (ed.), Fine Particles Processing, SME-AIME, New York, pp. 1709–1730.Google Scholar
- 3.Englande, Jr, A.J. (1994) Status and direction of waste minimization in the chemical and petrochemical industries, Wat. Sci. Tech. 29 (8), 25–36.Google Scholar
- 4.Frost, F.A. and Mensik, S. (1991) Balancing minerals development and environmental protection, Long Range Planning 24 (4), 58–73.CrossRefGoogle Scholar
- 5.Krishnan, E.R. Utrecht, P.W., Patkar, A.N., Davis, J.S., Pour, S.G., and Foerst M.E. (1993) Recovery of Metals from Sludges and Wastewaters,Noyes Data Corp., Park Ridge.Google Scholar
- 6.Powell, D.M. (1994) Selecting innovative cleanup technologies: EPA resources, Chem. Eng. Prog. 90, 33–41.Google Scholar
- 7.Matis, K.A. and Zouboulis, A.I. (1995) An overview of the process, in K.A. Matis (ed.), Flotation Science and Engineering, Marcel Dekker, New York, pp. 1–44.Google Scholar
- 8.Mihopoulos, J. and Hahn, H.H. (1994) Concepts for efficient liquid-solid separation - The key to successful pretreatment of industrial wastewaters, Wat. Sci. Tech. 29(9), 347–350.Google Scholar
- 9.Zabel, T.F. (1992) Flotation in water treatment, in P. Mavros and K.A. Matis (eds.), Innovations in Flotation Technology,Kluwer Academic, Dordrecht, pp. 431–454.Google Scholar
- 10.Levenspiel, O. (1972) Chemical Reaction Engineering,John Wiley and Sons, New York, p. 101.Google Scholar
- 11.Mavros, P. (1995) Residence time distribution in flotation cells, as in ref. [7], pp. 273–289.Google Scholar
- 12.Schofield, T. (1995) Design and operation of the world’s largest dissolved-air flotation water treatment plant, IAWQ Yearbook, London, pp. 10–13.Google Scholar
- 13.Versaw, R.E. (1980) Environmental considerations in mill siting, in A.L. Mular and R.B. Bhappu (eds.), Mineral Processing Plant Design, SME-AIME, New York, pp. 714–732.Google Scholar
- 14.Broman, P.G. (1980) Water reuse at sulphide ore concentrates in Sweden: practice, experience and current developments, in M.J. Jones (ed.), Complex Sulphide Ores, IMM, London, pp. 28–39.Google Scholar
- 15.Pugsley, E.B., Cheng C.Y., Updegraff, D.M., and Ross, L.W. (1970) Removal of heavy metals from mine drainage in Colorado by precipitation, Chem. Eng. Prog., Water Symp. Ser. 67, 75–89.Google Scholar
- 16.Ramadorai, G. and Hanten, J.P. (1986) Removal of molybdenum and heavy metals from effluents by flotation, Miner. Metallurg. Proces., Aug., 149–154.Google Scholar
- 17.Doyle, F.M. (1990) Acid mine drainage from sulphide ore deposits, in P.M.J. Gray (ed.), Sulphide Deposits–their Origin and Processing, IMM, London, pp. 301–310.CrossRefGoogle Scholar
- 18.Thomson, B.M. and Tumey, W.R. (1995) Minerals and mine drainage, Wat. Envir. Res. 67. 527–529.CrossRefGoogle Scholar
- 19.Kydros, K.A. and Matis, K.A. (1995) Flotation of iron sulfide minerals; electrokinetic aspects, in K.A. Matis (ed.), Flotation Science and Engineering, Marcel Dekker, New York, pp. 127–155.Google Scholar
- 20.Barrett, J. and Hughes M.N. (1993) The mechanism of the bacterial oxidation of arsenopyritepyrite mixtures: The identification of plant control parameters, Minerals Eng. 6, 969–975.CrossRefGoogle Scholar
- 21.Adam, K., Stefanakis, M., and Kontopoulos, A. (1989) Bacterial oxidation of the Olympias arsenical pyrite concentrate, in B.J. Scheiner, F.M. Doyle, and S.K. Kawatra (eds.), Biotechnology in Minerals and Metal Processing, SME-AIME, Littleton.Google Scholar
- 22.Yelloji Rao, M.K., and Somasundaran, P. (1995) Biomodification of mineral surfaces and flotation, as in ref. [7], pp. 455–472.Google Scholar
- 23.Kontopoulos, A. and Adam, K. (1992) Arsenic in extractive metallurgy: Environmental problems and solutions, Trans. Technic. Univ. Kosice (spec. issue) 2, 144–152.Google Scholar
- 24.Matis, K.A. and Gallios, G.P. (1986) Dissolved-air and electrolytic flotation, in B.A. Wills and R.W. Barley (eds.), Mineral Processing at a Crossroads, Martinus Nijhoff, Dordrecht, pp. 37–69.CrossRefGoogle Scholar
- 25.Dean, K.C., Froisland, L.J., and Shirts, M.B. (1986) Utilization and Stabilization of Mineral Wastes, Bulletin, US Bureau of Mines, No. 688.Google Scholar
- 26.Anthony, M.T. and Flett, D.S. (1994) Hydrometallurgy - an environmentally sustainable technology?, in Int. Symp. SCI, Hydrometallurgy ‘84, Chapman and Hall, London.Google Scholar
- 27.Matis, K.A. (1981) The removal of organic entrainment in copper solvent extraction by flotation, Chim. Chron.(New Ser.) 10, 93–100.Google Scholar
- 28.Zouboulis, A.I. and Matis, K.A. (1995) Metal ion flotation in hydrometallurgy; the case of Ge recovery, as in ref. [7], pp. 517–550.Google Scholar
- 29.Kula, P., Rezek, K., and Krcho, L. (1988) Possibility to use the precipitates flotation for removing of heavy metal ions from mining waters, in R. Abbou (ed.), Hazardous Waste: Detection, Control, Treatment, Elsevier, Amsterdam, pp. 1689–1696.Google Scholar
- 30.Jude, E. and Fratila N., (1973) Recovery of uranium compounds in mine water by ion flotation, 10 t Int. Miner. Process. Cong., IMM, London, paper 25.Google Scholar
- 31.Zouboulis, A.I., Kydros, K.A., and Matis, K.A. (1993) Removal of toxic metal ions from solutions using industrial solid by-products, Wat. Sci. Tech. 27 (10), 83–93.Google Scholar
- 32.Schweitzer, P.A. (ed.) (1979) Handbook of Separation Techniques for Chemical Engineers, McGraw-Hill, New York, p. 1–421.Google Scholar
- 33.Fuerstenau, D.W. (1980) Fine particle flotation, in P. Somasundaran (ed.), Fine Particles Processing, SME-AIME, New York, pp. 669–705.Google Scholar
- 34.Stumm, W. (1992) Chemistry of the Solid-Water Interface - Processes at the Mineral-Water and Particle-Water Interface in Natural Systems, John Wiley and Sons, New York.Google Scholar
- 35.Evans, G.M., Atkinson, B.W., and Jameson, G.J. (1995) The Jameson cell, as in ref. [7], pp. 331–363.Google Scholar
- 36.Gallios, G.P., Matis, K.A., and Balabanidis, T.N. (1995) Dissolved-air flotation of fine particles of salt-type minerals, as in ref. [7], pp. 493–516.Google Scholar
- 37.Matis, K.A. and Mavros, P. (1991) (i) Recovery of metals by ion flotation from dilute aqueous solutions, (ii) Foam/froth flotation. [I. Removal of particular matter, Sep. Purif. Methods 20, 1–48 and 163–198.Google Scholar
- 38.Zouboulis, A.I. and Matis, K.A. (1995) Removal of cadmium from dilute solutions by flotation, Wat. Sci. Tech. 31 (3–4), 315–326.CrossRefGoogle Scholar
- 39.Matis, K.A., Papadoyannis, I.N., and Zouboulis, A.I. (1989) Possibilities of Ge recovery from fly ash, Chim. Chron.(New Ser.) 18, 85–97.Google Scholar
- 40.Zouboulis, A.I., Kydros, K.A., and Matis, K.A. (1993) Recovery of gold from thiourea solutions by flotation, Hydrometallurgy 34, 79–90.CrossRefGoogle Scholar
- 41.Lazaridis, N.K. (1991) Selective Removal of Copper, Zinc and Arsenic Ions from Aqueous Solutions by Flotation Techniques, Ph. D. Thesis, Chem. Dept., Aristotle Univ., Thessaloniki.Google Scholar
- 42.Stalidis, G.A., Matis, K.A., and Lazaridis, N.K. (1988) A statistical approach to precipitate flotation of CuS/ZnS, Int. J. Miner. Process. 24, 203–216.CrossRefGoogle Scholar
- 43.Lazaridis, N.K., Matis, K.A., Stalidis, G.A., and Mavros, P. (1992) Dissolved-air flotation of metal ions, Sep. Sci. Tech. 27, 1743–1758.CrossRefGoogle Scholar
- 44.Matis, K.A. and Zouboulis, A.I. (1995) The role of bubble/particle size, as in ref. [7], pp. 63–87.Google Scholar
- 45.Ching, H.-W., Tanaka, T.S., and Elimelech, M. (1994) Dynamics of coagulation of kaolin particles with ferric chloride, Wat. Res. 28, 559–569.CrossRefGoogle Scholar
- 46.Mandjiny, S., Zouboulis, A.I., Zamboulis, D., and Matis, K.A. (1996) Flocculation of hydroxyapatite, Sep. Sci. and Technol., accepted for publication.Google Scholar
- 47.Zouboulis, A.I., Matis, K.A., and Stalidis, G.A. (1992) Flotation in wastewater treatment, as in ref. [9], pp. 475–498.Google Scholar
- 48.Peng, F.F. and Di, P. (1994) Removal of arsenic from aqueous solution by adsorbing colloid flotation, Ind. Eng. Chem. Res. 33, 922–928.CrossRefGoogle Scholar
- 49.Kydros K.A. (1992) A Study of Floatability of Pyrite, Arsenopyrite and their Concentrates, Ph. D. Thesis, Chem. Dept., Aristotle Univ., Thessaloniki.Google Scholar
- 50.Kydros, K.A., Gallios, G.P., and Matis, K.A. (1994) Modification of pyrite and sphalerite flotation by dextrin, Sep. Sci. Tech. 29, 2263–2275.CrossRefGoogle Scholar
- 51.Laskowski, J.S. and Ralston, J. (eds.) (1992) Colloid Chemistry in Mineral Processing, Elsevier, Amsterdam, p. 142.Google Scholar
- 52.Kydros, K.A., Matis, K.A., and Stalidis, G.A. (1993) Cationic flotation of pyrites, J. Coll. Interface Sci. 155, 409–414.CrossRefGoogle Scholar
- 53.Adam, K., Prevosteau, J.M. Kontopoulos, A., Stefanakis, M., and Errington, M. (1990) Applications of process mineralogy on the treatment of Olympias pyrite concentrate, in D.M. Hausen, D.N. Halbe, E.U. Petersen and W.J. Tafuri (eds.), Gold ‘80 Proceed., SME-AIME, Littleton (USA).Google Scholar
- 54.Kydros, K.A. and Matis, K.A. (1995) Processing an auriferous pyrite concentrate in presence of reducing agents, Can. Met. Quart. 34, 15–20.Google Scholar
- 55.Kydros, K.A., Matis, K.A., and Spathis, P.K. (1995) The use of nitrogen in flotation, as in ref. [7], pp. 473–491.Google Scholar
- 56.Rao, S.R., Labonte, G., and Finch, J.A. (1992) Electrochemistry in the plant, as in ref. [9], pp. 57–100.Google Scholar
- 57.Zouboulis, A.I., Kydros, K.A., and Matis, K.A. (1995) Removal of hexavalent chromium anions from solutions by pyrite fines, Wat. Res. 29, 1755–1760.CrossRefGoogle Scholar
- 58.Zouboulis, A.I., Kydros, K.A., and Matis, K.A. (1993) Arsenic (III and V) removal from solutions by pyrite fines, Sep. Sci. Tech. 28, 2449–2463.CrossRefGoogle Scholar
- 59.Zouboulis, A.I., Kydros, K.A., and Matis, K.A. (1992) Adsorbing flotation of copper hydroxoprecipitates by pyrite fines, Sep. Sci. Tech. 27, 2143–2155.CrossRefGoogle Scholar
- 60.Farley, K.J., Dzombak, D.A., and Morel, F.M.M. (1985) A surface precipitation model for the sorption of cations on metal oxides, J. Coll. Interface Sci. 106, 226–242.CrossRefGoogle Scholar
- 61.Mandjiny, S., Zouboulis, A.I., and Matis, K.A. (1995) Removal of cadmium from dilute solutions by hydroxyapatite. Part I. Sorption studies, Sep. Sci. Tech. 30, 2963–2978.CrossRefGoogle Scholar
- 62.Youcai, Z., Zouboulis, A.I., and Matis, K.A. (1996) Removal of molybdate and arsenate from aqueous solutions by flotation, Sep. Sci. Tech., 31, 769–785.CrossRefGoogle Scholar
- 63.Jeffreys, T.H., Ferguson, C.R., and Bennett, P.G. (1991) Biosorption of metal contaminants from acidic mine waters, in R.W. Smith and M. Misra (eds.), Mineral Bioprocessing, TMSAIME, Warrendale, pp. 289–298.Google Scholar
- 64.Solari, P., Zouboulis, A.I, Matis, K.A., and Stalidis, G.A. (1996) Removal of toxic metals by biosorption onto non-living sewage sludge, Sep. Sci. Tech., 31, 1075–1092.CrossRefGoogle Scholar
- 65.Matis, K.A., Zouboulis, A.I., and Hancock, I.C. (1994) Biosorptive flotation in metal ions recovery, Sep. Sci. Tech. 29, 1055–1071.CrossRefGoogle Scholar
- 66.Matis, K.A. and Zouboulis, A.I. (1994) Flotation of cadmium-loaded biomass, Biotech. Bioeng. 44, 354–360.CrossRefGoogle Scholar
- 67.Matis, K.A., Zouboulis, A.I., and Hancock, I.C. (1994) Waste microbial biomass for cadmium ion removal: application of flotation for downstream separation, Bioresource Tech. 49, 253–259.CrossRefGoogle Scholar