Alkenes

  • L. J. Bellamy
Chapter

Abstract

Infra-red absorption bands associated with the various types of double bond have been extensively studied, so that recognition of the presence and type of unsaturation in an unknown compound is usually possible with reasonable certainty, although this depends to some extent on the amount of substitution at the double bond. This is due to the fact that the most characteristic frequencies available for identification arise from CH stretching and deformation vibrations, so that in materials of the type R1 R2C=CHR3 the number of characteristic frequencies is reduced. Unsaturation in compounds of the type R1R2C=CR3R4 is extremely difficult to detect other than in the Raman spectra, as the only remaining characteristic frequency is the C=C stretching mode, the intensity of which is considerably reduced by the symmetry around the bond. A very full review of fundamental work on simple molecules in this field has been given by Sheppard and Simpson [47]. Other useful reviews are those of Lecomte and Naves [80], Gruzdev [81], O’Connor [82], and Dollish et al. [122].

Keywords

Double Bond Complex Molecule Vinyl Ether Vinyl Ester Fluorine Substitution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© L. J. Bellamy 1975

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  • L. J. Bellamy

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