Tetrathiafulvalenes in Macrocyclic and Supramolecular Chemistry: Self Assembly with Tetrathiafulvalenes

  • Jan Becher
  • Zhan-Ting Li
  • Philippe Blanchard
  • Niels Svenstrup
  • Jesper Lau
  • Mogens Brøndsted Nielsen
  • Klaus B. Simonsen
Conference paper

Abstract

We describe that use of stepvise selective protectiondeprotection of tetrathiafulvalene (TTF)-thiolates give rise to either two or three-dimensional macrobicyclic tetrathiafulvalenophanes in high yields by convergent syntheses. Configurationally selective selfassembly of cyclic tetrathiafulvalenes using the cyclic π-acceptor cyclo-bis(paraquat-p-phenylene) yields [2]- or [3]pseudocatenanes. A simple method for the preparation of donor-acceptor tetrathiafulvalenophanes is reported.

Keywords

Radical Cation Supramolecular Chemistry Charge Transfer Salt Convergent Synthesis Stable Radical Cation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

  1. 1.
    G. Schukat, A. M. Richter, E. Fanghänel, Sulfur Rep. 1987, 7, 155CrossRefGoogle Scholar
  2. 1.b)
    G. Schukat, E. Fanghänel, ibid. 1993, 14, 245.CrossRefGoogle Scholar
  3. 2.a)
    T. Jørgensen, T. K. Hansen, J. Becher, Chem. Soc. Rev. 1994, 23, 41CrossRefGoogle Scholar
  4. 2.b)
    M. Adam, K. Müllen, Adv. Mater. 1994, 6, 439.CrossRefGoogle Scholar
  5. 3.a)
    N. Svenstrup, K. M. Rasmussen, T. K. Hansen, J. Becher, Synthesis 1994, 809.Google Scholar
  6. 3.b)
    J. Becher, J. Lau, P. Leriche, P. Mørk, N. Svenstrup, J. Chem. Soc. Chem. Commun. 1994, 2715.Google Scholar
  7. 3.c)
    K. B. Simonsen, N. Svenstrup, J. Lau, O. Simonsen, P. Mørk, G. J. Kristensen and J. Becher, Synthesis, 1996, 407.Google Scholar
  8. 4.
    Z.-T. Li, P. C. Stein, N. Svenstrup, K. H. Lund, J. Becher, Angew. Chem. 1995, 107, 2719; Angew. Chem. Int. Ed. Engl. 1995, 34, 2524.CrossRefGoogle Scholar
  9. 5.
    Zhan-Tinh Li and J. Becher, Chem. Commun., 1996, 639.Google Scholar
  10. 6.
    P. Blanchard, N. Svenstrup and J. Becher, Chem. Commun., 1996, 615.Google Scholar
  11. 7.
    See for example, J. Issberner, R. Moors and F. Vögtle, Angew. Chem. Int. Ed. Engl. 1994, 33, 2413.CrossRefGoogle Scholar
  12. 8.
    Lau, O. Simonsen and J. Becher, Synthesis, 1996, 521.Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 1998

Authors and Affiliations

  • Jan Becher
    • 1
  • Zhan-Ting Li
    • 1
  • Philippe Blanchard
    • 1
  • Niels Svenstrup
    • 1
  • Jesper Lau
    • 1
  • Mogens Brøndsted Nielsen
    • 1
  • Klaus B. Simonsen
    • 1
  1. 1.Department of ChemistryOdense UniversityOdense MDenmark

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