Black Sea Oceanography pp 161-172 | Cite as
Total and Suspended Cadmium, Cobalt, Copper, Iron, Lead, Manganese, Nickel, and Zinc in the Water Column of the Black Sea
Chapter
Abstract
The trace metals cadmium, cobalt, copper, iron, manganese, nickel, lead and zinc were determined at eleven different stations in the Black Sea, in November 1984. Sampling from the surface down to 2100 m was carried out. Suspended matter was collected and analysed. It was found that elements which form strong sulphide complexes show significantly lower concentration in the anoxic zone. A simple scavenging mechanism based on adsorption of sulphides onto organic matter is proposed in order to explain this. The complex behaviour of particles in the oxic/anoxic interface is discussed.
Keywords
Trace Metal Graphite Furnace Atomic Absorption Spectroscopy Anoxic Environment Anoxic Water Benthic Flux
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References
- Andersson R. F., Flisher M. Q., and Letturay A. P. (1989) Concentration, Oxidation State, and Particulate Flux of Uranium in the Black Sea. Geochim. Cosmochim. Acta 53, 2215–2224.CrossRefGoogle Scholar
- Balzer W., Grasshoff K., Dieckmann P., Haardt H. and Petersohn U. (1983) Redox Turnover at the Sediment Water Interface Studied in a Large Bell Jar System. Oceanol. Acta 6, 377–344Google Scholar
- Danielsson L.G., B. Mangnusson, S. Westerlund and K. Zhang (1984) Trace-Metal Determination in Estuarine Waters by AAS after Extraction of Dithiocarbamate Complexes into Freon. Anal. Chim. Acta, 144,183–188.CrossRefGoogle Scholar
- Dyrssen D. (1985) Metal Complex Formation in Sulphidic Seawater. Mar. Chem., 15, 285–293.CrossRefGoogle Scholar
- Dyrssen D. (1991) Anoxic Basin Particulates. Manuscript for IUPAC Monograph. Sampling and Characterization of Environmental Particles., to be published 1991.Google Scholar
- Dyrssen D., P. Hall, C. Haraldsson, Å. Iverfeldt and S. Westerlund (1984) Trace Metals in the Anoxic Bottom Water of Framvaren. In: Complexation of Trace Metals in Natural Waters, Ed:s. Kramer and Duinker. Martinus Nijhoff / Dr W. Junk Publisher, The Hague/Boston/Lancaster, pp. 239–245.Google Scholar
- Dyrssen D., C. Haraldsson, S. Westerlund and K Åren (1986) Report on The Chemistry of seawater, XXXII.Department of Analytical and Marine Chemistry, Chalmers University of Technology and University of Göteborg, S–412 96 Göteborg, Sweden.Google Scholar
- Haraldsson C. and S. Westerlund (1988) Trace Metals in the Water Columns of the Black Sea and Framvaren Fjord. Mar. Chem., 23,417–424.CrossRefGoogle Scholar
- Honjo S., E. Izdar and E.T. Degens (1987) Sesonal Cyclicity of Lithogenic Particle Fluxes at a Southern Black Sea Trap Station. Proceedings from “European Conference on Ocean Fluxes”, Izmir,Turkey.Google Scholar
- Jacobs L. and S. Emerson (1982) Trace Metal Solubility in an Anoxic Ajord. Earth and Plan. Sci. Lett., 60, 237–252.CrossRefGoogle Scholar
- Jacobs L., S. Emerson and J. Skei (1985) Partitioning and Transport of Metals across the 02/H2S Interface in a Permanently Anoxic Basin: Framvaren Fjord, Norway. Geochim. Cosmochim. Acta, 49,1433–1444.CrossRefGoogle Scholar
- Karickhoff W (1981) Semi-Empirical Estimation of Sorption of Hydrophobic Pollutants on Natural Sediments and Soil. Chemoshere, 10, 8, 833–846CrossRefGoogle Scholar
- Laumond F., G. Copin-Montegut, P. Courau and E. Nicolas (1984) Cadmium, Copper and Lead in the Western Mediterranean Sea, Mar. Chem. 15, 251–261CrossRefGoogle Scholar
- Levis B. L. and W. M. Landing (1991) The Biogeochemistry of Manganese and Iron in the Black Sea. Deep-Sea Reserch, SubmittedGoogle Scholar
- Lindstrom C. H. M. (1980) Transformation of Iron Constituents During Early Diagenesis. In Situ Studies of a Baltic Sea Sediment Water Interface. Contrib. Microbial Geochem. No. 4 Dept. Geology, Univ. Stockholm. 162 p.Google Scholar
- Skei J. (1986) The Biogeochemistry of Framvaren NIVA report, Oslo, Norway, 256ppGoogle Scholar
- Spencer D. and P. Brewer 1971 Vertical Advection Diffusion and Redox Potential as Controls on the Distribution of Manganese and Other Trace Metals Dissolved in Waters of the Black Sea. J. Geophys. Res. ,76,5877–5892.CrossRefGoogle Scholar
- Spivack A.J., S.S. Huested and E.A. Boyle (1984) Copper, Nickel and Cadmium in the Surface Waters of the Medeterranean. In: Trace Metals in Sea Water, ed. C.S. Wong et al. Plenum, New YorkGoogle Scholar
- Sundby, B., L.G. Anderson, P.O.J. Hall, Å. Iverfeldt, M.M. Rutgers van der Loeff and S. Westerlund,. (1986) The Effect of Oxygen on Release and Uptake of Cobalt, Manganese, Iron and Phosphate at the Sediment-Water Interface. Geochim. Cosmochim. Acta, 50, 1281–1288.CrossRefGoogle Scholar
- Westerlund S. and B. Magnusson (1982) Report on the Chemistry of Seawater, XXXIV. Department of Analytical and Marine Chemistry, Chalmers University of Technology and University of Goteborg, S–412 96 Goteborg, Sweden.Google Scholar
- Westerlund, S., L.G. Anderson, P.O.J. Hall, Å. Iverfeldt, M.M. Rutgers van der Loeff and B. Sundby (1986) Benthic Fluxes of Cadmium, Copper, Nickel, Zink and Lead in the Coastal Environment. Geochim. Cosmochim. Acta, 50,1289–1296.CrossRefGoogle Scholar
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© Springer Science+Business Media Dordrecht 1991