Sampling and Analysis of Aerosols in the Black Sea Atmosphere

  • G. Hacisalihoglu
  • T. I. Balkas
  • M. Arami
  • I. Ölmez
  • G. Tuncel
Part of the NATO ASI Series book series (ASIC, volume 351)

Abstract

Atmospheric particulate samples were collected over the Black Sea, using cellulose filters during 1988. The chemical composition of atmospheric particles collected near sea level have been analyzed for 39 elements by nondestructive instrumental neutron activation analysis (INAA) and for SO4 =and NO3 - by ion chromatography. With few exceptions elemental concentrations follow log-normal distribution. The Cl/Na ratio was smaller than the corresponding ratio in seawater, owing to evaporation of Cl from sea salt particles as HC1. This ratio is also inversely related to nss-SO4.

Concentrations of elements in the Black Sea atmosphere were found to be intermediate between continental rural sites where local aerosols and long range transported particles affects observed concentrations and a remote marine site where local sources other than the ocean do not exist.

Keywords

Instrumental Neutron Activation Analysis Crustal Contribution Local Aerosol Marine Contribution Crustal Dust 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. Andreiev, B. G. and Lavrinenko, R. F., (1968), “Some data on the chemicalcomposition of atmospheric aerosols over Central Asia, Meteorology Gidrologia. 4, 63–69.Google Scholar
  2. Bates, T. S., Cline, J. D., (1985), “The Role of the Ocean in a Regional Sulfur Cycle”, J. Geophvs. Res., 90, 9168–9172.CrossRefGoogle Scholar
  3. Bates, T. S., Cline, J. D. , Gammon, R. H. , Hansen, S. R. K. , (1987), “Regional and Seasonal Variations in the Flux of Oceanic Dimethlysulfide to the Atmosphere”, J. Geophvs. Res., 92, 2930–2938.CrossRefGoogle Scholar
  4. Coleri, 1989, personnel communication.Google Scholar
  5. Cunnigham, W. C., (1979) Ph. D. Thesis University of Maryland, College ParkGoogle Scholar
  6. Dams, R. J., J. De Jonge, (1976),”Chemical Composition of Swiss Aerosols From the Jungfraujoch”, Atmos. Environ., 10, 1079–1084.CrossRefGoogle Scholar
  7. Duce, R.A., Arimoto, R. , Ray, B.J., Unni, C.K., Harder, P.J., (1983), „Atmospheric Trace Elements at Enewetak Atoll: 1. Concentrations, Sources and Temporal Variability.“, J . Geophvs. Res., 88, 5321–5342.CrossRefGoogle Scholar
  8. Dulac, F., Buat-Ménard, P., Arnold, M., Ezat, U., (1987), “Atmospheric Input of Trace Metals to the Western Mediterranean Sea: 1. Factors Controlling the Variability of Atmospheric Concentrations.”, J. Geophvs. Research. Vol.92, 8437–8453.CrossRefGoogle Scholar
  9. Dutkiewicz, V. A., P. P. Parekh, L. Husain (1986) “An Evaluation of Regional Elemental Signitures Relevant to the Northeastern United States”, Atmos. Environ., 21, 1033–1044.Google Scholar
  10. Dzubay, T. G., R. K. Stevens, P. L. Haagenson (1984),”Composition and Origins of Aerosol at a Forested Mountain in Soviet Georgia”.Environ. Sci. Technol.. 18, 873–883.CrossRefGoogle Scholar
  11. Galasyn, J. F., K. L. Tschudy, B. J. Huebert, (1987), “Seasonal and Diurnal Variability of Nitric Acid Vapor and Ionic Aerosol Species in the remote Free Troposphere”, J. Geophvs. Res., 92, 3105–3113.CrossRefGoogle Scholar
  12. Germani, M. S., I. Gokmen, A C. Sigleo, G. S. Kowalczyk, I. Olmez, A. M. Small, D. L. Anderson, M. P. Failey, M. C. Gulovali, C. E. Choquette, E. A. Lepel, G. E. Gordon, W. H. Zoller, (1980), “Concentrations of Elements in the NBS Bituminous and Subbituminous Coal Standard Reference Materials”, Anal. Chem., 52, 240.CrossRefGoogle Scholar
  13. GESAMP (IMO/FAO/UNESCO/WMO/IAEA/UN/UNEP Joint Group of Experts on the Scientific Aspects of Marine Pollution): Atmospheric transport of contaminants into the Mediterranean region, UNEP Regional Seas Reports and Studies No. 68, UNEP, 1985.Google Scholar
  14. Goldberg, E. D., (1963), “The Oceans as a Chemical System”, The Sea. Ed. by M. N. Hill, Vol. 2, Ch. 1, Interscience, NY.Google Scholar
  15. Hopke, P.K., E.S. Gladney, G.E. Gordon, W.H. Zoller, A.G. Jones, (1976), Atmos. Environ., 10, 1015–1025.CrossRefGoogle Scholar
  16. Kowalczyk, G. S., G. E. Gordon, S. W. Rheingrover (1982), “Identification of Atmospheric Particulate Sources in Washington, D.C., Using Chemical Element Balances”, Environ. Sci. Technol., 16, 79–90.CrossRefGoogle Scholar
  17. Legrand, M. R., Delmas, R. J., (1986), “Relative Contributions of Tropospheric and Stratospheric Sources to Nitrate in Antarctic Snow”, Tellus, 38B, 236–249CrossRefGoogle Scholar
  18. Meszaros, E., (1978), “Concentration of Sulfur Compounds In Remote Continental and Oceanic Areas”, Atmos. Environ., 12, 699–705.CrossRefGoogle Scholar
  19. Pacyna, J.M., Semb, A. and Hanssen, J.E., (1984), “Emission and Long-Range Transport of Trace Elements in Europe”, Tellus. 36B, pp.163–178.CrossRefGoogle Scholar
  20. Pacyna. J. M., B. Ottar (1989), “Origin of natural nonstituents in the Arctic aerosol” Atmos. Environ., 23, 809–815, 2A14CrossRefGoogle Scholar
  21. Raemdonck, H., W. Maenhaut, M. O. Andrea (1986) “ Chemistry of Marine Aerosol Over the Trophical and Equatorial Pacific”, J. Geophys.Res., 91, 8623–8636.CrossRefGoogle Scholar
  22. Taylor, R., (1964), “Abundance of Chemical Elements in the Continental Crust: A New Table”, Geochim. Cosmochim.Acta, 28, 1273.CrossRefGoogle Scholar
  23. Thurston, G. D., J.D. Spengler, (1985), Atmos. Environ., 19, 9–25.CrossRefGoogle Scholar
  24. Tomza, U., W. Maenhaut, J. Cafmeyer, (1982), “Trace Elements in Atmospheric Aerosols at Katowice, Poland” in Trace Substances in Environmental Health. D. D. Hemphill, Ed., 105–115.Google Scholar
  25. Tuncel, G. (1984), Ph.D thesis, University of Maryland, College Park.Google Scholar
  26. Tuncel, G. , N. K. Aras, W. H. Zoller, (1989), “Temporal Variations and Sources of Elements in the South Pole Atmosphere: 1. Non-Enriched and Moderately Enriched Elements” J. Geophvs. Res., 94, 13025–13039.CrossRefGoogle Scholar
  27. Watts, S. F., R. Yaaqub, T. Davies, (1987), “The use of Whatman 41 filter papers for high volume aerosol sampling”, Atmos. Environ., 21, 2731–2736.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 1991

Authors and Affiliations

  • G. Hacisalihoglu
    • 1
  • T. I. Balkas
    • 1
  • M. Arami
    • 1
  • I. Ölmez
    • 1
    • 2
  • G. Tuncel
    • 1
  1. 1.Environmental Engineering DepartmentMiddle East Technical UniversityAnkaraTurkey
  2. 2.Nuclear Reactor LaboratoryMassachusets Institute of TechnologyCambridgeUSA

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