Electrode Processes in Solid State Ionics pp 277-308 | Cite as
Ion Transfer at the Interface Between an Electronic and Ionic Conductor
Conference paper
Abstract
At the interface between a metal or semiconductor and an electrolyte (liquid or solid), the initial and final states of an ion transfer reaction are extremely different with respect to their chemical interaction with the surroundings. In the electronic conductor the binding is predominantly metallic or covalent while in the electrolyte the electrostatic forces are prevailing. This results in an energy barrier of often considerable height since an intermediate state has to be passed in which neither this nor the other type of interaction is fully developed.
Keywords
Ionic Conductor Minority Carrier Depletion Layer Space Charge Layer Current Voltage Curve
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References
- (1).V. A. Myamlin and Y. V. Pleskov “Electrochemistry of Semiconductors”, Plenum Press, New York 1967Google Scholar
- (2).H. Gerischer in “Physical Chemistry” Vol. IX A (edited by H. Eyring, D. Henderson, W. Jost) Academic press, New York 1970Google Scholar
- (3).A. Many, Y. Goldstein, and N. B. Grover “Semiconductor Surfaces” North Holland Publ. Co., Amsterdam 1965Google Scholar
- (4).R. H. Kingston and S. F. Nuestadter J. Appl. Phys. 26, 718 (1955)CrossRefGoogle Scholar
- (5).M.J. Spaarney, “The Electrical Double Layer” The International Encyclopedia of Physical Chemistry and Chemical Physics, Vol. 4, Pergamon Press, Oxford 1972Google Scholar
- (6).H. Gerischer, M. Hofmann-Perez and W. Mindt,Ber. Bunsenges. Phys. Chem. 69, 130 (1965)Google Scholar
- (7).N.F. Mott, Proc. Royal Soc. (London) A 171, 27 (1939)CrossRefGoogle Scholar
- (8).W. Schottky, Z. Phys. 113, 367 (1939)CrossRefGoogle Scholar
- (9).J.F. Dewald, Bell Syst. Techn. J. 39, 615 (1960)Google Scholar
- (10).C.G.B. Garrett and W.H. Brattain Phys. Rev. 99, 376 (1955)CrossRefGoogle Scholar
- (11).P.J. Boddy and W.H. Brattain Ann. N.Y. Academy Sci. 101, 683 (1963)CrossRefGoogle Scholar
- (12).F. Lohmann, Z. Naturforsch. 22a, 813 (1967)Google Scholar
- (13).H. Gerischer and W. Mindt Electrochim. Acta 13, 1329 (1968)CrossRefGoogle Scholar
- (14).H. Genscher, Surface Sci. 13; 265 (1969)CrossRefGoogle Scholar
- (15).W.H. Brattain and C.G.B. Garrett Bell Syst. Techn. J. 34, 129 (1955)Google Scholar
- (16).F. Beck and H. Genscher Z. Elektrochem. 63, 500 (1959)Google Scholar
- (17).P.J. Boddy, J. Electrochem. Soc. 111, 1136 (1964)CrossRefGoogle Scholar
- (18).P.F. Schmidt and W. Michel J. Electrochem. Soc. 104, 230 (1957)CrossRefGoogle Scholar
- (19).R. Memming and G. Schwandt Surface Sci. 4, 109 (1966)CrossRefGoogle Scholar
- (20).J. Taue, “Photo- and Thermoelectric Effects in Semiconductors”, Pergamon Press, Oxford 1962Google Scholar
- (21).F. Beck and H. Genscher Z. Elektrochem. 63, 943 (1959)Google Scholar
- (22).H. Gerischer Z. phys. Chem. (Frankfurt) 27, 48 (1961)CrossRefGoogle Scholar
- (23).H. Gerischer and I. Mattes Z. phys. Chem. (Frankfurt), 49, 112 (1966)CrossRefGoogle Scholar
- (24).H. Kiess and R. Williams J. Chem. Phys. 32, 1505 (1960)CrossRefGoogle Scholar
- (25).B. Pettinger, H.R. Schoppel, T. Yokoyama, and H. Gerischer Ber. Bunsenges. Phys. Chem. 78, 1024 (1974)Google Scholar
- (26).H.R. Schoppel and H. Gerischer Ber. Bunsenges. Phys. Chem., 75 1237 (1971)Google Scholar
- (27).H. Gerischer Advances in Electrochemistry and Electrochem. Engin. 1 139 (1961)Google Scholar
- (28).H. Gerischer, B. Pettinger, and M. Lübke “Proceedings of the Symposium on Electrocatalysis”, The Electrochemical Soc., 1974, p. 162Google Scholar
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© D. Reidel Publishing Company, Dordrecht, Holland 1976