Asymmetric Hydrogenation

  • F. J. McQuillin
Chapter
Part of the Homogeneous Catalysis in Organic and Inorganic Chemistry book series (CMCO, volume 1)

Abstract

Inspection of the alkene-metal hydride complex (1) in which the ligand X(SML) is asymmetrically substituted, indicates that steric or polar interaction between the groups S, M and L and the alkene substituents a, b, c, d should discriminate between alternative modes of co-ordination of the alkene i.e. between adducts (1) and (2).

Keywords

Phosphine Oxide Grignard Reagent Optical Yield Rhodium Complex Diethyl Ester 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© D. Reidel Publishing Company, Dordrecht, Holland 1976

Authors and Affiliations

  • F. J. McQuillin
    • 1
  1. 1.University of Newcastle upon TyneEngland

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