The Reality of Some Bond Properties Additive Systems: Faraday Effect and Bond Magnetic Rotations

  • Fernand G. Gallais
Part of the Localization and Delocalization in Quantum Chemistry book series (LDQC, volume 2)

Abstract

This paper which mainly reports experimental data might appear to be out of place in a theoretical discussion on electronic localization in molecules. Still it seems justified by the fact that these data are treated as bond specific moduli, as it is clearly impossible to think of bond moduli in the absence of localized bonds or at least in the absence of privileged space zones in which the electronic charge density should have a relatively high value and to a certain extent a specific one.

Keywords

Magnetic Susceptibility Secondary Alcohol Bond Rotation Molecular Rotation Faraday Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Gallais, F. and Voigt, D.: Bull. Soc. Chim. Fr., p.70 (1960).Google Scholar
  2. 2.
    Pascal, P.: Ann. Chim. Phys. 19, p. 70 (1910);Google Scholar
  3. Lemoult, P.: Rev. Gen. Sci. Pures Appl. 19, p. 137 (1908);Google Scholar
  4. Von Steiger, A. L.: Ber. 54, p. 1381 (1921);Google Scholar
  5. Pascal, P., Pacault, A., and Hoarau, J.: C.R. 233, p. 1078 (1951).Google Scholar
  6. 3.
    Gallais, F. and Labarre, J.-F.: C.R. 263, p. 1202 (1966);Google Scholar
  7. Gallais, F., Labarre, J.-F., and de Loth, Ph.: J. Chim. Phys. 64, p. 247 (1967).Google Scholar
  8. 4.
    Guy, J. and Tillieu, J.: C.R. 241, 1955, p. 382; J. Chem. Phys. 24, p. 1117 (1956);Google Scholar
  9. Baudet, J., Tillieu, J., and Guy, J.: C.R. 244, p. 1756 and 2920 (1957).Google Scholar
  10. 5.
    Laurent, J.-P.: C.R. 252, p. 3785 (1961);Google Scholar
  11. Laurent, J.-P. and Pasdeloup, M.: C.R. 256, p. 133 (1963);Google Scholar
  12. Laurent, J.-P.: C.R. 258, p. 1481 (1964);Google Scholar
  13. Gallais, F., Laurent, J.-P., and Cros, G.: C.R. 259, p. 4262 (1964);Google Scholar
  14. Cros, G. and Laurent, J.-P.: C.R. 265 (C), p. 1065 (1967);Google Scholar
  15. Laurent, J.-P. and Bonnet, J.-P.: Bull. Soc. Chico. Fr., p. 1447 (1966);Google Scholar
  16. Laurent, J.-P. and Pasdeloup, M.: C.R. 261, p. 4725 (1965);Google Scholar
  17. Laurent, J.-P. and Berthalon, J.-P.: Bull. Soc. Chim. Fr., p. 766 (1965).Google Scholar
  18. 5.
    bis. de Loth, Ph.: Thèse Doctorat Sciences Physiques, Toulouse, (1967);Google Scholar
  19. Haran, R. and Laurent, J.-P.: Bull. Soc. Chim. Fr., p. 3454 (1966).Google Scholar
  20. 6.
    Cf., Mikhailov, B. M., Shchegoleva, T. A., and Bubnov, Yu. N.: Izvest. Akad. S.S.S.R. Nauk, Otdel. Khim. Nauk, p. 413 (1962).Google Scholar
  21. Gillis, R. G.: Defence Standards Laboratories (Australia), Technical Note No. 51, July 1959;Google Scholar
  22. Sayre, R.: J. Amer. Chem. Soc. 80, p. 5438 (1958);CrossRefGoogle Scholar
  23. 7.
    Pascal, P., Voigt, D., Labarre, M.-C., and Fournes, L.: C.R. 262 (C), p. 1481 (1966);Google Scholar
  24. Voigt, D. and Labarre, M.-C.: Bull. Soc. Chico. Fr., p. 1583 (1967);Google Scholar
  25. Labarre, M.-C., Voigt, D., and Gallais, F.: Bull. Soc. Chim. Fr., p. 3328 (1967).Google Scholar
  26. 8.
    Gallais, F. and Voigt, D.: Bull. Soc. Chim. Fr., p. 1935 (1963);Google Scholar
  27. Mila, J.-P. and Labarre, J.-F.: C.R. 263 (C), p. 1481 (1966);Google Scholar
  28. Mila, J.-P. and Labarre, J.-F.: C.R. 264 (C), p. 1157 (1967).Google Scholar
  29. 9.
    Laurent, J.-P.: C.R. 256, p. 3283 (1963).Google Scholar
  30. 10.
    Gallais, F., Labarre, J.-F., and de Loth, Ph.: J. Chim. Phys. 63, p. 1175 (1966); 64, p.247 (1967); Voigt, D., Turpin, R., and Labarre, M.-C.: Bull. Soc. Chim. Fr., p. 3561 (1968).Google Scholar
  31. 11.
    Gallais, F. and Voigt, D.: Bull. Soc. Chico. Fr., p. 70 (1960).Google Scholar
  32. 12.
    Gallais, F. and Labarre, J.-F.: C.R. 263 (C), p. 1202 (1960).Google Scholar
  33. 13.
    Gallais, F., Labarre, J.-F., Voigt, D., and de Loth, Ph.: J. Chim. Phys. 63, p. 1175 (1966).Google Scholar

Copyright information

© D. Reidel Publishing Company, Dordrecht, Holland 1976

Authors and Affiliations

  • Fernand G. Gallais
    • 1
  1. 1.Laboratoire de Chimie de Coordination du CNRSToulouse, CedexFrance

Personalised recommendations