Light Emitting Devices Based On Silicon Nanocrystals

  • A. Irrera
  • D. Pacifici
  • M. Miritello
  • G. Franzò
  • F. Priolo
  • F. Iacona
  • P. G. Fallica
  • G. Di Stefano
  • D. Sanfilippo
Chapter
Part of the NATO Science Series book series (NAII, volume 93)

Abstract

Silicon has for a long time been considered unsuitable for optoelectronic applications. Due to the indirect nature of its energy band gap, bulk silicon is indeed a highly inefficient light source. Many efforts have been devoted towards the development of Si-based materials able to act as light emitters [1]. Quantum confinement in Si nanostructures, including porous Si [2], Si nanocrystals (nc) embedded in SiO2 [3], and Si/SiO2 su- perlattices [12], and rare earth doping of silicon have dominated the scientific scenario of silicon-based microphotonics. In particular, Si nc embedded in SiO2 have attracted a great attention, due to their high stability and to their full compatibility with Si technology. Si nc are characterized by an energy band gap which is enlarged with respect to bulk Si, and exhibit an intense and tunable room temperature photoluminescence (PL) in the visible-near IR range [15]. Si nc embedded in SiO2 are produced with several different techniques, such as ion implantation [4], chemical vapor deposition [11], sputtering and laser ablation [16]. Recently, the interest towards this material is greatly increased due to the first observation of light amplification in Si nanostructures [18].

Keywords

Excitation Cross Section Radiative Rate Silicon Nanocrystals Radiative Decay Rate SiOx Layer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Iyer, S.S., and H. Xie, Y., (1993) Light-emission from silicon, Science 260, 40–46.ADSCrossRefGoogle Scholar
  2. 2.
    Cullis, A. G., T. Canham, L., Calcott, P. D. J., (1997) The structural and luminescence properties of porous silicon, J. Appl. Phys. 82, 909–965.ADSCrossRefGoogle Scholar
  3. 3.
    Kanemitsu, Y., Ogawa, T., Shiraishi, K., and Takeda, K., (1993) Visible photoluminescence from oxidized Si nanometer-sized spheres: Exciton confinement on a spherical shell, Phys. Rev. B 48, 4883.ADSCrossRefGoogle Scholar
  4. 4.
    Shimizu-Iwayama, T., Fujita, K., Nakao, S., Saitoh, K., Fujita, T., and Itoh, N., (1994) Visible photoluminescence in Si+-implanted silica glass, J. Appl. Phys. 75, 7779–7783.ADSCrossRefGoogle Scholar
  5. 5.
    Zhu, J.G., White, C.W., Budai, J.D., Withrow, S.P., and Chen, Y., (1995) Growth of Ge, Si, and SiGe nanocrystals in SiO2 matrices, J. Appl. Phys. 78, 4386–4389.ADSCrossRefGoogle Scholar
  6. 6.
    Min, K.S., Shcheglov, K.V., Yang, C.M., Atwater, H.A., Brongersma, M.L., and Polman, A., (1996) Defect-related versus excitonic visible light emission from ion beam synthesized Si nanocrystals in SiO2, Appl. Phys. Lett. 69, 2033–2035.ADSCrossRefGoogle Scholar
  7. 7.
    Brongersma, M.L., Polman, A., Min, K.S., Boer, E., Tambo, T., and Atwater, H.A., (1998) Tuning the emission wavelength of Si nanocrystals in SiO2 by oxidation, Appl. Phys. Lett. 72, 2577–2579.ADSCrossRefGoogle Scholar
  8. 8.
    Klimov, V.I., Schwarz, Ch., McBranch, D., and White, C.W., (1998) Initial carrier relaxation dynamics in ion-implanted Si nanocrystals: Femtosecond transient absorption study, Appl Phys. Lett. 73, 2603–2605.ADSCrossRefGoogle Scholar
  9. 9.
    Shimizu-Iwayama, T., Kunumado, N., Hole, D.E., and Townsend, P., (1998) Optical properties of silicon nanoclusters fabricated by ion implantation, J. Appl. Phys. 83, 6018–6022.ADSCrossRefGoogle Scholar
  10. 10.
    Linnros, J., Lalic, N., Galeckas, A., and Grivickas, V., (1999) Analysis of the stretched exponential photoluminescence decay from nanometer-sized silicon crystals in SiO2, J. Appl. Phys. 86, 6128–6134.ADSCrossRefGoogle Scholar
  11. 11.
    Iacona, F., Franzò, G., and Spinella, C., (2000), Correlation between luminescence and structural properties of Si nanocrystals, J. Appl. Phys. 87, 1295–1303.ADSCrossRefGoogle Scholar
  12. 12.
    Lu, Z.H., Lockwood, D.J., and Baribeau, J.M., (1995), Quantum confinement and light-emission in SiO2/Si superlattices, Nature 378, 258–260.ADSCrossRefGoogle Scholar
  13. 13.
    Vinciguerra, V., Franzò, G., Priolo, F., Iacona, F., and Spinella, C., (2000) Quantum confinement and recombination dynamics in silicon nanocrystals embedded in Si/SiO2 superlattices, J. Appl. Phys. 87, 8165–8173.ADSCrossRefGoogle Scholar
  14. 14.
    Photopoulos, P., Nassiopoulou, A.G., Kouvatsos, D.N., and Travlos, A., (2000) Photoluminescence from nanocrystalline silicon in Si/SiO2 superlattices, J. Appl. Phys. 76, 3588–3590.Google Scholar
  15. 15.
    Priolo, F., Franzò, G., Pacifici, D., Vinciguerra, V., Iacona, F., and Irrera, A., (2001) Role of the energy transfer in the optical properties of undoped and Er-doped interacting Si nanocrystals, J. Appl. Phys. 89, 264–272.ADSCrossRefGoogle Scholar
  16. 16.
    Hayashi, S., Nagareda, T., Kanzawa, Y., and Yamamoto, K., (1993) Photoluminescence of Si-rich SiO2-films — Si clusters as luminescent centers, Jpn. J. Appl. Phys. 32, 3840–3845.ADSCrossRefGoogle Scholar
  17. 17.
    Werwa, E., Seraphin, A.A., Chin, L.A., Zhou, C., and Kolenbrander, K.D., (1994) Synthesis and processing of silicon nanocrystallites using a pulsed laser ablation supersonic expansion method, Appl. Phys. Lett. 64, 1821–1823.ADSCrossRefGoogle Scholar
  18. 18.
    Pavesi, L, Dal Negro, L, Mazzoleni, C., Franzò, G, Priolo, F, (2000) Optical gain in silicon nanocrystals, Nature 408, 440–444.ADSCrossRefGoogle Scholar
  19. 19.
    Franzò, G., Priolo, F., Coffa, S., Polman, A., Camera, A., (1994) Room-temperature electroluminescence from Er-doped crystalline Si, Appl. Phys. Lett. 64, 2235–2237.ADSCrossRefGoogle Scholar
  20. 20.
    Kenyon, A.J., Trwoga, P.F., M. Federighi, and C.W. Pitt, (1994) Optical-properties of PECVD erbium-doped silicon-rich silica — evidence for energy-transfer between silicon microclusters and erbium ions, J. Phys.: Condens. Matter 6, L319–L324.ADSCrossRefGoogle Scholar
  21. 21.
    Fujii, M., Yoshida, M., Kanzawa, Y., Hayashi, S., and Yamamoto, K., (1997) 1.54 μm photoluminescence of Er3+ doped into SiO2 films, containing Si nanocrystals: Evidence for energy transfer from Si nanocrystals to Er3+, Appl. Phys. Lett. 71, 1198–1200.ADSCrossRefGoogle Scholar
  22. 22.
    Franzò, G., Vinciguerra, V., and Priolo, F., (1999) The excitation mechanism of rare-earth ions in silicon nanocrystals, Appl. Phys. A 69, 3–12.ADSCrossRefGoogle Scholar
  23. 23.
    Franzò, G., Pacifici, D., Vinciguerra, V., Iacona, F., and Priolo, F., (2000) Er3+ ions-Si nanocrystals interactions and their effects on the luminescence properties, Appl. Phys. Lett. 76, 2167–2169.ADSCrossRefGoogle Scholar
  24. 24.
    Franzò, G., Irrera, A., C. Moreira, E., Miritello, M., Iacona, F., Sanfilippo, D., Di Stefano, G., Fallica, P.G., and Priolo, F., (2002) Electroluminescence of silicon nanocrystals in MOS structures, Appl. Phys. A 74, 1–5.ADSCrossRefGoogle Scholar
  25. 25.
    Irrera, A., Pacifici, D., Miritello, M., Franzò, G., Priolo, F., Iacona, F., Sanfilippo, D., Di Stefano, G., and Fallica, P.G., (2002) Excitation and de-excitation properties of silicon quantum dots under electrical pumping, Appl. Phys. Lett. 81, 1866–1868.ADSCrossRefGoogle Scholar
  26. 26.
    Calcott, P.D.J., Nash, K.J., Canham, L.T., Kane, M. J., and Brumhead, D., (1993) Identification of radiative transitions in highly porous silicon, J. Phys. Condens. Matter 5, L91–L98.ADSCrossRefGoogle Scholar
  27. 27.
    Brongersma, M.L., Kik, P.G., Polman, A., Min, K.S., and Atwater, H.A., (2000) Size-dependent electron-hole exchange interaction in Si nanocrystals, Appl. Phys. Lett. 76, 351–353.ADSCrossRefGoogle Scholar
  28. 28.
    Yu. Kobitski, A., Zhuravlev, K.S., Wagner, H.P., and Zahn, D.R.T., (2001) Self-trapped exciton recombination in silicon nanocrystals, Phys. Rev. B 63, 115423-1-115423-5.Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2003

Authors and Affiliations

  • A. Irrera
    • 1
  • D. Pacifici
    • 1
  • M. Miritello
    • 1
  • G. Franzò
    • 1
  • F. Priolo
    • 1
  • F. Iacona
    • 2
  • P. G. Fallica
    • 3
  • G. Di Stefano
    • 3
  • D. Sanfilippo
    • 3
  1. 1.INFM and Dipartimento di Fisica e AstronomiaUniversità di CataniaCataniaItaly
  2. 2.CNR-IMM, Sezione di CataniaCataniaItaly
  3. 3.STMicroelectronicsCataniaItaly

Personalised recommendations