Intermolecular Interactions Involving First Row Hydrides: Spectroscopic Studies of Complexes of HF, H2O, NH3, and HCN

  • K. I. Peterson
  • G. T. Fraser
  • D. D. NelsonJr.
  • W. Klemperer

Abstract

This article reviews the structural characterization, by means of rotational spectroscopy, of a number of complexes of HF, H2O, NH3, and HCN. In addition to the complexes of each of these hydrides with each other, the complexes with CO, CO2, C2H2, and C2H4 are also examined. The studies of the complexes of NH3 are complemented by recently obtained infrared-microwave double resonance results.

Keywords

Dipole Moment Rotational Constant Water Complex Quadrupole Coupling Constant Induce Dipole Moment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    F. Franks, “Water, A Comprehensive Treatise,” Vol. 4–6, (Plenum, New York, 1972).Google Scholar
  2. 2.
    R. Taylor and O. Kennard, Acc. Chem. Res. 17, 320 (1984).CrossRefGoogle Scholar
  3. 3.
    G.C. Pimentel and A.D. McClellan, “The Hydrogen Bond,” (Freeman, San Francisco, 1960).Google Scholar
  4. 4.
    T.C. English and J.C. Zorn, “Methods of Experimental Physics,” Vol. 3 (2nd Edition), D. Williams, ed. (Academic Press, Inc., New York, 1972).Google Scholar
  5. 5.
    T.J. Balle, E.J. Campbell, M.R. Keenam and W.H. Flygare, J. Chem. Phys. 71, 2723 (1979).CrossRefGoogle Scholar
  6. 6.
    Z. Kisiel, A.C. Legon and D.J. Milien, Proc. R. Soc. London A 381 , 419 (1982).Google Scholar
  7. 7.
    G.T. Fraser, D.D. Nelson, Jr., A. Charo and W. Klemperer, J. Chem. Phys., to be published.Google Scholar
  8. 8.
    S.A. Clough, Y. Beers, G.P. Klein and L.S. Rothman, J. Chera. Phys. 59, 2254 (1973).CrossRefGoogle Scholar
  9. 9.
    M.D. Marshall and J.S. Muenter, J. Mol. Spect. 85, 322 (1981).CrossRefGoogle Scholar
  10. 10.
    J.S. Muenter and W. Klemperer, J. Chem. Phys. 52, 6033 (1970).CrossRefGoogle Scholar
  11. 11.
    J.S. Muenter, J. Mol. Spec. 55, 490 (1975).CrossRefGoogle Scholar
  12. 12.
    W.L. Ebenstein and J.S. Muenter, J. Chem. Phys. 80, 3989 (1984).CrossRefGoogle Scholar
  13. 13.
    T.R. Dyke, K.M. Mack and J.S. Muenter, J. Chem. Phys. 66, 498 (1977).CrossRefGoogle Scholar
  14. 14.
    K.I. Peterson and W. Klemperer, J. Chem. Phys. 81, 3842 (1984).CrossRefGoogle Scholar
  15. 15.
    T.R. Dyke, Top. Current Chem. 120, 85 (Spring-Verlag, N.Y., 1984).Google Scholar
  16. 16.
    T.A. Fisher, K.I. Peterson and W. Klemperer, work in progress.Google Scholar
  17. 17.
    K.I. Peterson and W. Klemperer, J. Chem. Phys., manuscript in preparation.Google Scholar
  18. 18.
    P.D. Aldrich, A.C. Legon and W.H. Flygare, J. Chem. Phys. 75, 2126 (1981).CrossRefGoogle Scholar
  19. 19.
    A.J. Fillery-Travis, A.C. Legon and L.C. Willoughby, Chem. Phys. Lett. 98, 369 (1983).CrossRefGoogle Scholar
  20. 20.
    C.R. Quade, J. Chem. Phys. 47, 1073 (1967).CrossRefGoogle Scholar
  21. 21.
    M.J. Frisch, J.A. Pople and J.E. Del Bene, J. Chem. Phys. 78, 4063 (1983).CrossRefGoogle Scholar
  22. 22.
    G.T. Fraser, K.R. Leopold and W. Klemperer, J. Chem. Phys. 80, 1423 (1984).CrossRefGoogle Scholar
  23. 23.
    G.T. Fraser, K.R. Leopold, D.D. Nelson, Jr., A. Tung and W. Klemperer, J. Chem. Phys. 80, 3073 (1984).CrossRefGoogle Scholar
  24. 24.
    B.J. Howard, private communication.Google Scholar
  25. 25.
    G.T. Fraser, K.R. Leopold and W. Klemperer, J. Chem. Phys. 81, 2577 (1984).CrossRefGoogle Scholar
  26. 26.
    G.T. Fraser, D.D. Nelson, Jr. and W. Klemperer, work in progress.Google Scholar
  27. 27.
    Z. Latajka and S. Scheiner, J. Chem. Phys. 81, 407 (1984) and references therein.CrossRefGoogle Scholar
  28. 28.
    R.L. DeLeon and J.S. Meunter, J. Chem. Phys. 72, 6020 (1980).CrossRefGoogle Scholar
  29. 29.
    The 10 K rotational temperature of the van der Waals dimers is suggested by previous microwave studies of weakly bound complexes. See, for example, K.R. Leopold, G.T. Fraser and W. Klemperer, J. Chem. Phys. 80, 1039 (1984).CrossRefGoogle Scholar

Copyright information

© D. Reidel Publishing Company 1985

Authors and Affiliations

  • K. I. Peterson
    • 1
  • G. T. Fraser
    • 1
  • D. D. NelsonJr.
    • 1
  • W. Klemperer
    • 1
  1. 1.Department of ChemistryHarvard UniversityCambridgeUSA

Personalised recommendations