A Mathematical Model for Acidification and Neutralization of Soil Profiles Exposed to Acid Deposition

  • Harald U. Sverdrup
  • Per G. Warfvinge
  • Ulf von Brömssen
Conference paper

Abstract

A simple model for soil acidification describes the observed pH and base saturation profiles in a Swedish podzol affected by acid deposition. The model is based on a mechanistic respresentation of ion exchange and the weathering rate and is based on a mass balance for calcium and alkalinity. The model has been extended to include a dynamic model for dissolution of limestone in soils. This model has a potential use as a tool for planning and evaluation of different terrestial liming operations.

Keywords

Acid Deposition Base Saturation Cation Exchange Reaction Soil Liming Lund Institute 
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References

  1. (1).
    M. Lagache. Contribution a l’etude de la alteration des feldspats, dans l’eau, entre 100 et 200 °C, sous diverse pressions de CO2, et application a la synthese des minerals argileux. Bull. Soc. Franc. Miner. Christ., 223–253, 1965.Google Scholar
  2. (2).
    L. Chou and R. Wollast. Steady state kinetics and dissolution mechanisms of albite. American Journal of Science, 285: 963–993, 1985.CrossRefGoogle Scholar
  3. (3).
    H. Sverdrup and P. Warfvinge. The Kinetics of Mineral Weathering. Technical Report, Department of Chemical Engineering II, Lund Institute of Technology, 1987.Google Scholar
  4. (4).
    E.P. Manley and L.J. Evans. Dissolution of feldspars by low molecular weight aliphatic and aromatic acids. Soil Science, 141: 106–112, 1986.CrossRefGoogle Scholar
  5. (5).
    D.E. Grandstaff. The dissolution rate of forsteritic olivine from hawaiian beech sand. In 3rd In-ternational water-rock interaction symposium, Geochem. cosmochim. soc, Alberta research council, 1980.Google Scholar
  6. (6).
    S. Bergström, B. Carlsson, G. Sandberg, and L. Maxe. Integrated modelling of runoff, alkalinity and ph on a daily basis. Nordic Hydrology, 16: 89 - 104, 1985.Google Scholar
  7. (7).
    H. Sverdrup and P. Warfvinge. Upplösning av kalksten och andra neutralisationsmedel i mark. SNV Report 3311, Statens Naturvärdsverk, Solna, Sweden, 1987.Google Scholar
  8. (8).
    P. Warfvinge and H. Sverdrup. Upplösning av kalksten i sura, stagnanta vattenlösningar (Disso-lution of calcite in an acid, stagnant aqueous system). Technical report, Department of Chemical Engineering II, Lund Institute of Technology, 1987.Google Scholar
  9. (9).
    P. Warfvinge. Neutralization of soil sytems. CODEN L UTKDH/TKKT/1002/1-220/1986, De-partment of Chemical Engineering II, Lund Institute of Technology, 1986. Licentiate Thesis.Google Scholar
  10. (10).
    P. Warfvinge and H. Sverdrup. Upplösning av kalksten i mark - vatmarkskalkning (dissolution of calcite in soils - wetland liming). Vatten, 43: 59 - 64, 1987.Google Scholar

Copyright information

© ECSC, EEC, EAEC, Brussels and Luxembourg 1988

Authors and Affiliations

  • Harald U. Sverdrup
    • 1
  • Per G. Warfvinge
    • 1
  • Ulf von Brömssen
    • 2
  1. 1.Departement of Chemical EngineeringLund Institute of TechnologyLundSweden
  2. 2.Swedish Environmental Protection Board (SNV)SolnaSweden

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