Skip to main content
SpringerLink
Log in

Gas — Solid Interphase: Characterization by Infrared Spectroscopies

  • Chapter
Photocatalysis and Environment

Part of the book series: NATO ASI Series ((ASIC,volume 237))

Abstract

Infrared techniques give relevant and detailed information on: a) the structure of sites exposed on the surface of catalysts, b) the chemical nature and the structure of adsorbed species and c) the interactions in the adsorbed layer. The use of CO as a classic “probe” molecule is illustrated by the I.R. spectra obtained with model systems such as NiO and MgO. Carbon monoxide adsorption studies contributed to the characterization of active sites and to the understanding of the polymerization mechanism on the chromia-silica Phillips catalyst. The use of infrared spectroscopy to study the formation of anionic species by heterolytic dissociation of H2, NH3, hydrocarbons, etc. and the occurence of electron-transfer reactions between adsorbed species is also described. Preliminary results on photocatalytic systems are quoted.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W.N. Delgass, G.L. Halier, R. Kellermann and J.H. Lunsford, Spectroscopy in Heterogeneous Catalysis, Academic Press, New York, 1979, p.19.

    Book  Google Scholar 

  2. A.N. Terenin, Surface Chemical Compounds and Their Role in Adsorption Phenomena, A.V. Kiselev ed., Moscow State University Press, 1957.

    Google Scholar 

  3. R.P. Eischens, S.A. Francis and W.A. Pliskin, Phys. Chem., 60, 194 (1956).

    Article  CAS  Google Scholar 

  4. Vibration at Surfaces, D.A. King, N.V. Richardson and S. Holloway eds., Elsevier, Amsterdam, 1986.

    Google Scholar 

  5. Vibrational Spectroscopy of Adsorbates, R.F. Willis ed., Springer-Verlag, Berlin, 1980.

    Google Scholar 

  6. E. Borello, A. Zecchina and M. Castelli, Ann. Chim. (Rome), 53, 690 (1963).

    CAS  Google Scholar 

  7. J. Pritchard and T. Catterick, in Experimental Methods in Catalytic Research, vol. III R.B. Anderson and P.T. Dawson eds., Academic Press, New York, 1976, p. 281.

    Google Scholar 

  8. A.E. Martin, Infrared Interferometric Spectrometers, J.R. ed., Elsevier, Amsterdam, 1980.

    Google Scholar 

  9. Fourier Transform Infrared Spectroscopy, vol. 4, J.R. Ferraro and L.J. Basile eds., Academic Press, New York, 1985.

    Google Scholar 

  10. J.L. Roustan, Y. Lijour and B.A. Morrow, Inorg. Chem., 26, 2509 (1987);

    Article  CAS  Google Scholar 

  11. A.J. Dixon, S.J. Gravelle, L.J. van de Bürgt, M. Poliakoff, J.J. Turner and E. Weitz, J. Chem. Soc., Chem. Comm., 1023 (1987) and references therein.

    Google Scholar 

  12. N.B. Colthup, L.H. Daly and S.E. Wiberley, Introduction to Infrared and Raman Spectroscopy, Academic Press, New York, 1975.

    Google Scholar 

  13. R.P. Eischens and W.A. Pliskin, Adv. Catal., 10, 1 (1958).

    Article  CAS  Google Scholar 

  14. L.H. Little, Infrared Spectra of Adsorbed Species, Academic Press, New York, 1966.

    Google Scholar 

  15. A. Zecchina, E. Garrone and E. Guglielminotti, in Specialist Periodical Reprts, Catalysis, vol. 6, Royal Society of Chemistry, London, 1983, p. 90.

    Google Scholar 

  16. A. Zecchina, S. Coluccia and C. Morterra, Appl. Spectr. Rev., 21, 259 (1985).

    Article  CAS  Google Scholar 

  17. E. Escalona Platero, S. Coluccia and A. Zecchina, Surface Sci., 171, 465 (1986).

    Article  CAS  Google Scholar 

  18. F.M. Hoffmann, Surface Sci. Rept., 3, 107 (1983).

    Article  CAS  Google Scholar 

  19. M.A. Van Hove, in: The Nature of the Surface Chemical Bond, T.N. Rhodin and G. Ertl eds., North-Holland, Amsterdam, 1979, p. 276.

    Google Scholar 

  20. E. Escalona Platero, D. Scarano, G. Spoto and A. Zecchina, Faraday Discuss. Chem. Soc., 80, 1 (1985).

    Google Scholar 

  21. N. Sheppard and T.T. Nguyen, in Advances in Infrared and Raman Spectroscopy, vol. 5, R.J.H. Clark and R.E. Hester eds., Heyden, London, 1978, p. 87.

    Google Scholar 

  22. E. Guglielminotti, S. Coluccia, E. Garrone, L. Cerruti and A. Zecchina, Chem. Soc. Faraday Trans. 1, 75, 96 (1979)

    Article  Google Scholar 

  23. S. Coluccia, E. Garrone, E. Guglielminotti and A. Zecchina, J. Chem. Soc. Faraday Trans. 1, 77, 1063 (1981).

    Article  Google Scholar 

  24. F.S. Stone and A. Zecchina, in Proceedings 6th Int. Congr. on Catalysis, The Chemical Society, London, 1977, vol. I, p. 162.

    Google Scholar 

  25. G. Ghiotti, E. Garrone and A. Zecchina, presented at the 7th Intern. Cong. on Olefin Metathesis and Polymerization, Hall, 1987, to be published in J. Mol. Catal., and references therein.

    Google Scholar 

  26. M. Che and A.J. Tench, Adv. Catalysis, 31, 77 (1982)

    CAS  Google Scholar 

  27. M. Che and A.J. Tench, Adv. Catalysis, 32, 1 (1983).

    CAS  Google Scholar 

  28. D. Cordischi, V. Indovina and M. Occhiuzzi, Chem. Soc., Faraday Trans. 1, 74, 456 (1978)

    Article  Google Scholar 

  29. D. Cordischi, V. Indovina and M. Occhiuzzi, Chem. Soc., Faraday Trans. 74, 883 (1978).

    Article  CAS  Google Scholar 

  30. S. Coluccia, F. Boccuzzi, G. Ghiotti and C. Mirra, Z. Phys. Chem. (N.F.) 121, 141 (1980)

    Article  CAS  Google Scholar 

  31. S. Coluccia, F. Boccuzzi, G. Ghiotti and C. Morterra, Chem. Soc., Faraday Trans. 1, 78, 2111 (1982).

    Article  Google Scholar 

  32. S. Coluccia, A. Barton and A.J Tench, Chem. Soc. Faraday Trans. 1, 77, 2203 (1981).

    Article  Google Scholar 

  33. T. Iizuka, Chem. Letters (Japan), 981 (1973)

    Google Scholar 

  34. T. Iizuka and K. Tanabe, Bull. Chem. Soc. Japan, 48, 2527 (1975).

    Article  CAS  Google Scholar 

  35. M. Che, A.J. Tench, S. Coluccia and A. Zecchina, J. Chem. Soc., Faraday Trans. 1, 72, 1553 (1976)

    Article  Google Scholar 

  36. M. Che, S. Coluccia and A. Zecchina, J. Chem. Soc., Faraday Trans. 1, 74, 1324 (1978).

    Article  Google Scholar 

  37. S. Coluccia, A. Chiorino, E. Guglielminotti and C. Morterra, J. Chem. Soc., Faraday Trans. 1, 75, 2188 (1979)

    Article  Google Scholar 

  38. S. Coluccia, E. Garrone and C. Morterra, Z. Phys. Chem. (N.F.), 124, 201 (1981).

    Article  CAS  Google Scholar 

  39. S. Coluccia, J.F. Hemidy and A.J. Tench, Chem. Soc., Faraday Trans. 1, 74, 2763 (1978).

    Article  Google Scholar 

  40. E. Garrone, A. Zecchina and F. Stone, Catal., 62, 396 (1980).

    Article  CAS  Google Scholar 

  41. A.J. Tench and D. Giles, J. Chem. Soc., Faraday Trans. 1, 68, 193 (1972)

    Article  Google Scholar 

  42. A.J. Tench and D. Giles, J. Chem. Soc., Faraday Trans. 68, 197 (1972).

    Article  CAS  Google Scholar 

  43. S. Coluccia, E. Garrone and E. Borello, J. Chem. Soc., Faraday Trans. 1, 79, 607 (1983).

    Article  Google Scholar 

  44. S. Coluccia, S. Lavagnino and L. Marchese, J. Chem. Soc., Faraday Trans. 1, 83, 477 (1987).

    Article  Google Scholar 

  45. E. Borello, S. Coluccia and A. Zecchina, Catal., 93, 331 (1985).

    Article  CAS  Google Scholar 

  46. E. Garrone, S. Coluccia and E. Giamello, Spectrochim. Acta, 43A, (1987), in press.

    Google Scholar 

  47. E. Escalona Platero, S. Coluccia and A. Zecchina, J. Catal., 103, 270 (1987).

    Article  CAS  Google Scholar 

  48. S. Tunesi and M.A. Anderson, Chemosphere, 16, 1447 (1987).

    Article  CAS  Google Scholar 

  49. V. Augugliano, L. Palmisano, M. Schiavello and A. Sclafani, J. Catal., 99, 62 (1986).

    Article  Google Scholar 

  50. A.Sclafani, L. Palmisano, M. Schiavello, V.Augugliano, S. Coluccia and L. Marchese, Nouv. J. Chim., in press.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Fisica, Via P. Giuria, 7, 10125, Torino, Italy

    S. Coluccia & L. Marchese

Authors
  1. S. Coluccia
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Marchese
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemical Engineering of Processes and Materials, Engineering Faculty, University of Palermo, Palermo, Italy

    Mario Schiavello

Rights and permissions

Reprints and permissions

Copyright information

© 1988 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Coluccia, S., Marchese, L. (1988). Gas — Solid Interphase: Characterization by Infrared Spectroscopies. In: Schiavello, M. (eds) Photocatalysis and Environment. NATO ASI Series, vol 237. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3015-5_5

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-3015-5_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7855-9

  • Online ISBN: 978-94-009-3015-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation