Molecules in Physics, Chemistry, and Biology pp 287-310 | Cite as
Small Naked Homonuclear Clusters of Transition Metal Atoms
Abstract
“Cluster” is a word that appears more and more frequently in the scientific literature, particularly in physics, chemistry, and biology; it defines [1, 2] an agglomerate of atoms or molecules (from two to several thousands), preferably of the same species, often embedded in matrices or supported on a solid substrate. In the scale of complexity of the structure of matter, clusters occupy the region between isolated atoms or molecules and their large aggregates with liquid or solid properties; one would then expect that cluster research would not only provide useful information on the cluster behavior, which is of great technological importance in its own right, but also serve as a basis for the study of the transition from the gas phase to condensed matter. Moreover, as clusters possess the very significant property of having a large surface in comparison to their volume, they represent ideal objects for surface physics studies.
Keywords
Vibrational Frequency Dissociation Energy Internuclear Distance Equilibrium Distance Spectroscopic ConstantPreview
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