Effect of Active Elements on the Oxidation Behaviour of Al2O3-Formers

  • A. M. Huntz
Chapter

Abstract

The main mechanisms suggested in the literature for interpreting the effect of active elements on the growth and adhesion of alumina scales are reviewed and discussed, with particular emphasis on some of the more recent contributions.

First, the various active elements will be considered on whether they can detrimentally affect alumina scales, show varying effects or improve the protective character of such scales.

Then, the discussion will be focused on some of the more important mechanisms developed during the recent years and which account for the improvement of the properties of Al2O3 scales, i.e. effect of active elements on:

  • the strengthening of the alloy-scale bonding with relation to segregation phenomena;

  • the scale morphology and microstructure;

  • the diffusion mechanisms;

  • the scale plasticity.

The discussion will be supported by results obtained on doped massive alumina.

Keywords

Oxide Scale Active Element Oxidation Behaviour Alumina Scale Chromia Scale 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

  1. 1.
    D.P. Whittle and J. Stringer, Phil. Trans. R. Soc. London, Ser. A, 1980, 295, 309.CrossRefGoogle Scholar
  2. 2.
    G.C. Wood and F.H. Stott, in High Temperature Corrosion, NACE-6, 1983, 227.Google Scholar
  3. 3.
    H. Hindam and D.P. Whittle, Oxid. Met., 1982, 18, 245.CrossRefGoogle Scholar
  4. 4.
    F.H. Stott and G.C. Wood, Mat. Sci. and Eng., 1987, 87, 267.CrossRefGoogle Scholar
  5. 5.
    A.M. Huntz, Mat. Sci. and Eng., 1987, 87, 251.CrossRefGoogle Scholar
  6. 6.
    D.P. Moon, UKAEA Report no AERE R 12930, 1988.Google Scholar
  7. 7.
    J.G. Smeggil, A.W. Funkenbusch and N.S. Bornstein, Met. Trans., 1986, 17A, 923.Google Scholar
  8. 8.
    J.G. Smeggil, Mat. Sci. and Eng., 1987, 87, 261.CrossRefGoogle Scholar
  9. 9.
    A.R. Nicoll and G. Wahl, Superalloys 1984, Met. Soc. of AIME Pub., 1984, 805.Google Scholar
  10. 10.
    A. Boumaza, G. Moulin and A.M. Huntz, Oxid. Met., 1988, 30, 3-4, 141, and A. Boumaza, Thesis, University Paris XI, Orsay, France, 1987.Google Scholar
  11. 11.
    R. Mevrel, ONERA, private communication.Google Scholar
  12. 12.
    M.H. Lagrange, A.M. Huntz and J.H. Davidson, Corr. Sci., 1984, 24 (7), 613.CrossRefGoogle Scholar
  13. 13.
    D. Fellman, Y. Bienvenu and M. Foucault, Mem. Sci. Rev. Met., 1983, 80, 37.Google Scholar
  14. 14.
    S. Taniguchi and T. Shibata, 10th ICMC, Madras 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, Vol IV, 3385.Google Scholar
  15. 15.
    P. Pauwels, Thesis, ENSMP-ARMINES, France, 1988.Google Scholar
  16. 16.
    A.S. Kahn, C.E. Lowell and C.A. Barret, J. of the Electrochemical Soc., 1980, 127 (3), 670.CrossRefGoogle Scholar
  17. 17.
    J.L. Pandey, S. Prakash, and M.L. Mehta, 10th ICMC, Madras, 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, vol IV, 3507.Google Scholar
  18. 18.
    D. Saxena, S. Prakash, M.L. Mehta and I.P. Saraswat, 10 ICMC, Madras, 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, vol IV, 3495.Google Scholar
  19. 19.
    P. Choquet, Doctor Thesis, University Paris XI, Orsay, France, 1987 and P. Choquet and R. Mevrel, Proc. Int. Conf. on Metallurgical Coatings, San Diego, 17-21 April 1989., D. Diot, P. Choquet and R. Mevrel, Proc. ICRS-2, 23-25 Nov. 1988, Nancy.Google Scholar
  20. 20.
    I.M. Allam, D.P. Whittle and J. Stringer, Oxid. Met., 1978, 12 (1), 35.CrossRefGoogle Scholar
  21. 21.
    J.C. Pivin, D. Delaunay, C. Roques-Carmes, A.M. Huntz and P. Lacombe, Corr. Sci., 1980, 20, 351.CrossRefGoogle Scholar
  22. 22.
    G. Ben Abderrazik, G. Moulin, A.M. Huntz and R. Berneron, J. of Mat. Sci., 1984, 19, 3173.CrossRefGoogle Scholar
  23. 23.
    A.M. Huntz, G. Moulin and G. Ben Abderrazik, Ann. Chim. Fr., 1986, 11, 291.Google Scholar
  24. 24.
    J. Rousselet, Doctor thesis, University Paris XI, Orsay, France, 1988, and Proceedings of Euroanalysis VI, 7-11 Sept. 1987, Paris, Ed. GAMS, Paris.Google Scholar
  25. 25.
    A.W. Funkenbusch, J.G. Smeggil and N.S. Bornstein, Met. Trans., 1985, 16A, 1164.Google Scholar
  26. 26.
    D.G. Lees, Oxid. Met., 1987, 27 (1-2), 75.CrossRefGoogle Scholar
  27. 27.
    C.L. Briant and K.L. Luthra, Met. Trans., 1988, 19A, 2091 and 2099.Google Scholar
  28. 28.
    R.P. Messmer and C.L. Briant, Acta Met., 1982, 30, 457.CrossRefGoogle Scholar
  29. 29.
    H. Hindam and D.P. Whittle, J. Electrochem. Soc., 1982, 129, 1147.CrossRefGoogle Scholar
  30. 30.
    J.H. Davidson, P. Lacombe, A.M. Huntz, C. Roques-Carmes, J.C. Pivin and D. Delaunay, in: Behaviour of high temperature alloys in aggressive environments. The Metals Society, London, 1980, 209.Google Scholar
  31. 31.
    D.P. Whittle and D.H. Boone, Proc. 8th ICMC, Mainz, 1981, Dechema, Frankfurt-Main, 718.Google Scholar
  32. 32.
    C.S. Giggins and F.S. Pettit, Report ARL 75-0234, 1975.Google Scholar
  33. 33.
    I.A. Allam, D.P. Whittle and J. Stringer, Oxid. Met., 1979, 13, 381.CrossRefGoogle Scholar
  34. 34.
    F.A. Golightly, F.H. Stott and G.C. Wood, J. Electrochem. Soc., 1976, 126, 1035.CrossRefGoogle Scholar
  35. 35.
    D. Delaunay and A.M. Huntz, J. Mat. Sci., 1982, 17, 2027.CrossRefGoogle Scholar
  36. 36.
    F.A. Golightly, F.H. Stott and G.C. Wood, Oxid. Met., 1976, 10, 163.CrossRefGoogle Scholar
  37. 37.
    C.S. Giggins, B.H. Kear, F.S. Pettit and J.K. Tien, Met. Trans., 1974, 5, 1685.CrossRefGoogle Scholar
  38. 38.
    J.D. Kuenzly and D.L. Douglass, Oxid. Met., 1974, 8, 139.CrossRefGoogle Scholar
  39. 39.
    J.K. Tien and F.S. Pettit, Met. Trans., 1972, 3, 1587.CrossRefGoogle Scholar
  40. 40.
    A. Kumar, M. Hasrallah and D.L. Douglass, Oxid. Met., 1974, 8, 227.CrossRefGoogle Scholar
  41. 41.
    T. Amano, S. Yajima and Y. Saito, Trans. JIM, 1979, 20, 431.Google Scholar
  42. 42.
    J.L. Smialek and R. Gibala, Met. Trans., 1983, 14A, 2143.Google Scholar
  43. 43.
    J.C. Pivin, C. Roques-Carmes, J. Chaumont and H. Bernas, Corr. Sci., 1980, 20, 947.CrossRefGoogle Scholar
  44. 44.
    A.B. Anderson, S.P. Mehandra and J.L. Smialek, J. Electrochem. Soc. 1985, 132, 1695.CrossRefGoogle Scholar
  45. 45.
    J.G. Smeggil, A.W. Funkenbusch and N.S. Bornstein, Proc. Spring Electrochemical Society Meeting, Cincinnati, Ohio, 1984.Google Scholar
  46. 46.
    C.L. Briant and R.A. Mulford, Met. Trans., 1982, 13A, 745.Google Scholar
  47. 47.
    J.L. Smialek, NASA, TM 81676, 1981, and TM 100 209, 1987. J.L. Smialek and R. Browning, NASA TM 87168, 1985.Google Scholar
  48. 48.
    J.L. Smialek, Met. Trans. 1987, A18, 164.Google Scholar
  49. 49.
    H. Hindam and W.W. Smeltzer, J. Electrochem. Soc., 1980, 127, 1630 and Oxid. Met., 1980, 14 (4), 337.Google Scholar
  50. 50.
    J. Jedlinski, 10th ICMC, Madras, 7-11 Nov. 1987, Ed. by Oxford and IBM Publishing Co, PVT, LTD, vol VI, 3709.Google Scholar
  51. 51.
    S.S. Mrowec, A. Gil and A. Jedlinski, Werkstoffe und Korrosion, 1987, 38, 563.CrossRefGoogle Scholar
  52. 52.
    A.M. Huntz, G. Ben Abderrazik, G. Moulin, E.W. Joung and J.H.W. De Wit, Applied Surface Science, 1987, 28, 345 and Solid State Ionics, 1987, 22, 285.Google Scholar
  53. 53.
    E.J. Felten and F.S. Pettit, Oxid. Met., 1976, 10, 189.CrossRefGoogle Scholar
  54. 54.
    T.A. Ramanarayanan, R. Ayer, R. Petkovic-Luton and D.P. Leta, Oxid. Met., 1988, 9, (5-6), 445.CrossRefGoogle Scholar
  55. 55.
    D. Nicolas-Chaubet, Thesis, University Paris XI, Orsay, 1989.Google Scholar
  56. 56.
    J.K. Doychak, T.E. Mitchell and J.L. Smialek, Mat. Res. Soc. Symp. Proc., 1985, 39, 475.CrossRefGoogle Scholar
  57. 57.
    J. Jedlinski and S. Mrowec, Mat. Sci. and Eng., 1987, 87, 281.CrossRefGoogle Scholar
  58. 58.
    G. Tremouilles, Doctor Thesis, University Paris VI, France, 1988, and G. Termouilles, J.L. Derep and R. Portier, Advances in Thermal Spraying, ITCS’86, Pergamon 1986, 465.Google Scholar
  59. 59.
    J.D. Cawley, and J.W. Halloran, J. Amer. Cer. Soc., 1986, 69 (8), C 195–196.CrossRefGoogle Scholar
  60. 60.
    G. Petot-Ervas, D. Deweirder, M. Loudjani, B. Lesage and A.M. Huntz, Advances in Ceramics, 1987, 23, 125.Google Scholar
  61. 61.
    I.A. Bondar, Izv. Akad. Nauk. SSSR, Neorg. Mat., 1984, 20 (2), 257.Google Scholar
  62. 62.
    D. Bouchet, University Paris XI, Orsay, private communication.Google Scholar
  63. 63.
    D. Prot, B. Lesage, C. Monty and A.M. Huntz, unpublished work.Google Scholar
  64. 64.
    K.P.R. Reddy, J.L. Smialek and A.R. Cooper, Oxid. Met., 1982, 17 (5-6), 429.CrossRefGoogle Scholar
  65. 65.
    T.A. Ramanarayanan, M. Rachavan and R. Petkovic-Luton, Oxid. Met., 1984, 22 (3-4), 83, and J. Electrochem. Soc., 1984, 131 (4), 923.Google Scholar
  66. 66.
    E.W.A. Young and J.H.W. De Wit, Solid State Ionics, 1985, 16, 39 and Oxid. Met., 1986, 26, 351.Google Scholar
  67. 67.
    M.J. Bennet and D.P. Moon, this conference.Google Scholar
  68. 68.
    M.M. El Aiat and F.A. Kroger, J. Am. Ceram. Soc., 1982, 65 (6), 280.CrossRefGoogle Scholar
  69. 69.
    G.J. Dienes, D.O. Welch, C.R. Fisher, R.D. Hatcher, D. Lazareth and M. Samberg, Phys. Rev., 1975, B11 (8), 3060.Google Scholar
  70. 70.
    S. Lartigue, Doctor Thesis, University Paris XI, Orsay, France, 1988 and Phys. Rev., 1975, B11 (8), 3060.Google Scholar
  71. 71.
    M.H. Lagrange, A.M. Huntz and J.Y. Laval, Ann. Chim. Fr., 1987, 12, 9.Google Scholar
  72. 72.
    A.M. Huntz, G. Moulin and B. Lesage, Proc. 9th ICMC, Toronto, June 3-7, 1984, voll II, National Research Council of Canada, Toronto, 1984, 400.Google Scholar
  73. 73.
    A.E. Paladino and W.D. Kingery, J. Chem. Phys., 1962, 37 (5), 957.CrossRefGoogle Scholar
  74. 74.
    Y. Oishi and W.D. Kingery, J. Chem. Phys., 1960, 33 (2), 480.CrossRefGoogle Scholar
  75. 75.
    F.A. Kroger, Solid State Ionics, 1984, 12, 189.CrossRefGoogle Scholar
  76. 76.
    A. Atkinson, this conference.Google Scholar
  77. 77.
    J. Nowok, Oxid. Met., 1982, 18 (1-2), 1.CrossRefGoogle Scholar
  78. 78.
    J. Castaing, this conference.Google Scholar
  79. 79.
    C. Carry and A. Mocellin, Ceramics International, 1987, 13, 89.CrossRefGoogle Scholar
  80. 80.
    A.M. Huntz et al., Mat. Sci. and Techn., 1988, 4 (5), 470 and 1988, 4 (12), 1079.Google Scholar
  81. 81.
    D. Delaunay, A.M. Huntz and P. Lacombe, Corr. Sci., 1980, 20, 1109.CrossRefGoogle Scholar
  82. 82.
    K.L. Luthra and C.L. Briant, Oxid. Met., 1986, 26 (5-6), 397.CrossRefGoogle Scholar
  83. 83.
    R.M. Cannon, W.H. Rhodes and A.H. Heuer, J. Am. Ceram. Soc., 1980, 63, 46.CrossRefGoogle Scholar
  84. 84.
    M.I. Manning, in: Corrosion and Mechanical Stress at High Temperature, eds. V. Guttman and M. Merz, Applied Science Publishers Ltd., London, 1981, 323.Google Scholar
  85. 85.
    J.D. Cawley, J.W. Halloran and A.R. Cooper, NASA T.M. 83622, 1984.Google Scholar
  86. 86.
    W.D. Kingery, D.C. Hill and R.P. Nelson, J. Amer. Cer. Soc., 1960, 43, 473.CrossRefGoogle Scholar
  87. 87.
    Y. Oishi, H. Koizumi, Y. Sakka and K. Ando, J. Met. Sc. Letter, 1985, 4 (2), 176.CrossRefGoogle Scholar
  88. 88.
    H. Haneda, Y. Miyasawa and S. Shirasaki, J. of Crystal Growth, 1984, 68 (2), 581.CrossRefGoogle Scholar
  89. 89.
    M.F. Berard, J. Amer. Cer. Soc., 1968, 51_, 648.CrossRefGoogle Scholar
  90. 90.
    M.F. Berard, J. Amer. Cer. Soc., 1967, 50, 113.CrossRefGoogle Scholar
  91. 91.
    K. Ando, J. Amer. Cer. Soc., 1983, 66, C–222.Google Scholar

Copyright information

© ECSC, EEC, EAEC. Brussels and Luxembourg 1989

Authors and Affiliations

  • A. M. Huntz
    • 1
  1. 1.Laboratoire de Métallurgie Structurale, ISMA, CNRS UA, 1107Université Paris XIOrsay CedexFrance

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