Stereoselective Formation of Linear AZA-Triquinanes by Three Consecutive Radical Ring Closures

  • Lucien Stella
  • Doug Boate
  • Eric Guittet
Part of the NATO ASI Series book series (ASIC, volume 260)

Abstract

Treatment of the trienyl N-chloroamine 5 with titanium trichloride affords regio- and stereoselectively, as the major product (nearly half of the overall yield) the 8-aza-4-anti-chloromethyl-cis, syn, cis tricyclo (6, 3, 0, 0 2,6) undecane 10d by serial homolytic cyclisations.

Keywords

Tetrahedron Letter Bicyclic Compound Medium Pressure Liquid Chromatography Titanium Trichloride Bridgehead Carbon 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic Publishers 1989

Authors and Affiliations

  • Lucien Stella
    • 1
  • Doug Boate
    • 1
  • Eric Guittet
    • 2
  1. 1.Laboratoire de Chimie Organique BUniversité d’Aix-Marseille 3Marseille Cedex 13France
  2. 2.Institut de Chimie des Substances NaturellesCNRSGif sur YvetteFrance

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