Dynamics at Fluid Solid Interfaces: Porous Media and Colloidal Particles

  • Rainer Kimmich
Chapter
First Online:

Abstract

This chapter could be entitled “molecular motions in complex media” as well. The point is that the systems of interest can be defined by the existence of fluid–solid interfaces. Surface-related phenomena are therefore of central interest. There is an endless list of examples belonging to this category in principle. Emphasis will be laid on porous glasses, fine-particle agglomerates, biopolymer solutions, lipid bilayers, biological tissue, etc. The predominant purpose of this chapter is to elaborate a well-classified scheme of the key mechanisms determining molecular dynamics in the presence of fluid–solid interfaces. This includes adsorption and exchange kinetics, translational and rotational diffusion, and liquid/vapor coexistence phenomena. Effects due to fluid–wall interactions on the one hand and, on the other hand, owing to geometric confinement in mesoscopic pore spaces will thoroughly be discriminated.

Keywords

Spin Relaxation Hydration Shell Lattice Relaxation Adsorbed Phase Translational Diffusion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer Science+Business Media Dordrecht 2012

Authors and Affiliations

  • Rainer Kimmich
    • 1
  1. 1.Sektion KernresonanzspektroskopieUniversität UlmUlmGermany

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