New Membrane Materials Via Catalytic Polymerization of Bis(Trimethylsilyl)-Substituted Norbornene Type Monomers

  • Maxim V. Bermeshev
  • Maria L. Gringolts
  • Ludmila E. Starannikova
  • Alexei V. Volkov
  • Eugene Sh. Finkelstein
Conference paper
Part of the NATO Science for Peace and Security Series A: Chemistry and Biology book series (NAPSA)

Abstract

In this work we summarize our results of investigation on ring-opening metathesis (ROMP) and addition polymerization (AP) of a range of norbornene, norbornadiene and tricyclononene monomers containing two Me3Sisubstituents. The tested monomers exhibited different reactivity in ROMP and AP. The new polymers obtained demonstrated high gas permeability and allowed defining some correlations between features of their chemical structure and gas separation characteristics.

Keywords

Silyl norbornenes ROMP Addition polymerization Gas permeability 
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Notes

Acknowledgment

The authors would like to thank Dr. V. Lakhtin for the preparation of bis(trichlorosilyl)ethyne and 1,2-trans-bis(trichlorosilyl)ethylene.

This work was supported by The Russian Foundation of Basic Research 09-03-00342-a and The Russian Science Support Foundation.

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Copyright information

© Springer Science+Business Media B.V. 2009

Authors and Affiliations

  • Maxim V. Bermeshev
    • 1
  • Maria L. Gringolts
    • 1
  • Ludmila E. Starannikova
    • 1
  • Alexei V. Volkov
    • 1
  • Eugene Sh. Finkelstein
    • 1
  1. 1.Russian Academy of SciencesA.V Topchiev Institute of Petrochemical SynthesisMoscowRussia

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