Introduction to Astrochemistry pp 11-36 | Cite as
Derivation of Molecular Abundances
Abstract
General derivation of molecular abundances from spectral lines observed with radio telescopes is presented. After describing basic physical properties of thermal radiation and blackbody radiation, a radiative transfer equation is derived and applied for a few ideal cases. A rotation diagram method under a local thermodynamic equilibrium (LTE) condition, a concept of the critical density, and a basic principle of statistical equilibrium calculations for a non-LTE condition are described. Practical cautions in deriving molecular abundances are also given, which include beam dilution effects, a use of molecular parameters including a relation between a partition function and line strengths, and a treatment of ortho/para species of molecules.
Keywords
Thermal radiation Radiative transfer Optical depth Critical density Molecular parametersReferences
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