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Diffusion coefficient of acetonitrile-d3 in trichloro-deuterio-methane

  • Jochen Winkelmann
Chapter
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of acetonitrile-d3 in trichloro-deuterio-methane at different concentrations measured using NMR spin echo pulse gradient.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C2 D3 N

(1)

acetonitrile-d3

2206-26-0

C Cl3 D

(2)

trichloro-deuterio-methane

865-49-6

Intradiffusion Coefficient: D1T (xi); T = 298.15 K; Method: NMR PG

Ref.: [1989K6]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

1.00

101.32

4.04

 

0.692

101.32

3.28

 

0.501

101.32

2.88

 

0.304

101.32

2.68

 

0.149

101.32

2.60

 

0.104

101.32

2.66

 

0.032

101.32

2.60

 

Intradiffusion Coefficient: D2T (xi); T = 298.15 K; Method: NMR PG

Ref.: [1989K6]

x 1

p [kPa]

D ⋅ 109 [m2/s]

 

0.692

101.32

2.68

 

0.501

101.32

2.42

 

0.304

101.32

2.34

 

0.149

101.32

2.33

 

0.104

101.32

2.40

 

0.032

101.32

2.41

 

0.0

101.32

2.45

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

NMR PG

NMR spin echo pulse gradient

x i

mole fraction

References

  1. [1989K6]
    Kovacs, H., Kowalewski, J., Maliniak, A., Stilbs, P.: J. Phys. Chem. 93 (1989) 962–969.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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