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Diffusion coefficient of carbon disulfide in toluene

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of carbon disulfide in toluene at different concentrations measured using porous frits, plug or barrier.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C S2

(1)

carbon disulfide

75-15-0

C7 H8

(2)

toluene

108-88-3

Mutual Diffusion Coefficient: D12(xi); T = 293.15 ± 0.1 K; Method: PF

Ref.: [1953K1]

x 1

p [atm]

D ⋅ 109 [m2/s]

 

0.50

1.0

1.93 ± 5%

 

0.50

50

1.93 ± 5%

 

0.50

300

1.49 ± 5%

 

0.50

900

0.742 ± 5%

 

0.50

3300

0.575 ± 5%

 

0.50

7150

0.530 ± 5%

 

Mutual Diffusion Coefficient: D12(xi); T = 313.15 ± 0.1 K; Method: PF

Ref.: [1953K1]

x 1

p [atm]

D ⋅ 109 [m2/s]

 

0.50

200

4.03 ± 5%

 

0.50

900

1.97 ± 5%

 

0.50

1500

1.49 ± 5%

 

0.50

3500

0.850 ± 5%

 

0.50

5750

0.710 ± 5%

 

0.50

9100

0.669 ± 5%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

PF

porous frits, plug or barrier

x i

mole fraction

References

  1. [1953K1]
    Koeller, R.C., Drickammer, H.G.: J. Chem. Phys. 21 (1953) 575–588.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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