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Diffusion coefficient of carbon disulfide in methyl-cyclohexane

  • Jochen Winkelmann
Part of the Physical Chemistry book series (volume 15B2)

Abstract

This chapter provides the diffusion coefficient of carbon disulfide in methyl-cyclohexane at different concentrations measured using porous frits, plug or barrier.

3 Diffusion in Liquid Mixtures

3.1. Data

3.1.1. Diffusion in Binary Mixtures

C S2

(1)

carbon disulfide

75-15-0

C7 H14

(2)

methyl-cyclohexane

108-87-2

Mutual Diffusion Coefficient: D12(x i ); T = 273.15 ± 0.1 K; Method: PF

Ref.: [1953K1]

x 1

p [atm]

D ⋅ 109 [m2/s]

 

0.50

50

2.37 ± 5%

 

0.50

1200

0.621 ± 5%

 

0.50

3000

0.236 ± 5%

 

Mutual Diffusion Coefficient: D12(x i ); T = 293.15 ± 0.1 K; Method: PF

Ref.: [1953K1]

x 1

p [atm]

D ⋅ 109 [m2/s]

 

0.50

50

2.65 ± 5%

 

0.50

900

1.83 ± 5%

 

0.50

3000

0.585 ± 5%

 

0.50

7000

0.192 ± 5%

 

Mutual Diffusion Coefficient: D12(x i ); T = 313.15 ± 0.1 K; Method: PF

Ref.: [1953K1]

x 1

p [atm]

D ⋅ 109 [m2/s]

 

0.50

200

3.00 ± 5%

 

0.50

900

1.97 ± 5%

 

0.50

2000

1.34 ± 5%

 

0.50

4000

0.965 ± 5%

 

0.50

5000

0.690 ± 5%

 

0.50

6300

0.540 ± 5%

 

0.50

7750

0.485 ± 5%

 

0.50

10000

0.351 ± 5%

 
Symbols and Abbreviations

Short Form

Full Form

D

diffusion coefficient

p

pressure

T

temperature

PF

porous frits, plug or barrier

x i

mole fraction

References

  1. [1953K1]
    Koeller, R.C., Drickammer, H.G.: J. Chem. Phys. 21 (1953) 575–588.CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2018

Authors and Affiliations

  • Jochen Winkelmann
    • 1
  1. 1.Universität Halle-Wittenberg, Institut für Physikalische ChemieHalle/S.Germany

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